Allyl phenyl sulfone

Product Name: Allyl phenyl sulfone
CAS No.: 16212-05-8
Chemical Name: Allyl phenyl sulfone
Synonyms: Allyl Phenyl sulone;ALLYLSULFONYLBENZENE;ALLYL PHENYL SULFONE;sulfone, allyl phenyl;Phenyl allyl sulfone.;ALLYL PHENYL SULPHONE;(allylsulphonyl)benzene;Allyl phenyl sulfone,98%;Allyl Phenyl Sulfone >Phenyl 2-propenyl sulfone
CBNumber: CB5189995
Molecular Formula: C9H10O2S
Formula Weight: 182.24
MOL File: 16212-05-8.mol

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Allyl phenyl sulfone Property

Boiling point:: 110-113 °C/0.5 mmHg (lit.)
Density: 1.189 g/mL at 25 °C (lit.)
refractive index: n20/D 1.548(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
form: clear liquid
color: Colorless to Orange to Green
Water Solubility: insol water; sol most organic solvents.
Sensitive: Light Sensitive
BRN: 1863561
InChIKey: KYPIULIVYSQNNT-UHFFFAOYSA-N
CAS DataBase Reference: 16212-05-8(CAS DataBase Reference)
EPA Substance Registry System: Benzene, (2-propenylsulfonyl)- (16212-05-8)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
RTECS: WR2400000
F: 8-10
TSCA: T
HazardClass: IRRITANT
HS Code: 2930909899
Toxicity: mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02689,

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 06061
Product name: Allyl phenyl sulfone
Purity: purum, ≥98.0% (GC)
Packaging: 50ml
Price: $439
Updated: 2024/03/01

Sigma-Aldrich

Product number: 06061
Product name: Allyl phenyl sulfone
Purity: purum, ≥98.0% (GC)
Packaging: 10ml
Price: $125
Updated: 2023/06/20

TCI Chemical

Product number: A1444
Product name: Allyl Phenyl Sulfone
Purity: >95.0%(GC)
Packaging: 5g
Price: $64
Updated: 2024/03/01

Alfa Aesar

Product number: A10401
Product name: Allyl phenyl sulfone, 98%
Packaging: 5g
Price: $49.65
Updated: 2024/03/01

Alfa Aesar

Product number: A10401
Product name: Allyl phenyl sulfone, 98%
Packaging: 25g
Price: $156.65
Updated: 2024/03/01

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Allyl phenyl sulfone Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO FAINTLY YELLOW LIQUID

Uses

Possible usages of allyl phenyl sulfone:

It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Reactivity Profile

Allyl phenyl sulfone could be used as metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent[1].

Synthesis

The Preparative Method of Allyl phenyl sulfone: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure is most straightforward and avoids the use of strong-smelling thiols.

References

1. (a) Magnus, P. D. T 1977, 33, 2019. (b) Block, E. Reactions of Organosulfur Compounds; Academic Press: New York, 1978. (c) Biellmann, J.-F.; Ducep, J.-B. OR 1982, 27, 1.
2. Otto, R. LA 1894, 283, 18; Cope, A. C.; Morrison, D. E.; Field, L. JACS 1950, 72, 59. Vennstra, G. E.; Zwaneburg, B. S 1975, 519.

Allyl phenyl sulfone Preparation Products And Raw materials

Raw materials

Preparation Products

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Allyl phenyl sulfone Suppliers

Americas 1 Belgium 2 China 79 Europe 1 France 1 Germany 5 India 5 Japan 3 South Korea 1 Switzerland 2 United Kingdom 16 United States 35 Global 151

Alfa Aesar, Thermo Fisher Scientific

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SYNTHON Chemicals GmbH & Co. KG

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Email: synthon@synthon-chemicals.com
Country: Germany
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CHEMOS GmbH & Co. KG

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Email: chemos@chemos.de
Country: Germany
ProdList: 6727
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ABCR GmbH & CO. KG

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Email: info@abcr.de
Country: Germany
ProdList: 6831
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Service Chemical Inc.

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Email: sales@chemos-group.com
Country: Germany
ProdList: 6350
Advantage: 71

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View Lastest Price from Allyl phenyl sulfone manufacturers

Career Henan Chemical Co

Product: Allyl phenyl sulfone 16212-05-8
Price: US $6.60/KG
Min. Order: 500g
Purity: 98%
Supply Ability: 1kg, 50kg, 100kg
Release date: 2019-12-25

16212-05-8, Allyl phenyl sulfoneRelated Search:

Allyl chloride Allyl glycidyl ether Benzene Allyl bromide Tetradifon METHYLSTYRENE Diallylamine Allyl hexanoate PHENYL VALERATE Sodium allylsulfonate Diphenyl ether PHENYL RESIN Allylamine Phenylacetic acid BIS(P-DIMETHYLAMINOSTYRYL)-P-METHYLPHENYLSULFONYLMETHANE DIOXO(PHENYL)(3-PHENYL-2-PROPENYL)-LAMBDA6-SULFANE Allyl phenyl sulfone (4-CHLOROPHENYL)(DIOXO)(3-PHENYL-2-PROPENYL)-LAMBDA6-SULFANE

ALLYL PHENYL SULFONE

ALLYL PHENYL SULPHONE

ALLYLSULFONYLBENZENE

(allylsulphonyl)benzene

Allyl Phenyl sulone

sulfone, allyl phenyl

3-(Phenylsulfonyl)-1-propene

Phenyl (2-propenyl) sulfone

Phenyl 2-propenyl sulfone

Allyl phenyl sulfone,98%

Phenyl allyl sulfone.

(2-propenylsulfonyl)-benzen

Benzene, (2-propenylsulfonyl)-

Prop-2-enylsulfonylbenzene

Allyl Phenyl Sulfone &gt

Benzene, (2-propen-1-ylsulfonyl)-

(Prop-2-ene-1-sulfonyl)-benzene

16212-05-8

16212-05-08

C9H10O2S

C6H5SO2CH2CHCH2

KETONE

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Phenyls & Phenyl-Het

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry

Phenyls & Phenyl-Het

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