ChemicalBook > CAS DataBase List > Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate

Product Name
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
CAS No.
132705-51-2
Chemical Name
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
Synonyms
PYBROP;BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE;PYBRBOP;PYBROP(R);PYBROP(TM);PyBroP\(rg;PyBrOP®PyBroP Novabiochem;Bromo-tris-pyrrolidi;Pyrrolidine phosphorus complex
CBNumber
CB5318935
Molecular Formula
C12H24BrF6N3P2
Formula Weight
466.19
MOL File
132705-51-2.mol
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Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Property

Melting point:
100 °C
storage temp. 
-20°C
solubility 
DMF: 0.4 g/mL, clear
form 
Powder
color 
White to off-white
Water Solubility 
moderately soluble
Sensitive 
Moisture Sensitive
BRN 
7845702
Stability:
Moisture Sensitive
InChIKey
CYKRMWNZYOIJCH-UHFFFAOYSA-N
CAS DataBase Reference
132705-51-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,C
Risk Statements 
36/37/38-34
Safety Statements 
26-36-45-36/37/39-27
WGK Germany 
3
F 
10-21
HS Code 
2933 99 80
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.51010
Product name
PyBroP
Purity
Novabiochem?
Packaging
25g
Price
$380
Updated
2024/03/01
Sigma-Aldrich
Product number
8.51010
Product name
PyBroP
Purity
Novabiochem?
Packaging
100g
Price
$1130
Updated
2024/03/01
Sigma-Aldrich
Product number
18565
Product name
Bromotripyrrolidinophosphonium hexafluorophosphate
Purity
≥95.0% (HPLC)
Packaging
1g
Price
$11.6
Updated
2024/03/01
Sigma-Aldrich
Product number
18565
Product name
Bromotripyrrolidinophosphonium hexafluorophosphate
Purity
≥95.0% (HPLC)
Packaging
5g
Price
$138
Updated
2024/03/01
TCI Chemical
Product number
B2680
Product name
Bromotripyrrolidinophosphonium Hexafluorophosphate
Purity
>98.0%(HPLC)(N)
Packaging
5g
Price
$77
Updated
2024/03/01
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Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Chemical Properties,Usage,Production

Chemical Properties

white to off-white powder

Uses

A stable reagent for the coupling of N-Methylamino acids in peptide synthesis.

Uses

It can be used as a coupling reagent:

  • For Suzuki–Miyaura cross-coupling of phenols and arylboronic acids to synthesize biaryls and heterobiaryls.
  • To functionalize pyrimidines (synthesized from 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) via the Kappe dehydrogenation) by using various nucleophiles.
  • To synthesize formamidines by coupling with various primary amines and N,N-diisopropylethylamine.

It can also be used as an activating reagent:
  • For the activation of C-OH bond in tautomerizable heterocycles to form the phosphonium salt which aids the Sonogashira coupling of heterocycles with various alkynes.
  • For the one–pot activation of C-O bond in phenols and further coupling reaction with phosphine oxide or phosphite to form C-P bonds.

Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Suppliers

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View Lastest Price from Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-06
Henan Aochuang Chemical Co.,Ltd.
Product
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate 132705-51-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10

132705-51-2, Bromo-tris-pyrrolidino-phosphonium hexafluorophosphateRelated Search:

Potassium hexafluorophosphate BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) Hexafluorophosphoric acid Lithium hexafluorophosphate Tris(hydroxymethyl)aminomethane BIS-Tris Ammonium hexafluorophosphate Tricine 5-Chloro-1-[bis(dimethylamino)methylene]-1H-benzotriazolium 3-oxide hexafluorophosphate Diphenylphosphoryl azide TRIS(DIETHYLAMINO)PHOSPHINE Hexamethylphosphorous triamide Bromotris(dimethylamino)phosphonium hexafluorophosphate Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Bromine TRIS BUFFER SOLUTION PH 8.5, 1 L bromo-Dragonfly

  • PYBROP
  • PYBROP(R)
  • PYBROP(TM)
  • BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE
  • BROMO-TRIS-PYRROLIDINO-PHOSPHONIUM HEXAFLUOROPHOSPHATE
  • BROMO-TRIS-PYRROLIDINO-PHOSPHONIUM HEXFLUOROPHOSPHATE
  • Pybrop(Bromo-Tris-PyrrolidinophosphoniumHexafluorophosphate)
  • PyBroP\(rg
  • Bromotri(pyrrolidin-1-yl)phosphoniumhexafluorophosphate
  • Pyrrolidine phosphorus complex
  • Bromo-tris-pyrrolidino-phosphonium hexafluorophosphat
  • Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate ,97%
  • Bromotri(1-pyrrolidinyl)phosphonium hexafluorophosphate, 97%
  • Bromo-tris-pyrrolidi
  • Bromo-tris-pyrrolidino-phosphoniumhexafluorophpsphate
  • PYBRBOP
  • BroMo-tris-pyrrolidino-phosphoniuM hexafluorophosphate, 97% 25GR
  • BroMotri(pyrrolidin-1-yl)phosphoniuM hexafluorophosphate(V)
  • Three pyrrolidino phosphoniuM broMide hexafluorophosphate (PYBROP)
  • BroMotripyrrolidinophosphoniuM hexafluorophosphate, 98%+
  • Bromotripyrrolidinophosphonium hexafluorophosphate >=95.0% (HPLC)
  • Bromotripyrrolidinylphosphonium hexafluorophosphate, 97%
  • PyBrOP&reg
  • Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate≥ 99% (HPLC)
  • PyBroP Novabiochem
  • Bromo-tris-pyrrolidinophosphoniumhexafluorophosphate(PyBrop)
  • Bromotripyrrolidinophosphonium Hexafluorophosphate &gt
  • Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate, 97%, for synthesis
  • Phosphorus(1+), bromotri-1-pyrrolidinyl-, (T-4)-, hexafluorophosphate(1-) (1:1)
  • Bromotri(pyrrolidino)phosphonium hexafluorophosphate (PyBrOP)
  • (T-4)-bromotri-1-pyrrolidinyl-Phosphorus(1+) hexafluorophosphate(1-) (1:1)
  • PyBroP BroMo-tris-pyrrolidinophosphoniuMhexafluorophosp
  • Pyrrolyl phosphonium bromide hexafluorophosphate
  • 132705-51-2
  • C12H24BrN3PPF6
  • C12H24N3P2BrF6
  • C12H24BrN3PF6P
  • C12H24BrF6N3P2
  • Coupling
  • Phosphonium/Uronium/Formamidinium
  • Synthetic Reagents
  • Peptide
  • Coupling Reagent
  • Peptide Coupling Reagents