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2-BROMO-6-CHLOROBENZYL BROMIDE

Product Name
2-BROMO-6-CHLOROBENZYL BROMIDE
CAS No.
75002-98-1
Chemical Name
2-BROMO-6-CHLOROBENZYL BROMIDE
Synonyms
-3-chlorobenzene;1-Bromo-2-(bromomethyl);2-bromo-6-chlorobromobenzyl;2-BROMO-6-CHLOROBENZYL BROMIDE;2-Bromo-6-chlorobenzyl bromide 97%;1-BroMo-2-(broMoMethyl)-3-chlorobenzene;Benzene, 1-bromo-2-(bromomethyl)-3-chloro-;1-Bromo-2-(bromomethyl)-3-chlorobenzene, 2-Chloro-alpha,6-dibromotoluene
CBNumber
CB6259907
Molecular Formula
C7H5Br2Cl
Formula Weight
284.38
MOL File
Mol file
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2-BROMO-6-CHLOROBENZYL BROMIDE Property

Melting point:
62-64°C
Boiling point:
283.4±25.0 °C(Predicted)
Density 
1.93g/ml
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
Light brown to off-white Solid
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Safety

RIDADR 
UN1759
HazardClass 
8
HS Code 
2903998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Oakwood
Product number
019489
Product name
2-Bromo-6-chlorobenzylbromide
Purity
98%
Packaging
5g
Price
$225
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-D-04
Product name
2-Bromo-6-chlorobenzyl bromide
Purity
97%
Packaging
1g
Price
$240
Updated
2021/12/16
Oakwood
Product number
019489
Product name
2-Bromo-6-chlorobenzylbromide
Purity
98%
Packaging
1g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
1665AC
Product name
1-Bromo-2-(bromomethyl)-3-chlorobenzene
Packaging
250mg
Price
$77
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-D-04
Product name
2-Bromo-6-chlorobenzyl bromide
Purity
97%
Packaging
5G
Price
$600
Updated
2021/12/16
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2-BROMO-6-CHLOROBENZYL BROMIDE Chemical Properties,Usage,Production

Synthesis

62356-27-8

75002-98-1

General procedure for the synthesis of 2-bromo-6-chlorobenzyl bromide (compound [5-2]) from 2-bromo-6-chlorotoluene: 2-bromo-6-chlorotoluene (1.58 g) was dissolved in 15 mL of carbon tetrachloride, and N-bromosuccinimide (1.63 g) and 2,2'-azino-bis (isobutyronitrile) (125 mg) were added. The reaction mixture was heated to reflux for 24 hours. After completion of the reaction, the reaction was quenched with water and the mixture was extracted with chloroform. The organic layers were combined, dried over anhydrous sodium sulfate, filtered and the filtrate concentrated under reduced pressure. The resulting residue was purified by silica gel column chromatography to afford 2-bromo-6-chlorobenzyl bromide (2.16 g) as a white solid.1H-NMR (400 MHz, CDCl3) δ: 7.51 (1H, d, J = 8.1 Hz), 7.37 (1H, d, J = 8.1 Hz), 7.11 (1H, d, J = 8.1 Hz), 4.80 (2H, s) .

References

[1] Organic and Biomolecular Chemistry, 2012, vol. 10, # 31, p. 6404 - 6409
[2] Journal of Medicinal Chemistry, 1981, vol. 24, # 4, p. 382 - 389
[3] Patent: US4259349, 1981, A
[4] Journal of the American Chemical Society, 2008, vol. 130, # 45, p. 15157 - 15166
[5] Journal of the American Chemical Society, 2011, vol. 133, # 24, p. 9282 - 9285

2-BROMO-6-CHLOROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-6-CHLOROBENZYL BROMIDE Suppliers

China 75 India 1 United Kingdom 6 United States 8 Global 90
A.J Chemicals
Tel
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Fax
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Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
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75002-98-1, 2-BROMO-6-CHLOROBENZYL BROMIDERelated Search:


  • 2-Bromo-6-chlorobenzyl bromide 97%
  • 2-BROMO-6-CHLOROBENZYL BROMIDE
  • 1-BroMo-2-(broMoMethyl)-3-chlorobenzene
  • 1-Bromo-2-(bromomethyl)-3-chlorobenzene, 2-Chloro-alpha,6-dibromotoluene
  • 1-Bromo-2-(bromomethyl)
  • Benzene, 1-bromo-2-(bromomethyl)-3-chloro-
  • 2-bromo-6-chlorobromobenzyl
  • -3-chlorobenzene
  • 75002-98-1
  • C7H5Br2Cl