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Diallylamine

Product Name
Diallylamine
CAS No.
124-02-7
Chemical Name
Diallylamine
Synonyms
DAA;diallyamine;N,N-Diallylamine;DI-2-PROPENYLAMINE;Diallymine;dillylamine;Dallylamine;DIALLYLAMINE;diallyl-amin;diallylaMate
CBNumber
CB9852983
Molecular Formula
C6H11N
Formula Weight
97.16
MOL File
124-02-7.mol
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Diallylamine Property

Melting point:
-88 °C (lit.)
Boiling point:
111-112 °C (lit.)
Density 
0.787 g/mL at 25 °C (lit.)
vapor density 
3.35 (vs air)
vapor pressure 
18 mm Hg ( 20 °C)
refractive index 
n20/D 1.440(lit.)
Flash point:
60 °F
storage temp. 
Store below +30°C.
solubility 
86g/l
form 
Liquid
pka
pK1:9.29(+1) (25°C,μ=0.02)
color 
Clear colorless to yellow
PH
11.5 (9.7g/l, H2O)
Odor
ammonia-like odor
explosive limit
0.93-14.2%(V)
Water Solubility 
8.6 g/100mL
Sensitive 
Air Sensitive
Merck 
14,2971
BRN 
773718
Dielectric constant
3.7799999999999998
LogP
-0.653 at 23℃
CAS DataBase Reference
124-02-7(CAS DataBase Reference)
NIST Chemistry Reference
2-Propen-1-amine, N-2-propenyl-(124-02-7)
EPA Substance Registry System
Diallylamine (124-02-7)
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Safety

Hazard Codes 
F,T
Risk Statements 
11-20/22-24-34
Safety Statements 
16-26-36/37/39-45-28A
RIDADR 
UN 2359 3/PG 2
WGK Germany 
3
RTECS 
UC6650000
2-10
Autoignition Temperature
273 °C
TSCA 
Yes
HS Code 
2921 19 99
HazardClass 
3
PackingGroup 
II
Hazardous Substances Data
124-02-7(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 0.65 g/kg (Smyth)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D9603
Product name
Diallylamine
Purity
99%
Packaging
100ml
Price
$45.6
Updated
2024/03/01
Sigma-Aldrich
Product number
D9603
Product name
Diallylamine
Purity
99%
Packaging
1l
Price
$170
Updated
2024/03/01
Sigma-Aldrich
Product number
8.03521
Product name
Diallylamine
Purity
for synthesis
Packaging
250ML
Price
$69.9
Updated
2024/03/01
Sigma-Aldrich
Product number
8.03521
Product name
Diallylamine
Purity
for synthesis
Packaging
1L
Price
$172
Updated
2024/03/01
TCI Chemical
Product number
D0069
Product name
Diallylamine
Purity
>98.0%(GC)
Packaging
25mL
Price
$31
Updated
2024/03/01
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Diallylamine Chemical Properties,Usage,Production

Chemical Properties

Diallylamine is a clear colourless to yellow flammable liquid. Soluble in water, alcohol, ether, benzene, with ammonia smell. It can be detected, but it is not unpleasant at 2-9 ppm and is not intolerable at 70 ppm.

Uses

Diallylamine is used as a solvent and in organic synthesis, including crop protection, an auxiliary in paper making, ionic water purifier, polymer monomer, pharmaceutical intermediate, etc. It is also used in the production of N,N-diallyldimethylammonium chloride and N,N-diallyldichloroacetamide, which is used as a safener in the preemergence herbicide EPTC (S-ethyl dipropylthiocarbamate).

Preparation

Diallylamine is synthesized by hydrolysis of diallyl cyanamide. The hydrolysis reaction was carried out in a sulfuric acid medium, and the reflux was moderated for 6h. Yield 80-88%.

General Description

A liquid with a disagreeable odor. Less dense than water. Flash point 70°F. May be toxic by inhalation and skin absorption. Irritates skin and eyes. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

Diallylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Diallylamine is a flammable liquid and a dangerous fire hazard when exposed to heat or flame. Vapors may travel to a source of ignition and flash back, while containers may explode in the heat of a fire. The compound may present a vapor explosion hazard indoors, outdoors, or in sewers. When heated to decomposition, diallylamine emits toxic fumes of NOx (Lewis, 1992).

Toxicology

Diallylamine can cause myocardial degeneration as well as damage to the kidneys and liver. This has been observed in rats and rabbits. Allylamines cause a severe primary fibrosis of the myocardium, The oral application of allylamine in the drinking water over 81–104 days caused a dose-dependent myocardial degeneration in rats.

Safety Profile

Poison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by inhalation. Human systemic effects by inhalation route: eye lachrymation and changes in the trachea or bronchi. A skin and severe eye irritant. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALLYL COMPOUNDS.

Purification Methods

Keep the amine over KOH pellets overnight, decant and distil it from a few pellets of KOH at atmospheric pressure (b 108-111o), then fractionate through a Vigreux column (p 11). [Vliet J Am Chem Soc 46 1307 1924, Org Synth Coll Vol 1 201 1941.] The hydrochloride has m 164-165o (from Me2CO/EtOH). [Butler & Angels J Am Chem Soc 79 3128 1957.]

Diallylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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Diallylamine Suppliers

Zouping Mingxing Chemical Co.,Ltd
Tel
18806491188
Email
lzkysong@163.com
Country
China
ProdList
20
Advantage
58
Shanghai YouPeng Chemical Co. Ltd.
Tel
021-69005955 13701776567
Fax
021-69005775
Email
youpengchem@163.com
Country
China
ProdList
4304
Advantage
56
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2883
Advantage
65
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9984
Advantage
60
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View Lastest Price from Diallylamine manufacturers

Henan Fengda Chemical Co., Ltd
Product
Diallylamine 124-02-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Wuhan Boyuan Import & Export Co., LTD
Product
Diallylamine 124-02-7
Price
US $58.00/kg
Min. Order
1kg
Purity
99.96%
Supply Ability
50ton
Release date
2023-06-12
Wuhan Boyuan Import & Export Co., LTD
Product
Diallylamine 124-02-7
Price
US $20.00-10.00/kg
Min. Order
1kg
Purity
99.60%
Supply Ability
50tons
Release date
2023-12-11

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