Methyl 4-Methyl-3-(trifluoroMethyl)benzoate
- Product Name
- Methyl 4-Methyl-3-(trifluoroMethyl)benzoate
- CAS No.
- 116419-94-4
- Chemical Name
- Methyl 4-Methyl-3-(trifluoroMethyl)benzoate
- Synonyms
- 131250;Methyl 4-methyl-3-trifluorobenzoate;Methyl 4-Methyl-3-(trifluoroMethyl)benzoate;4-methyl-3-(trifluoromethyl)benzoic acid methyl ester;Methyl 4-methyl-3-(trifluoromethyl)benzoate - [M54015];Benzoic acid, 4-methyl-3-(trifluoromethyl)-, methyl ester
- CBNumber
- CB62658991
- Molecular Formula
- C10H9F3O2
- Formula Weight
- 218.17
- MOL File
- 116419-94-4.mol
Methyl 4-Methyl-3-(trifluoroMethyl)benzoate Property
- Boiling point:
- 229.7±40.0 °C(Predicted)
- Density
- 1.231±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M354453
- Product name
- Methyl4-Methyl-3-(trifluoromethyl)benzoate
- Packaging
- 250mg
- Price
- $310
- Updated
- 2021/12/16
- Product number
- 133380
- Product name
- Methyl4-methyl-3-(trifluoromethyl)benzoate
- Purity
- 97%
- Packaging
- 1g
- Price
- $357
- Updated
- 2021/12/16
- Product number
- PC48380
- Product name
- Methyl 4-methyl-3-(trifluoromethyl)benzoate
- Packaging
- 250mg
- Price
- $77
- Updated
- 2021/12/16
- Product number
- 2823-3-18
- Product name
- Methyl 4-methyl-3-(trifluoromethyl)benzoate
- Purity
- 97%
- Packaging
- 250mg
- Price
- $92
- Updated
- 2021/12/16
- Product number
- 133380
- Product name
- Methyl4-methyl-3-(trifluoromethyl)benzoate
- Purity
- 97%
- Packaging
- 5g
- Price
- $1224
- Updated
- 2021/12/16
Methyl 4-Methyl-3-(trifluoroMethyl)benzoate Chemical Properties,Usage,Production
Synthesis
74-88-4
116419-94-4
General procedure for the synthesis of methyl 4-methyl-3-(trifluoromethyl)benzoate from iodomethane: Potassium hydroxide (KOH, 84 mg, 1.5 mmol) was dissolved in dimethylsulfoxide (DMSO, 5 mL) and allowed to stand for 30 min at 25 °C. Subsequently, a solution of 4-methyl-3-(trifluoromethyl)benzoic acid (306 mg, 1.5 mmol) in DMSO (5 mL) was added to the above slurry and the resulting mixture was stirred for 15 min. Next, iodomethane (426 mg, 3 mmol) was added and the reaction mixture was stirred at 25 °C for 2 hours. After completion of the reaction, the reaction was quenched with water. The reaction mixture was extracted with ethyl acetate (EtOAc) and the organic layer was washed with saturated sodium chloride (NaCl) solution and dried with anhydrous sodium sulfate (Na2SO4). The organic solvent was removed by concentration under reduced pressure to give methyl 4-methyl-3-(trifluoromethyl)benzoate as an oil (327 mg, 100% yield). Nuclear magnetic resonance hydrogen spectroscopy (1H NMR) data: δ 8.10 (m, 2H), 7.60 (s, 1H), 3.86 (s, 3H), 2.45 (s, 3H); mass spectrum (m/z): 218.
References
[1] Patent: WO2006/67446, 2006, A1. Location in patent: Page/Page column 130
[2] Patent: WO2006/79791, 2006, A1. Location in patent: Page/Page column 39
[3] Patent: WO2007/71963, 2007, A2. Location in patent: Page/Page column 56
Methyl 4-Methyl-3-(trifluoroMethyl)benzoate Preparation Products And Raw materials
Raw materials
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