ChemicalBook > CAS DataBase List > Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen]
Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen]
Reaction- Product Name
- Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen]
- CAS No.
- 944450-46-8
- Chemical Name
- Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen]
- Synonyms
- RuCl[(S)-dm-segphos][(S,S)-dpen];RuCl2[(S)-(DM-SEGPHOS)][(S,S)-DPEN];RuCl2[(S)-dm-segphos(regR)][(S,S)-dpen];RuCl2[(S)-dm-segphos(regR)][(S,S)-dpen] RuCl2[(S)-dm-segphos][(S,S)-dpen];Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen];Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen] ;Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos(R)][(S,S)-dpen];[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane:(1S,2S)-1,2-diphenylethane-1,2-diamine:ruthenium(2+):dichloride
- CBNumber
- CB62512473
- Molecular Formula
- C60H60Cl2N2O4P2Ru
- Formula Weight
- 1107.052922
- MOL File
- 944450-46-8.mol
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Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen] Property
- storage temp.
- 2-8°C
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
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Safety
- WGK Germany
- 3
- HS Code
- 2843.90.0000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H360May damage fertility or the unborn child
H371May cause damage to organs
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P314Get medical advice/attention if you feel unwell.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 693200
- Product name
- RuCl2[(S)-(DM-SEGPHOS?)][(S,S)-DPEN]
- Packaging
- 50mg
- Price
- $31
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 693200
- Product name
- RuCl2[(S)-(DM-SEGPHOS?)][(S,S)-DPEN]
- Packaging
- 100mg
- Price
- $58.5
- Updated
- 2023/01/07
TCI Chemical
- Product number
- R0130
- Product name
- RuCl2[(S)-dm-segphos[R]][(S,S)-dpen]
- Packaging
- 200mg
- Price
- $67
- Updated
- 2021/12/16
TCI Chemical
- Product number
- R0130
- Product name
- RuCl2[(S)-dm-segphos[R]][(S,S)-dpen]
- Packaging
- 1g
- Price
- $221
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0229
- Product name
- Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos(R)][(S,S)-dpen]
- Packaging
- 250mg
- Price
- $64
- Updated
- 2024/03/01
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Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen] Chemical Properties,Usage,Production
Reaction
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
Uses
Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen] Preparation Products And Raw materials
Raw materials
Preparation Products
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Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen] Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
944450-46-8, Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} [(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos][(S,S)-dpen] Related Search:
Carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl) aMino]rutheniuM(II), Min.98% Ru-MACHO BH
Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R)-daipen]
Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen]