ALLYL PHENYL SULFOXIDE
- Product Name
- ALLYL PHENYL SULFOXIDE
- CAS No.
- 19093-37-9
- Chemical Name
- ALLYL PHENYL SULFOXIDE
- Synonyms
- Einecs 242-811-4;Phenyl allyl sulfoxide;(Allylsulfinyl)benzene;ALLYL PHENYL SULFOXIDE;(allylsulphinyl)benzene;(2-Propenylsulfinyl)benzene;Phenyl (2-propenyl) sulfoxide;ALLYL PHENYL SULFOXIDE, TECH.;Benzene, (2-propen-1-ylsulfinyl)-
- CBNumber
- CB6268897
- Molecular Formula
- C9H10OS
- Formula Weight
- 166.24
- MOL File
- 19093-37-9.mol
ALLYL PHENYL SULFOXIDE Property
- Boiling point:
- 85 °C0.3 mm Hg(lit.)
- Density
- 1.122 g/mL at 20 °C(lit.)
- refractive index
- n20/D 1.578
- solubility
- sparingly soluble hexane; sol most other organic solvents
ALLYL PHENYL SULFOXIDE Chemical Properties,Usage,Production
Uses
Allyl Phenyl Sulfoxide is use in: allylic sulfoxides undergo allylic rearrangement to form sulfenate esters, allowing the generation of allylic alcohols; metalated derivatives serve as ambident nucleophiles; precursors to Pummerer intermediates.
Synthesis Reference(s)
Synthesis, p. 815, 1983 DOI: 10.1055/s-1983-30526
Tetrahedron Letters, 35, p. 1413, 1994 DOI: 10.1016/S0040-4039(00)76232-0
Synthesis
Oxidation of Allyl Phenyl Sulfide in dichloromethane with m-Chloroperbenzoic Acid acid (1.2 equiv) added slowly as a solution in dichloromethane at -70 °C affords the sulfoxide in high yields with minimal over-oxidation to the sulfone. The m-chlorobenzoic acid formed may be removed simply by filtration. Other oxidizing agents such as Sodium Bromite3 and Trifluoroperacetic Acid4 afford the sulfoxide in yields greater than 80% and are also highly selective.
storage
No special precautions are required. The sulfoxide may be handled normally at the bench for general weighing and transferring. However, for maximum shelf-life it is recommended that it be stored at 4 °C in a sealed vessel with exclusion of oxygen and moisture.
ALLYL PHENYL SULFOXIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ALLYL PHENYL SULFOXIDE manufacturers
- Product
- ALLYL PHENYL SULFOXIDE 19093-37-9
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2020-03-04