ChemicalBook > CAS DataBase List > Allyl phenyl sulfone
Allyl phenyl sulfone
- Product Name
- Allyl phenyl sulfone
- CAS No.
- 16212-05-8
- Chemical Name
- Allyl phenyl sulfone
- Synonyms
- Allyl Phenyl sulone;ALLYLSULFONYLBENZENE;ALLYL PHENYL SULFONE;sulfone, allyl phenyl;Phenyl allyl sulfone.;ALLYL PHENYL SULPHONE;(allylsulphonyl)benzene;Allyl phenyl sulfone,98%;Allyl Phenyl Sulfone >Phenyl 2-propenyl sulfone
- CBNumber
- CB5189995
- Molecular Formula
- C9H10O2S
- Formula Weight
- 182.24
- MOL File
- 16212-05-8.mol
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Allyl phenyl sulfone Property
- Boiling point:
- 110-113 °C/0.5 mmHg (lit.)
- Density
- 1.189 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.548(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- form
- clear liquid
- color
- Colorless to Orange to Green
- Water Solubility
- insol water; sol most organic solvents.
- Sensitive
- Light Sensitive
- BRN
- 1863561
- InChIKey
- KYPIULIVYSQNNT-UHFFFAOYSA-N
- CAS DataBase Reference
- 16212-05-8(CAS DataBase Reference)
- EPA Substance Registry System
- Benzene, (2-propenylsulfonyl)- (16212-05-8)
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- RTECS
- WR2400000
- F
- 8-10
- TSCA
- T
- HazardClass
- IRRITANT
- HS Code
- 2930909899
- Toxicity
- mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02689,
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 06061
- Product name
- Allyl phenyl sulfone
- Purity
- purum, ≥98.0% (GC)
- Packaging
- 50ml
- Price
- $439
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 06061
- Product name
- Allyl phenyl sulfone
- Purity
- purum, ≥98.0% (GC)
- Packaging
- 10ml
- Price
- $125
- Updated
- 2023/06/20
TCI Chemical
- Product number
- A1444
- Product name
- Allyl Phenyl Sulfone
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $64
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A10401
- Product name
- Allyl phenyl sulfone, 98%
- Packaging
- 5g
- Price
- $49.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A10401
- Product name
- Allyl phenyl sulfone, 98%
- Packaging
- 25g
- Price
- $156.65
- Updated
- 2024/03/01
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Allyl phenyl sulfone Chemical Properties,Usage,Production
Chemical Properties
CLEAR COLOURLESS TO FAINTLY YELLOW LIQUID
Uses
Possible usages of allyl phenyl sulfone:
- It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
- It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
- It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.
Reactivity Profile
Allyl phenyl sulfone could be used as metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent[1].
Synthesis
The Preparative Method of Allyl phenyl sulfone: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure is most straightforward and avoids the use of strong-smelling thiols.
References
1. (a) Magnus, P. D. T 1977, 33, 2019. (b) Block, E. Reactions of Organosulfur Compounds; Academic Press: New York, 1978. (c) Biellmann, J.-F.; Ducep, J.-B. OR 1982, 27, 1.
2. Otto, R. LA 1894, 283, 18; Cope, A. C.; Morrison, D. E.; Field, L. JACS 1950, 72, 59. Vennstra, G. E.; Zwaneburg, B. S 1975, 519.
Allyl phenyl sulfone Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Allyl phenyl sulfone manufacturers
Career Henan Chemical Co
- Product
- Allyl phenyl sulfone 16212-05-8
- Price
- US $6.60/KG
- Min. Order
- 500g
- Purity
- 98%
- Supply Ability
- 1kg, 50kg, 100kg
- Release date
- 2019-12-25
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