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Allyl phenyl sulfone

Product Name
Allyl phenyl sulfone
CAS No.
16212-05-8
Chemical Name
Allyl phenyl sulfone
Synonyms
Allyl Phenyl sulone;ALLYLSULFONYLBENZENE;ALLYL PHENYL SULFONE;sulfone, allyl phenyl;Phenyl allyl sulfone.;ALLYL PHENYL SULPHONE;(allylsulphonyl)benzene;Allyl phenyl sulfone,98%;Allyl Phenyl Sulfone >Phenyl 2-propenyl sulfone
CBNumber
CB5189995
Molecular Formula
C9H10O2S
Formula Weight
182.24
MOL File
16212-05-8.mol
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Allyl phenyl sulfone Property

Boiling point:
110-113 °C/0.5 mmHg (lit.)
Density 
1.189 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.548(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Orange to Green
Water Solubility 
insol water; sol most organic solvents.
Sensitive 
Light Sensitive
BRN 
1863561
InChIKey
KYPIULIVYSQNNT-UHFFFAOYSA-N
CAS DataBase Reference
16212-05-8(CAS DataBase Reference)
EPA Substance Registry System
Benzene, (2-propenylsulfonyl)- (16212-05-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
WR2400000
F 
8-10
TSCA 
T
HazardClass 
IRRITANT
HS Code 
2930909899
Toxicity
mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02689,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
06061
Product name
Allyl phenyl sulfone
Purity
purum, ≥98.0% (GC)
Packaging
50ml
Price
$439
Updated
2024/03/01
Sigma-Aldrich
Product number
06061
Product name
Allyl phenyl sulfone
Purity
purum, ≥98.0% (GC)
Packaging
10ml
Price
$125
Updated
2023/06/20
TCI Chemical
Product number
A1444
Product name
Allyl Phenyl Sulfone
Purity
>95.0%(GC)
Packaging
5g
Price
$64
Updated
2024/03/01
Alfa Aesar
Product number
A10401
Product name
Allyl phenyl sulfone, 98%
Packaging
5g
Price
$49.65
Updated
2024/03/01
Alfa Aesar
Product number
A10401
Product name
Allyl phenyl sulfone, 98%
Packaging
25g
Price
$156.65
Updated
2024/03/01
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Allyl phenyl sulfone Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO FAINTLY YELLOW LIQUID

Uses

Possible usages of allyl phenyl sulfone:

  • It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
  • It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
  • It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Reactivity Profile

Allyl phenyl sulfone could be used as metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent[1].

Synthesis

The Preparative Method of Allyl phenyl sulfone: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure is most straightforward and avoids the use of strong-smelling thiols.

References

1. (a) Magnus, P. D. T 1977, 33, 2019. (b) Block, E. Reactions of Organosulfur Compounds; Academic Press: New York, 1978. (c) Biellmann, J.-F.; Ducep, J.-B. OR 1982, 27, 1.
2. Otto, R. LA 1894, 283, 18; Cope, A. C.; Morrison, D. E.; Field, L. JACS 1950, 72, 59. Vennstra, G. E.; Zwaneburg, B. S 1975, 519.

Allyl phenyl sulfone Preparation Products And Raw materials

Raw materials

Preparation Products

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Allyl phenyl sulfone Suppliers

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View Lastest Price from Allyl phenyl sulfone manufacturers

Career Henan Chemical Co
Product
Allyl phenyl sulfone 16212-05-8
Price
US $6.60/KG
Min. Order
500g
Purity
98%
Supply Ability
1kg, 50kg, 100kg
Release date
2019-12-25

16212-05-8, Allyl phenyl sulfoneRelated Search:

Allyl chloride Allyl glycidyl ether Benzene Allyl bromide Tetradifon METHYLSTYRENE Diallylamine Allyl hexanoate PHENYL VALERATE Sodium allylsulfonate Diphenyl ether PHENYL RESIN Allylamine Phenylacetic acid BIS(P-DIMETHYLAMINOSTYRYL)-P-METHYLPHENYLSULFONYLMETHANE DIOXO(PHENYL)(3-PHENYL-2-PROPENYL)-LAMBDA6-SULFANE Allyl phenyl sulfone (4-CHLOROPHENYL)(DIOXO)(3-PHENYL-2-PROPENYL)-LAMBDA6-SULFANE

  • ALLYL PHENYL SULFONE
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  • ALLYLSULFONYLBENZENE
  • (allylsulphonyl)benzene
  • Allyl Phenyl sulone
  • sulfone, allyl phenyl
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  • Phenyl (2-propenyl) sulfone
  • Phenyl 2-propenyl sulfone
  • Allyl phenyl sulfone,98%
  • Phenyl allyl sulfone.
  • (2-propenylsulfonyl)-benzen
  • Benzene, (2-propenylsulfonyl)-
  • Prop-2-enylsulfonylbenzene
  • Allyl Phenyl Sulfone &gt
  • Benzene, (2-propen-1-ylsulfonyl)-
  • (Prop-2-ene-1-sulfonyl)-benzene
  • 16212-05-8
  • 16212-05-08
  • C9H10O2S
  • C6H5SO2CH2CHCH2
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  • Sulfur Compounds (for Synthesis)
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