Reaction
ChemicalBook > CAS DataBase List > (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

Reaction
Product Name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
CAS No.
856407-37-9
Chemical Name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
Synonyms
(R)-SITCP;17ef]phosphocin, min. 97% (R)-SITCP;(R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane;(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd;(R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane;(R)-SITCP,(R)-dimethylene-[7,7′-(1,1′-spiro indan)]-phenylphospholane;(R)-12-phenyl-4,5,6,7,12,13-hexahydro-11H-diindeno[7,1-cd:1',7'-ef]phosphocine;(11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin, 5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)-;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)
CBNumber
CB62526469
Molecular Formula
C25H23P
Formula Weight
354.42
MOL File
856407-37-9.mol
More
Less

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Property

Melting point:
148-149°C
alpha 
+6° (c 0.5, CH2Cl2)
Boiling point:
505.6±50.0 °C(Predicted)
storage temp. 
-20°C, protect from light, stored under nitrogen
form 
solid
color 
white
Sensitive 
air sensitive
More
Less

Hazard and Precautionary Statements (GHS)

More
Less

N-Bromosuccinimide Price

Strem Chemicals
Product number
15-5184
Product name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1,7-ef]phosphocin, min. 97% (R)-SITCP
Packaging
25mg
Price
$108
Updated
2024/03/01
Strem Chemicals
Product number
15-5184
Product name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1,7-ef]phosphocin, min. 97% (R)-SITCP
Packaging
100mg
Price
$320
Updated
2024/03/01
AK Scientific
Product number
2467AQ
Product name
(R)-SITCP
Packaging
50mg
Price
$809.6
Updated
2021/12/16
ChemScene
Product number
CS-0037625
Product name
(R)-SITCP
Purity
≥97.0%
Packaging
25mg
Price
$110
Updated
2021/12/16
ChemScene
Product number
CS-0037625
Product name
(R)-SITCP
Purity
≥97.0%
Packaging
50mg
Price
$210
Updated
2021/12/16
More
Less

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Chemical Properties,Usage,Production

Reaction

  1. Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
  2. Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
  3. Catalytic, enantioselective carbon-oxygen bond formation – phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
  4. Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Suppliers

China 28 United States 2 Global 30
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
T&W GROUP
Tel
021-61551611 13296011611
Fax
＋86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
13350
Advantage
58
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
3397
Advantage
58
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2280
Advantage
58
Greenherbs Science and Technology Development Co., Ltd.
Tel
010-61136123
Fax
+86 (10) 8857-9127
Email
pub02@greenherbs.com.cn
Country
China
ProdList
4049
Advantage
58
Aikon International Limited
Tel
025-66061636 18013972705
Fax
(3)02557626880
Email
qqyang@aikonchem.com
Country
China
ProdList
15814
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901 18018851262;
Email
420970979@qq.com
Country
China
ProdList
5894
Advantage
58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
Email
sales@rrkchem.com
Country
China
ProdList
57422
Advantage
58

856407-37-9, (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCPRelated Search:

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aS)- (9CI)

  • (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
  • 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)
  • (R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane
  • (11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin
  • (R)-SITCP
  • (R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane
  • (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd
  • 17ef]phosphocin, min. 97% (R)-SITCP
  • 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin, 5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)-
  • (R)-SITCP,(R)-dimethylene-[7,7′-(1,1′-spiro indan)]-phenylphospholane
  • (R)-12-phenyl-4,5,6,7,12,13-hexahydro-11H-diindeno[7,1-cd:1',7'-ef]phosphocine
  • 856407-37-9
  • C25H23P
  • Chiral Phosphine
  • Chiral Spiro Ligand