ChemicalBook > CAS DataBase List > (2-BROMO-6-FLUOROPHENYL)METHANOL

(2-BROMO-6-FLUOROPHENYL)METHANOL

Uses

Product Name: (2-BROMO-6-FLUOROPHENYL)METHANOL
CAS No.: 261723-33-5
Chemical Name: (2-BROMO-6-FLUOROPHENYL)METHANOL
Synonyms: 2-Bromo-6-fluorobenzyl alcohol;6-Bromo-2-fluorobenzyl alcohol;2-bromo-6-fluoroBenzenemethanol;(2-BROMO-6-FLUOROPHENYL)METHANOL;BenzeneMethanol, 2-broMo-6-fluoro-
CBNumber: CB62449432
Molecular Formula: C7H6BrFO
Formula Weight: 205.02
MOL File: 261723-33-5.mol

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(2-BROMO-6-FLUOROPHENYL)METHANOL Property

Melting point:: 40-60°
Boiling point:: 256.7±25.0 °C(Predicted)
Density: 1.658±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 13.47±0.10(Predicted)
form: solid
color: White
InChI: InChI=1S/C7H6BrFO/c8-6-2-1-3-7(9)5(6)4-10/h1-3,10H,4H2
InChIKey: HHGJENWYHVFPSA-UHFFFAOYSA-N
SMILES: C1(CO)=C(F)C=CC=C1Br

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Safety

HS Code: 2906290090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: B692105
Product name: 2-Bromo-6-fluorobenzylalcohol
Packaging: 500mg
Price: $65
Updated: 2021/12/16

TRC

Product number: B692105
Product name: 2-Bromo-6-fluorobenzylalcohol
Packaging: 100mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2701-B-01
Product name: 2-Bromo-6-fluorobenzyl alcohol
Packaging: 5G
Price: $48
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0036852
Product name: (2-BROMO-6-FLUOROPHENYL)METHANOL
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

ChemScene

Product number: CS-W006374
Product name: (2-Bromo-6-fluorophenyl)methanol
Purity: 99.86%
Packaging: 10g
Price: $67
Updated: 2021/12/16

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(2-BROMO-6-FLUOROPHENYL)METHANOL Chemical Properties,Usage,Production

Uses

2-Bromo-6-fluorobenzyl alcohol is an important pharmaceutical intermediate.

Synthesis

360575-28-6

261723-33-5

General procedure for the synthesis of 2-fluoro-6-bromobenzenemethanol from 2-bromo-6-fluorobenzaldehyde: Sodium borohydride (284 g, 7.93 mol) was added batchwise to a solution of 2-bromo-6-fluorobenzaldehyde (1.60 kg, 7.91 mol) in methanol (14 L) at 0 °C, with a controlled rate of addition to regulate exothermic and gas production. After 15 minutes of reaction, the reaction was quenched with water (500 mL) and the reaction mixture was subsequently concentrated to give a yellow oil. The oil was dissolved in ethyl acetate (6L) and washed with (3L) water. The aqueous layer was back-extracted with ethyl acetate (1L). The organic phases were combined, washed with brine (2L), dried over anhydrous sodium sulfate, filtered and concentrated to give 2-fluoro-6-bromobenzenemethanol as an orange oil (1614 g, 100%). The product was characterized by 1H NMR (CDCl3): δ 7.40 (d, 1H), 7.18 (m, 1H), 7.07 (t, 1H), 4.86 (s, 2H).

References

[1] Patent: US2009/163472, 2009, A1. Location in patent: Page/Page column 18
[2] Patent: US2011/65727, 2011, A1. Location in patent: Page/Page column 16
[3] Patent: US2011/65699, 2011, A1. Location in patent: Page/Page column 14
[4] Advanced Synthesis and Catalysis, 2014, vol. 356, # 16, p. 3415 - 3421

(2-BROMO-6-FLUOROPHENYL)METHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(2-BROMO-6-FLUOROPHENYL)METHANOL Suppliers

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View Lastest Price from (2-BROMO-6-FLUOROPHENYL)METHANOL manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 2-Bromo-6-fluorobenzyl alcohol 261723-33-5
Price: US $0.00-0.00/KG
Min. Order: 10mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-17

Hangzhou ICH Biofarm Co., Ltd

Product: 2-Bromo-6-fluorobenzyl alcohol 261723-33-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 2000kg
Release date: 2023-06-09

Henan Bao Enluo International TradeCo.，LTD

Product: (2-BROMO-6-FLUOROPHENYL)METHANOL 261723-33-5
Price: US $20.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 50000tons
Release date: 2023-08-08

261723-33-5, (2-BROMO-6-FLUOROPHENYL)METHANOLRelated Search:

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261723-33-5