ChemicalBook > CAS DataBase List > Methyl 5-(broMoMethyl)-2-fluorobenzoate

Methyl 5-(broMoMethyl)-2-fluorobenzoate

Product Name: Methyl 5-(broMoMethyl)-2-fluorobenzoate
CAS No.: 709-45-5
Chemical Name: Methyl 5-(broMoMethyl)-2-fluorobenzoate
Synonyms: Methyl 5-(broMoMethyl)-2-fluorobenzoate;5-Bromomethyl-2-fluoro-benzoic acid methyl ester;5-(bromomethyl)-2-fluoro-methylester benzoic acid;Benzoic acid, 5-(bromomethyl)-2-fluoro-, methyl ester
CBNumber: CB62648514
Molecular Formula: C9H8BrFO2
Formula Weight: 247.06
MOL File: 709-45-5.mol

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Methyl 5-(broMoMethyl)-2-fluorobenzoate Property

Boiling point:: 304.0±37.0 °C(Predicted)
Density: 1.534±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to off-white Solid

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

SynQuest Laboratories

Product number: 2723-B-22
Product name: Methyl 5-(bromomethyl)-2-fluorobenzoate
Purity: 95%
Packaging: 250mg
Price: $202
Updated: 2021/12/16

AK Scientific

Product number: 4457DA
Product name: Methyl5-(bromomethyl)-2-fluorobenzoate
Packaging: 1g
Price: $321
Updated: 2021/12/16

Ambeed

Product number: A192839
Product name: Methyl5-(bromomethyl)-2-fluorobenzoate
Purity: 95%
Packaging: 100mg
Price: $50
Updated: 2021/12/16

Aaron Chemicals

Product number: AR005QQ2
Product name: Benzoicacid,5-(bromomethyl)-2-fluoro-,methylester
Purity: 95%
Packaging: 100mg
Price: $56
Updated: 2021/12/16

Ambeed

Product number: A192839
Product name: Methyl5-(bromomethyl)-2-fluorobenzoate
Purity: 95%
Packaging: 250mg
Price: $77
Updated: 2021/12/16

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Methyl 5-(broMoMethyl)-2-fluorobenzoate Chemical Properties,Usage,Production

Synthesis

816449-70-4

709-45-5

Preparation of methyl 5-(bromomethyl)-2-fluorobenzoate (3): methyl 2-fluoro-5-(hydroxymethyl)benzoate (2) (5 g, 27.17 mmol, 1 eq.) was dissolved in anhydrous dichloromethane (50 mL) followed by addition of phosphorus tribromide (2.19 g, 8.12 mmol, 0.3 eq.). The reaction mixture was stirred at room temperature for 3 hours. Upon completion of the reaction, the reaction was quenched with saturated sodium bicarbonate solution and extracted with dichloromethane (3 x 100 mL). The organic phases were combined, washed sequentially with water (3 x 30 mL) and brine (1 x 30 mL), dried over anhydrous sodium sulfate, filtered and concentrated to afford methyl 5-(bromomethyl)-2-fluorobenzoate (3) (4.8 g, 71% yield) as an off-white solid.

References

[1] Patent: WO2016/16316, 2016, A1. Location in patent: Page/Page column 226; 227; 354; 355

Methyl 5-(broMoMethyl)-2-fluorobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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709-45-5, Methyl 5-(broMoMethyl)-2-fluorobenzoateRelated Search:

Methyl 5-(broMoMethyl)-2-fluorobenzoate

5-Bromomethyl-2-fluoro-benzoic acid methyl ester

5-(bromomethyl)-2-fluoro-methylester benzoic acid

Benzoic acid, 5-(bromomethyl)-2-fluoro-, methyl ester

709-45-5