ChemicalBook > CAS DataBase List > Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
- Product Name
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
- CAS No.
- 132705-51-2
- Chemical Name
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
- Synonyms
- PYBROP;BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE;PYBRBOP;PYBROP(R);PYBROP(TM);PyBroP\(rg;PyBrOP®PyBroP Novabiochem;Bromo-tris-pyrrolidi;Pyrrolidine phosphorus complex
- CBNumber
- CB5318935
- Molecular Formula
- C12H24BrF6N3P2
- Formula Weight
- 466.19
- MOL File
- 132705-51-2.mol
More
Less
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Property
- Melting point:
- 100 °C
- storage temp.
- -20°C
- solubility
- DMF: 0.4 g/mL, clear
- form
- Powder
- color
- White to off-white
- Water Solubility
- moderately soluble
- Sensitive
- Moisture Sensitive
- BRN
- 7845702
- Stability:
- Moisture Sensitive
- InChIKey
- CYKRMWNZYOIJCH-UHFFFAOYSA-N
- CAS DataBase Reference
- 132705-51-2(CAS DataBase Reference)
More
Less
Safety
- Hazard Codes
- Xi,C
- Risk Statements
- 36/37/38-34
- Safety Statements
- 26-36-45-36/37/39-27
- WGK Germany
- 3
- F
- 10-21
- HS Code
- 2933 99 80
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 8.51010
- Product name
- PyBroP
- Purity
- Novabiochem?
- Packaging
- 25g
- Price
- $380
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 8.51010
- Product name
- PyBroP
- Purity
- Novabiochem?
- Packaging
- 100g
- Price
- $1130
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 18565
- Product name
- Bromotripyrrolidinophosphonium hexafluorophosphate
- Purity
- ≥95.0% (HPLC)
- Packaging
- 1g
- Price
- $11.6
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 18565
- Product name
- Bromotripyrrolidinophosphonium hexafluorophosphate
- Purity
- ≥95.0% (HPLC)
- Packaging
- 5g
- Price
- $138
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B2680
- Product name
- Bromotripyrrolidinophosphonium Hexafluorophosphate
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 5g
- Price
- $77
- Updated
- 2024/03/01
More
Less
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Chemical Properties,Usage,Production
Chemical Properties
white to off-white powder
Uses
A stable reagent for the coupling of N-Methylamino acids in peptide synthesis.
Uses
It can be used as a coupling reagent:
- For Suzuki–Miyaura cross-coupling of phenols and arylboronic acids to synthesize biaryls and heterobiaryls.
- To functionalize pyrimidines (synthesized from 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) via the Kappe dehydrogenation) by using various nucleophiles.
- To synthesize formamidines by coupling with various primary amines and N,N-diisopropylethylamine.
It can also be used as an activating reagent:
- For the activation of C-OH bond in tautomerizable heterocycles to form the phosphonium salt which aids the Sonogashira coupling of heterocycles with various alkynes.
- For the one–pot activation of C-O bond in phenols and further coupling reaction with phosphine oxide or phosphite to form C-P bonds.
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Suppliers
More
Less
View Lastest Price from Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate manufacturers
WUHAN FORTUNA CHEMICAL CO., LTD
- Product
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-06
Hebei Lingding Biotechnology Co., Ltd.
- Product
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
- Price
- US $350.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 9000kg/per week
- Release date
- 2021-09-14
Henan Aochuang Chemical Co.,Ltd.
- Product
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-26
132705-51-2, Bromo-tris-pyrrolidino-phosphonium hexafluorophosphateRelated Search:
Potassium hexafluorophosphate
BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)
Hexafluorophosphoric acid
Lithium hexafluorophosphate
Tris(hydroxymethyl)aminomethane
BIS-Tris
Ammonium hexafluorophosphate
Tricine
5-Chloro-1-[bis(dimethylamino)methylene]-1H-benzotriazolium 3-oxide hexafluorophosphate
Diphenylphosphoryl azide
TRIS(DIETHYLAMINO)PHOSPHINE
Hexamethylphosphorous triamide
Bromotris(dimethylamino)phosphonium hexafluorophosphate
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
Bromine
TRIS BUFFER SOLUTION PH 8.5, 1 L
bromo-Dragonfly