4-Iodophenetole
- Product Name
- 4-Iodophenetole
- CAS No.
- 699-08-1
- Chemical Name
- 4-Iodophenetole
- Synonyms
- P-IODOPHENETOLE;4-IODOPHENETOLE;4-Iodophenetole98%;4-Iodophenetole>4-iodobenzyl ether;4-Iodophenetole 98%;4-Iodophenetole,97%;4-ETHOXYIODOBENZENE;4-ethyloxyiodobenzene;4-ETHOXY-4-IODOBENZENE
- CBNumber
- CB6284138
- Molecular Formula
- C8H9IO
- Formula Weight
- 248.06
- MOL File
- 699-08-1.mol
4-Iodophenetole Property
- Melting point:
- 25-28 °C (lit.)
- Boiling point:
- 133-134°C 19mm
- Density
- 1.6502 (estimate)
- refractive index
- 1.5970
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- powder to lump to clear liquid
- color
- White or Colorless to Yellow to Orange
- Sensitive
- Light Sensitive
- BRN
- 2042067
- InChIKey
- WSWPHHNIHLTAHB-UHFFFAOYSA-N
- CAS DataBase Reference
- 699-08-1(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 538744
- Product name
- 4-Iodophenetole
- Purity
- 97%
- Packaging
- 5g
- Price
- $61.4
- Updated
- 2023/01/07
- Product number
- I0525
- Product name
- 4-Iodophenetole
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $30
- Updated
- 2025/07/31
- Product number
- I0525
- Product name
- 4-Iodophenetole
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $85
- Updated
- 2025/07/31
- Product number
- E892265
- Product name
- 1-Ethoxy-4-iodobenzene
- Packaging
- 1g
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 455666
- Product name
- Methyl 5-bromo-2-methylpyridine-3-carboxylate
- Packaging
- 25mg
- Price
- $305
- Updated
- 2021/12/16
4-Iodophenetole Chemical Properties,Usage,Production
Chemical Properties
Off-white low melting solid
Uses
4-Iodophenetole may be used as one of the components in the synthesis of bis(4-ethoxyphenyl)amine.
Uses
Intermediates of Liquid Crystals
Uses
suzuki reaction
Synthesis
74-96-4
540-38-5
699-08-1
The general procedure for the synthesis of 4-iodophenylethyl ether from ethyl bromide and 4-iodophenol was as follows: 233.50 g (1.06 mol) of 4-iodophenol and 42.45 g (1.06 mol) of sodium hydroxide were ground to a powder in a dry mortar and pestle, and the mixture was subsequently transferred to a 1000 mL round-bottomed flask equipped with a magnetic stirrer. To the flask was added 300 mL of ethylene bromide, 15 mL of N,N-dimethylformamide and a catalytic amount of cesium hydroxide. The reaction mixture was stirred at room temperature for 1 hour and then gradually heated to 80 °C and refluxed for about 70 hours. Complete consumption of the reaction starting material was confirmed by thin layer chromatography (TLC). After the reaction solution was cooled to room temperature, the solvent ethyl bromide was removed by evaporation under reduced pressure. Subsequently, appropriate amounts of dichloromethane and water were added sequentially under stirring, the organic layer was separated, dried with anhydrous magnesium sulfate, filtered and concentrated to give 252.43 g of a red oily product in 96.2% yield. The structure of the product was characterized by 1H NMR, IR and HRMS: 1H NMR (400 MHz, (CD3)2SO) δ 7.57 (d, J = 8.8 Hz, 2H), 6.76 (d, J = 8.8 Hz, 2H), 3.98 (q, J = 6.9 Hz, 2H), 1.30 (t, J = 7.0 Hz, 3H); IR (KBr , cm-1) 2979, 2929, 1586, 1486, 1392, 1244, 1047, 820, 630, 507; HRMS (GCT-MS) calculated value C8H9IO [M+] 247.97, measured value 247.9692.
References
[1] Journal of Materials Chemistry B, 2014, vol. 2, # 33, p. 5430 - 5440
[2] Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2015, vol. 150, p. 867 - 878
[3] Journal of Materials Chemistry C, 2014, vol. 2, # 19, p. 3686 - 3694
[4] Chemical Communications, 2009, # 19, p. 2756 - 2758
[5] Journal of Organometallic Chemistry, 1994, vol. 465, # 1-2, p. 97 - 100
4-Iodophenetole Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Iodophenetole manufacturers
- Product
- 4-Iodophenetole 699-08-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- 4-Iodophenetole 699-08-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09
- Product
- 4-Iodophenetole 699-08-1
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2018-08-20