Reaction
ChemicalBook > CAS DataBase List > (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

Reaction
Product Name
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
CAS No.
443965-10-4
Chemical Name
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms
SF120132;(S)-SIPHOS;(R)-SIPHOS;1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE;N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%;N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS;(S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine;(S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
CBNumber
CB6285478
Molecular Formula
C19H20NO2P
Formula Weight
325.34
MOL File
443965-10-4.mol
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Property

Melting point:
95-96°C
Boiling point:
429.6±55.0 °C(Predicted)
alpha 
-502° (c 0.5, CH2Cl2)
storage temp. 
-20°C
pka
2.19±0.20(Predicted)
form 
solid
color 
white
Sensitive 
moisture sensitive
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Safety

HS Code 
29252900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-5151
Product name
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS
Packaging
100mg
Price
$107
Updated
2024/03/01
Strem Chemicals
Product number
15-5151
Product name
(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS
Packaging
500mg
Price
$421
Updated
2024/03/01
ChemScene
Product number
CS-0062402
Product name
(S)-SIPHOS
Packaging
50mg
Price
$88
Updated
2021/12/16
ChemScene
Product number
CS-0062402
Product name
(S)-SIPHOS
Packaging
100mg
Price
$158
Updated
2021/12/16
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties,Usage,Production

Reaction

  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. 


Chemical Properties

White to light yellow powder

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials

Raw materials

Toluene Hexamethylphosphorous triamide (S)-1,1'-SPIROBIINDANE-7,7'-DIOL

Preparation Products

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Suppliers

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443965-10-4, (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINERelated Search:

Indene Dimethylamine (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

  • (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
  • N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE
  • (R)-SIPHOS
  • (S)-SIPHOS
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS
  • N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(S)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite
  • N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%
  • Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)- (9CI)
  • N,N-Dimethylphosphoramidousacid (1S)-(2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl) ester
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e.
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (S)-SIPHOS
  • 1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
  • SF120132
  • Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)-
  • (S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
  • (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine
  • (S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
  • 443965-10-4
  • Chiral Phosphine
  • Chiral Spiro Ligand
  • CPN