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Bis(triphenylphosphinepalladium) acetate

Product Name
Bis(triphenylphosphinepalladium) acetate
CAS No.
14588-08-0
Chemical Name
Bis(triphenylphosphinepalladium) acetate
Synonyms
BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DIACETATE;adium(II) diacetate;Bis(triphenylphosphinepalladiu;Palladium triphenylphosphine acetate;Palladium, bis(acetato-O)bis(triphenyl;Actatebis(triphenylphosphine) palladium;Bis(triphenylphosphinepalladium) acetate;BIS(ACETATO)TRIPHENYLPHOSPHINEPALLADIUM&;Diacetoxybis(triphenylphosphine)palladium;Actatebis(triphenylphosphine) palladium(II)
CBNumber
CB6243634
Molecular Formula
C40H36O4P2Pd
Formula Weight
749.08
MOL File
14588-08-0.mol
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Bis(triphenylphosphinepalladium) acetate Property

Melting point:
136 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
sol acetonitrile, benzene, dioxane, DMF, DMSO, THF; low sol petroleum ether.
form 
Powder
color 
Yellow
Stability:
store cold
InChI
InChI=1S/2C18H15P.2C2H4O2.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2(3)4;/h2*1-15H;2*1H3,(H,3,4);/q;;;;+2/p-2
InChIKey
OZELLBKLLRMCRL-UHFFFAOYSA-M
SMILES
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1.O(C(=O)C)[Pd]OC(=O)C
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Safety

Hazard Codes 
Xn
Safety Statements 
22-24/25
WGK Germany 
3
F 
1-3-10
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
225452
Product name
Bis(triphenylphosphine)palladium(II) diacetate
Purity
98%
Packaging
10g
Price
$483
Updated
2023/06/20
TCI Chemical
Product number
B2042
Product name
Bis(triphenylphosphine)palladium(II) Diacetate
Purity
>98.0%(T)
Packaging
1g
Price
$192
Updated
2024/03/01
TCI Chemical
Product number
B2042
Product name
Bis(triphenylphosphine)palladium(II) Diacetate
Purity
>98.0%(T)
Packaging
5g
Price
$704
Updated
2024/03/01
Alfa Aesar
Product number
H61853
Product name
Diacetatobis(triphenylphosphine)palladium(II), Pd 14.2%
Packaging
1g
Price
$75.3
Updated
2023/06/20
Alfa Aesar
Product number
H61853
Product name
Diacetatobis(triphenylphosphine)palladium(II), Pd 14.2%
Packaging
10g
Price
$526
Updated
2023/06/20
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Bis(triphenylphosphinepalladium) acetate Chemical Properties,Usage,Production

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Bis(triphenylphosphine)palladium(II) diacetate can be used as a catalyst for C-C bond formation via Sonogashira coupling, Negishi coupling, Heck coupling, and Suzuki coupling reaction.
It can also be used as a catalyst to synthesize:

  • Pyrido[1,2-a]benzimidazole derivatives by electro-oxidative intramolecular C-H/N-H annulation reaction.
  • α, β-Unsaturated carboxylic acids by hydroxycarbonylation of vinyl triflates.
  • Secondary imides by C-H functionalization of aldehydes with different N-substituted N-heteroarene-2-carboxamides.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Bis(triphenylphosphinepalladium) acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(triphenylphosphinepalladium) acetate Suppliers

Americas 1 Australia 1 Belgium 2 China 220 Europe 1 France 2 Germany 6 India 10 Japan 3 South Korea 1 Switzerland 2 United Kingdom 6 United States 29 Global 284
SINOPRO.CO.LTD
Tel
0082-42-721-7177
Fax
0082-42-3676760
Email
michael@sinopro.co.kr
Country
South Korea
ProdList
297
Advantage
58
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View Lastest Price from Bis(triphenylphosphinepalladium) acetate manufacturers

henan kanbei chemical co.,ltd
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 14588-08-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-20
Longyan Tianhua Biological Technology Co., Ltd
Product
Bis(triphenylphosphinepalladium) acetate 14588-08-0
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Bis(triphenylphosphinepalladium) acetate 14588-08-0
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
100kg
Release date
2018-12-22

14588-08-0, Bis(triphenylphosphinepalladium) acetateRelated Search:

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  • Catalysis and Inorganic Chemistry
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  • Pd (Palladium) Compounds
  • Metal Complexes
  • Classes of Metal Compounds
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  • Transition Metal Compounds
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  • Classes of Metal Compounds
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