Copper(II) phthalocyanine

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Copper(II) phthalocyanine

Product Name: Copper(II) phthalocyanine
CAS No.: 147-14-8
Chemical Name: Copper(II) phthalocyanine
Synonyms: CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue
CBNumber: CB6255035
Molecular Formula: C32H16CuN8
Formula Weight: 576.07
MOL File: 147-14-8.mol

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Copper(II) phthalocyanine Property

Melting point:: 600°C (dec.)
Density: 1.62[at 20℃]
storage temp.: Inert atmosphere,Room Temperature
solubility: insoluble in H2O, ethanol; soluble in concHSO 4
Colour Index: 74160
form: Fine Crystalline Powder
color: Dark blue
Odor: odorless
Water Solubility: <0.1 g/100 mL at 20 ºC
λmax: 602nm(CHCl3)(lit.)
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Merck: 14,2520
BRN: 4121848
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey: XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP: -1 at 23℃
NIST Chemistry Reference: Copper phthalocyanine(147-14-8)
EPA Substance Registry System: C.I. Pigment Blue 15 (147-14-8)
Absorption: λmax 678 nm (DMF)

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Safety

Safety Statements: 22-24/25
WGK Germany: -
RTECS: GL8510000
TSCA: Yes
HS Code: 32041300
Hazardous Substances Data: 147-14-8(Hazardous Substances Data)
Toxicity: LD50 intraperitoneal in rat: > 3gm/kg

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 252980
Product name: Copper(II) phthalocyanine
Purity: β-form, Dye content 90 %
Packaging: 5g
Price: $34.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 252980
Product name: Copper(II) phthalocyanine
Purity: β-form, Dye content 90 %
Packaging: 25g
Price: $59.3
Updated: 2024/03/01

TCI Chemical

Product number: P0655
Product name: Pigment Blue 15
Packaging: 25g
Price: $64
Updated: 2024/03/01

TCI Chemical

Product number: P1005
Product name: Copper(II) Phthalocyanine (α-form)
Purity: >90.0%(T)
Packaging: 25g
Price: $21
Updated: 2024/03/01

Alfa Aesar

Product number: 043650
Product name: Copper(II) phthalocyanine
Packaging: 10g
Price: $36
Updated: 2024/03/01

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Copper(II) phthalocyanine Chemical Properties,Usage,Production

Description

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

Chemical Properties

dark blue fine crystalline powder

Uses

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

Application

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic–organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

General Description

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10^-4 cm²/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

Flammability and Explosibility

Not classified

Purification Methods

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

Properties and Applications

TEST ITEMS	SPECIFICATION
APPEARANCE	BLUE POWDER
SHADE	REDDISH
HEAT RESISTANCE	300 °C min
LIGHT FASTNESS	7-8
ACID RESISTANCE	5
ALKALI RESISTANCE	5
FASTNESS TO BLEEDING	5
OIL ABSORPTION	40-45%
SPECIFIC SURFACE	29 m ² /g
DENSITY	1.60 g/cm ³
RESIDUE ON 80 MESH	5.0% max
WATER SOLUBLE	1.0% max
VOLATITE 105 °C	1.0% max
TINTING STRENGTH	100-105 %

Toxics Screening Level

The initial threshold screening level (ITSL) for phthalocyanine blue is 21 μg/m3 (annual average).

Copper(II) phthalocyanine Preparation Products And Raw materials

Raw materials

Xylene FUMING SULFURIC ACID Copper(II) chloride dihydrate Ammonium molybdate tetrahydrate Potassium iodide Calcium chloride Chlorine Ammonium molybdate Urea Ammonium chloride Copper(II) chloride dihydrate Copper(I) chloride Phthalic anhydride Hydrochloric acid Sodium hydroxide 1,2,4-Trichlorobenzene Sulfuric acid Zinc stearate

Preparation Products

4923 Spirit Light Fast Ball-pen Blue GR Reactive Turquoise Blue Kn-G Various color alkyd primer Various color amino baking enamel A04-9 POLYSULFONE Alkyd enamel CI Pigment Blue 15:3 (74160) Direct Blue 199 Various color nitrocellulose exterior enamel Q04-2 Amino resin paint Reactive Blue 231 Direct Blue 86 Chromium(III) oxide Reactive Blue 14 Ferro phthalocyanine green Pigment Geen 7 Sulphur Green 14

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View Lastest Price from Copper(II) phthalocyanine manufacturers

Hebei Andu Technology Com.,Ltd

Product: Copper(II) phthalocyanine 147-14-8
Price: US $3.50/kg
Min. Order: 1kg
Purity: ≥99%
Supply Ability: 3000tons/month
Release date: 2024-08-17

Zhejiang Free Trade Zone Violet Trade Co., Ltd.

Product: CuPC 147-14-8
Price: US $0.00/g
Min. Order: 1g
Purity: 99.5%
Supply Ability: 100kgs
Release date: 2021-09-16

Hebei Weibang Biotechnology Co., Ltd

Product: Copper(II) phthalocyanine 147-14-8
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-11-04

147-14-8, Copper(II) phthalocyanineRelated Search:

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phthalocyanine blueB15:0

(29H,31H-phthaL

ocyaninato(2-)-N29,N30,N31,N32)copper

Pigment Blue 15 (purified by sublimation)

calcotonebluegp

ceresbluebhr

chromatexbluebn

ciingrainblue2

cipigmentblue15

congoblueb-4

Copper phthalocyanine,CI 74160

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copper,(29h,31h-phthalocyaninato(2-)-n(sup29),n(sup30),n(sup31),n(sup32)

Copper,[29H,31H-phthalocyaninato(2(-))-N29,N30,N31,N32]-(SP-4-1)-

copperphthalocyanin

copperphthalocyanineblue

cromophtalblue4g

cyanbluebnc55-3745

cyanbluebnf55-3753

cyanbluegt55-3295

cyaninebluebb

CyanineBlueBB,BF,GC,HB,LB

cyaninebluec

cyanpeacockblueg

dainichicyanineblueb

dainichicyaninebluefpg

daltolitefastblueb

duratintblue1001

fastogenblue5110

fastogenblueb

fastoluxblue

fenalacbluebdisp

franconiabluea-4431

graphtolblue2gls

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HelioFastBlueB,BB,BF,BRN,BT,GO,GOT,HB,HG

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lbx5

Monastral blue B

phthaloblue

phthalocyanineblue15

phthalocyaninebluepigment(pigmentblue15:3,15:4)

pigmentblue15:4

PigmentphthalocyanineblueB

PigmentphthalocyanineblueBN

PigmentphthalocyanineblueBS

PigmentphthalocyanineblueBX

PigmentphthalocyanineblueFGX

Copper(II) Phthalocyanine (alpha-form)