Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate

Product Name: Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
CAS No.: 132705-51-2
Chemical Name: Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
Synonyms: PYBROP;BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE;PYBRBOP;PYBROP(R);PYBROP(TM);PyBroP\(rg;PyBrOP®PyBroP Novabiochem;Bromo-tris-pyrrolidi;Pyrrolidine phosphorus complex
CBNumber: CB5318935
Molecular Formula: C12H24BrF6N3P2
Formula Weight: 466.19
MOL File: 132705-51-2.mol

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Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Property

Melting point:: 100 °C
storage temp.: -20°C
solubility: DMF: 0.4 g/mL, clear
form: Powder
color: White to off-white
Water Solubility: moderately soluble
Sensitive: Moisture Sensitive
BRN: 7845702
Stability:: Moisture Sensitive
InChIKey: CYKRMWNZYOIJCH-UHFFFAOYSA-N
CAS DataBase Reference: 132705-51-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,C
Risk Statements: 36/37/38-34
Safety Statements: 26-36-45-36/37/39-27
WGK Germany: 3
F: 10-21
HS Code: 2933 99 80

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.51010
Product name: PyBroP
Purity: Novabiochem?
Packaging: 25g
Price: $380
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.51010
Product name: PyBroP
Purity: Novabiochem?
Packaging: 100g
Price: $1130
Updated: 2024/03/01

Sigma-Aldrich

Product number: 18565
Product name: Bromotripyrrolidinophosphonium hexafluorophosphate
Purity: ≥95.0% (HPLC)
Packaging: 1g
Price: $11.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 18565
Product name: Bromotripyrrolidinophosphonium hexafluorophosphate
Purity: ≥95.0% (HPLC)
Packaging: 5g
Price: $138
Updated: 2024/03/01

TCI Chemical

Product number: B2680
Product name: Bromotripyrrolidinophosphonium Hexafluorophosphate
Purity: >98.0%(HPLC)(N)
Packaging: 5g
Price: $77
Updated: 2024/03/01

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Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Chemical Properties,Usage,Production

Chemical Properties

white to off-white powder

Uses

A stable reagent for the coupling of N-Methylamino acids in peptide synthesis.

Uses

It can be used as a coupling reagent:

For Suzuki–Miyaura cross-coupling of phenols and arylboronic acids to synthesize biaryls and heterobiaryls.
To functionalize pyrimidines (synthesized from 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) via the Kappe dehydrogenation) by using various nucleophiles.
To synthesize formamidines by coupling with various primary amines and N,N-diisopropylethylamine.

It can also be used as an activating reagent:

For the activation of C-OH bond in tautomerizable heterocycles to form the phosphonium salt which aids the Sonogashira coupling of heterocycles with various alkynes.
For the one–pot activation of C-O bond in phenols and further coupling reaction with phosphine oxide or phosphite to form C-P bonds.

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Suppliers

Americas 1 Belgium 1 China 212 Europe 3 France 1 Germany 5 India 7 Israel 2 Japan 4 South Korea 1 Switzerland 3 United Kingdom 11 United States 44 Global 295

Suzhou Highfine Biotech Co., Ltd

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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ShangHai DEMO Chemical Co.,Ltd

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Energy Chemical

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Wuhan Chemwish Technology Co., Ltd

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View Lastest Price from Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-06

Henan Aochuang Chemical Co.,Ltd.

Product: Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-26

Zhuozhou Wenxi import and Export Co., Ltd

Product: Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

132705-51-2, Bromo-tris-pyrrolidino-phosphonium hexafluorophosphateRelated Search:

Potassium hexafluorophosphate BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) Hexafluorophosphoric acid Lithium hexafluorophosphate Tris(hydroxymethyl)aminomethane BIS-Tris Ammonium hexafluorophosphate Tricine 5-Chloro-1-[bis(dimethylamino)methylene]-1H-benzotriazolium 3-oxide hexafluorophosphate Diphenylphosphoryl azide TRIS(DIETHYLAMINO)PHOSPHINE Hexamethylphosphorous triamide Bromotris(dimethylamino)phosphonium hexafluorophosphate Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Bromine TRIS BUFFER SOLUTION PH 8.5, 1 L bromo-Dragonfly

PYBROP

PYBROP(R)

PYBROP(TM)

BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE

BROMO-TRIS-PYRROLIDINO-PHOSPHONIUM HEXAFLUOROPHOSPHATE

BROMO-TRIS-PYRROLIDINO-PHOSPHONIUM HEXFLUOROPHOSPHATE

Pybrop(Bromo-Tris-PyrrolidinophosphoniumHexafluorophosphate)

PyBroP\(rg

Bromotri(pyrrolidin-1-yl)phosphoniumhexafluorophosphate

Pyrrolidine phosphorus complex

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphat

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate ,97%

Bromotri(1-pyrrolidinyl)phosphonium hexafluorophosphate, 97%

Bromo-tris-pyrrolidi

Bromo-tris-pyrrolidino-phosphoniumhexafluorophpsphate

PYBRBOP

BroMo-tris-pyrrolidino-phosphoniuM hexafluorophosphate, 97% 25GR

BroMotri(pyrrolidin-1-yl)phosphoniuM hexafluorophosphate(V)

Three pyrrolidino phosphoniuM broMide hexafluorophosphate (PYBROP)

BroMotripyrrolidinophosphoniuM hexafluorophosphate, 98%+

Bromotripyrrolidinophosphonium hexafluorophosphate >=95.0% (HPLC)

Bromotripyrrolidinylphosphonium hexafluorophosphate, 97%

PyBrOP&reg

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate≥ 99% (HPLC)

PyBroP Novabiochem

Bromo-tris-pyrrolidinophosphoniumhexafluorophosphate(PyBrop)

Bromotripyrrolidinophosphonium Hexafluorophosphate &gt

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate, 97%, for synthesis

Phosphorus(1+), bromotri-1-pyrrolidinyl-, (T-4)-, hexafluorophosphate(1-) (1:1)

Bromotri(pyrrolidino)phosphonium hexafluorophosphate (PyBrOP)

(T-4)-bromotri-1-pyrrolidinyl-Phosphorus(1+) hexafluorophosphate(1-) (1:1)

PyBroP BroMo-tris-pyrrolidinophosphoniuMhexafluorophosp

Pyrrolyl phosphonium bromide hexafluorophosphate

132705-51-2

C12H24BrN3PPF6

C12H24N3P2BrF6

C12H24BrN3PF6P

C12H24BrF6N3P2

Coupling

Phosphonium/Uronium/Formamidinium

Synthetic Reagents

Peptide

Coupling Reagent

Peptide Coupling Reagents