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Hexamethylphosphorous triamide

Product Name
Hexamethylphosphorous triamide
CAS No.
1608-26-0
Chemical Name
Hexamethylphosphorous triamide
Synonyms
HMPT;TRIS(DIMETHYLAMINO)PHOSPHINE;Hexamethylphosphorous;(Me2N)3P;Tri(dimethylamino)phosphine;HEXAMETHYL PHOSPHORUS TRIAMIDE;Hexamethylphosphorous triamide ,98%;[bis(dimethylamino)phosphanyl]dimethylamine;NSC 102707;((CH3)2N)3P
CBNumber
CB6140896
Molecular Formula
C6H18N3P
Formula Weight
163.2
MOL File
1608-26-0.mol
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Hexamethylphosphorous triamide Property

Melting point:
-44 °C
Boiling point:
48-50 °C/12 mmHg (lit.)
Density 
0.898 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.463(lit.)
Flash point:
73 °F
storage temp. 
Inert atmosphere,2-8°C
form 
Liquid
pka
8.03±0.70(Predicted)
Specific Gravity
0.8980
color 
Clear colorless to slightly yellow
Water Solubility 
REACTS
Sensitive 
Moisture Sensitive
BRN 
906778
Stability:
Stable. Highly flammable - note low flash point. Incompatible with oxidizing agents.
InChIKey
XVDBWWRIXBMVJV-UHFFFAOYSA-N
CAS DataBase Reference
1608-26-0(CAS DataBase Reference)
NIST Chemistry Reference
Phosphorous triamide, hexamethyl-(1608-26-0)
EPA Substance Registry System
Phosphorous triamide, hexamethyl- (1608-26-0)
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Safety

Hazard Codes 
T,Xi,Xn,F
Risk Statements 
45-46-10-40-36/37/38
Safety Statements 
53-45-36/37/39-26-16-37/39-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
RTECS 
TH3390000
10
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29299000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
393290
Product name
Tris(dimethylamino)phosphine
Purity
97%
Packaging
5ml
Price
$70.4
Updated
2024/03/01
Sigma-Aldrich
Product number
393290
Product name
Tris(dimethylamino)phosphine
Purity
97%
Packaging
25ml
Price
$288
Updated
2024/03/01
TCI Chemical
Product number
T1317
Product name
Tris(dimethylamino)phosphine (may contain precipitate)
Purity
>96.0%(GC)
Packaging
25mL
Price
$302
Updated
2024/03/01
TCI Chemical
Product number
T1317
Product name
Tris(dimethylamino)phosphine (may contain precipitate)
Purity
>96.0%(GC)
Packaging
250mL
Price
$1721
Updated
2024/03/01
Alfa Aesar
Product number
A12571
Product name
Hexamethylphosphorous triamide, 97%
Packaging
5g
Price
$52.65
Updated
2024/03/01
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Hexamethylphosphorous triamide Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

Hexamethylphosphorous triamide can be combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.

Uses

Hexamethylphosphorous triamide can be uesd in suzuki reaction.

Uses

Hexamethylphosphorous triamide can be widely used in industry, with applications such as being a flame retardant for building materials to a phosphorylating agent in synthetic chemistry. It is a classified carcinogen.

Purification Methods

It may contain more than 1% of phosphoric triamide. The yellow oil is first distilled at atmospheric pressure, then under reduced pressure and stored under N2. It is air sensitive, TOXIC, and should not be inhaled. It is absorbed through the skin. [Mark Org Synth Coll Vol V 602 1973, Beilstein 4 IV 274.]

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Hexamethylphosphorous triamide Suppliers

Shaanxi Rock New Materials Co., Ltd.
Tel
917-917-8888777 18691746767
Email
zhaoting@bjrock.com
Country
China
ProdList
300
Advantage
62
Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
349
Advantage
55
Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-022-83946278 13820372920
Fax
022-83945176
Email
sales@creasyn.com
Country
China
ProdList
1003
Advantage
68
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3576
Advantage
66
Bridge Organics
Tel
+1269-649-4200
Fax
+1269-649-0611
Email
ab@bridgeorganics.com
Country
United States
ProdList
163
Advantage
55
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
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View Lastest Price from Hexamethylphosphorous triamide manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
Hexamethylphosphorous triamide 1608-26-0
Price
US $0.00-0.00/g
Min. Order
100g
Purity
98%
Supply Ability
25KG
Release date
2024-03-26
XINGTAI XINGJIU NEW MATERIAL TECHNOLOGY CO., LTD
Product
Hexamethylphosphorous triamide 1608-26-0
Price
US $25.00/KG
Min. Order
1KG
Purity
0.99
Supply Ability
50000kg/month
Release date
2022-01-24
Shaanxi Dideu Medichem Co. Ltd
Product
Hexamethylphosphorous triamide 1608-26-0
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 Tons
Release date
2020-01-14

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