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3-Bromopyridine-4-methanol

Product Name
3-Bromopyridine-4-methanol
CAS No.
146679-66-5
Chemical Name
3-Bromopyridine-4-methanol
Synonyms
METHYL 6-BROMOPYRA...;(3-Bromopyridin-4-yl);3-Bromo-4-pyridinemethanol;3-Bromopyridine-4-methanol;(3-Bromo-4-pyridyl)methanol;4-PyridineMethanol, 3-broMo-;(3-Bromo-4-pyridinyl)methanol;3-Bromo-4-(hydroxymethyl)pyridine;3-Bromopyridine-4-methanol ISO 9001：2015 REACH;β-D-Ribofuranoside,methyl5-deoxy-2,3-O-(5-methylethylidene)-
CBNumber
CB62499442
Molecular Formula
C6H6BrNO
Formula Weight
188.02
MOL File
146679-66-5.mol
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3-Bromopyridine-4-methanol Property

Boiling point:
287.1±25.0 °C(Predicted)
Density 
1.668±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
pka
12.72±0.10(Predicted)
Appearance
Off-white to light yellow Solid
InChI
InChI=1S/C6H6BrNO/c7-6-3-8-2-1-5(6)4-9/h1-3,9H,4H2
InChIKey
LQBUZBOVEZBDEB-UHFFFAOYSA-N
SMILES
C1=NC=CC(CO)=C1Br
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Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
MNO000077
Product name
(3-Bromo-4-pyridyl)methanol
Purity
Aldrich
Packaging
1g
Price
$185
Updated
2025/07/31
TRC
Product number
B698870
Product name
(3-Bromopyridin-4-yl)methanol
Packaging
500mg
Price
$85
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB140387
Product name
(3-Bromopyridin-4-yl)methanol
Packaging
1g
Price
$91
Updated
2021/12/16
Apolloscientific
Product number
OR959577
Product name
(3-Bromopyridin-4-yl)methanol
Purity
98%
Packaging
1g
Price
$100
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
B12248
Product name
3-Bromo-4-(hydroxymethyl)pyridine
Purity
98%
Packaging
5g
Price
$130
Updated
2021/12/16
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3-Bromopyridine-4-methanol Chemical Properties,Usage,Production

Synthesis

70201-43-3

146679-66-5

General procedure for the synthesis of 3-bromopyridine-4-methanol from 3-bromopyridine-4-aldehyde: To a solution of 3-bromo-4-pyridinecarboxaldehyde (3.0 g, 16.2 mmol) in anhydrous methanol (40 mL) was slowly added NaBH4 (0.736 g, 19.5 mmol) at 0 °C. The reaction mixture was stirred continuously at 0 °C for 2 h under nitrogen protection. After completion of the reaction, the solvent was removed by distillation under reduced pressure. To the residue, water and ethyl acetate were added for extraction, and the organic layer was separated and washed with distilled water, dried over anhydrous Na2SO4, and finally concentrated under reduced pressure to obtain the target product 3-bromopyridine-4-methanol (3.021 g, 100% yield) as a white powder. The structure of the product was determined by 1H NMR (CDCl3, 300 MHz, 298K, δ ppm): 8.61 (s, 1H), 8.51 (d, 1H, J = 4.8 Hz), 7.55 (d, 1H, J = 4.8 Hz), 4.76 (s, 2H), 2.89 (s, 1H); 13C NMR (CDCl3, 75.5MHz, 298K, δ ppm) 298K, δ ppm): 151.14, 149.45, 148.54, 122.47, 119.90, 63.47; GC/MS (m/z): 188; IR (KBr, v, cm-1): 3152, 2894, 2829, 1593, 1447, 1401, 1333, 1223, 1170. 1070, 1024, 834, 705, 599 Confirmed.

References

[1] Patent: EP2759536, 2014, A1. Location in patent: Paragraph 0067; 0068
[2] Patent: WO2014/114742, 2014, A1. Location in patent: Page/Page column 25
[3] Patent: WO2015/25172, 2015, A1. Location in patent: Page/Page column 90
[4] Journal of Medicinal Chemistry, 2015, vol. 58, # 20, p. 8309 - 8313
[5] Organic Letters, 2008, vol. 10, # 13, p. 2701 - 2704

3-Bromopyridine-4-methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Bromopyridine-4-methanol Suppliers

China 113 Germany 1 India 1 Switzerland 1 United Kingdom 2 United States 10 Global 128
Block Chemical Technology (Shanghai) Co., LTD
Tel
021-20432219 13918097649
Fax
QQ79021576
Email
li_jinfei@acblock-lab.com
Country
China
ProdList
9673
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Shanghai Rlavie Technology Co., Ltd.
Tel
21-67759270 17717059219
Fax
QQ：1479352695
Email
sales@rlavie.com
Country
China
ProdList
1620
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J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Fax
86-025-86918232
Email
sales@pharmablock.com
Country
China
ProdList
5000
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Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
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Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
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China
ProdList
14101
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Accela ChemBio Co.,Ltd.
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021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
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ZEROSCHEM.CO.,LTD.
Tel
10-61256048 13810278579
Fax
+86 10 61256049
Email
sales@zeroschem.com
Country
China
ProdList
1371
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Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
16075
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
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42934
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View Lastest Price from 3-Bromopyridine-4-methanol manufacturers

Shanghai Rlavie Technology Co ltd
Product
3-Bromo-4-pyridinemethanol 146679-66-5
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
100kgs/month
Release date
2021-11-20
Honest Joy Holdings Limited
Product
(3-bromopyridin-4-yl)methanol 146679-66-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98.1%
Supply Ability
100 tons
Release date
2022-01-26
Dideu Industries Group Limited
Product
3-Bromopyridine-4-methanol 146679-66-5
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-08-23

146679-66-5, 3-Bromopyridine-4-methanolRelated Search:


  • 3-Bromopyridine-4-methanol
  • 3-Bromo-4-pyridinemethanol
  • 3-Bromo-4-(hydroxymethyl)pyridine
  • (3-Bromo-4-pyridyl)methanol
  • 4-PyridineMethanol, 3-broMo-
  • (3-Bromopyridin-4-yl)
  • METHYL 6-BROMOPYRA...
  • 3-Bromopyridine-4-methanol ISO 9001：2015 REACH
  • (3-Bromo-4-pyridinyl)methanol
  • β-D-Ribofuranoside,methyl5-deoxy-2,3-O-(5-methylethylidene)-
  • 146679-66-5