(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID

Product Name: (4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
CAS No.: 24589-89-7
Chemical Name: (4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
Synonyms: AKOS B005879;(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID;2-(4-bromo-2-formylphenoxy)acetic acid;Acetic acid, 2-(4-bromo-2-formylphenoxy)-;2-(4-bromo-2-methanoyl-phenoxy)ethanoic acid;3-Pyridinecarboxylicacid,2,7-dimethyl-,methylester
CBNumber: CB6291291
Molecular Formula: C9H7BrO4
Formula Weight: 259.05
MOL File: 24589-89-7.mol

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(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Property

Boiling point:: 413.6±30.0 °C(Predicted)
Density: 1.699±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 2.96±0.10(Predicted)

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Safety

Hazard Codes: Xn
Risk Statements: 22
HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific

Product number: 8265AD
Product name: 2-(4-Bromo-2-formylphenoxy)aceticacid
Packaging: 250mg
Price: $126
Updated: 2021/12/16

Matrix Scientific

Product number: 038969
Product name: 2-(4-Bromo-2-formylphenoxy)acetic acid
Packaging: 500mg
Price: $126
Updated: 2021/12/16

AK Scientific

Product number: 8265AD
Product name: 2-(4-Bromo-2-formylphenoxy)aceticacid
Packaging: 1g
Price: $239
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0042550
Product name: 2-(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
Purity: 95.00%
Packaging: 1G
Price: $771.89
Updated: 2021/12/16

Abosyn

Product number: 61-0553
Product name: 2-(4-bromo-2-formylphenoxy)aceticacid
Purity: 95-98%
Packaging: 0.25g
Price: $1350
Updated: 2021/12/16

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(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Chemical Properties,Usage,Production

Synthesis

51336-47-1

24589-89-7

Ethyl (4-bromo-2-formylphenoxy)acetate (60 g, 0.209 mol) was added to a mixture of LiOH (7.5 g, 0.31 mol), THF (250 mL) and water (100 mL) and stirred for 24 h at room temperature. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure and the residue was acidified to pH=2 with 1.5 N HCl. The resulting solid precipitate was filtered and dried to afford (4-bromo-2-formylphenoxy)acetic acid (50 g, 94% yield).

References

[1] Patent: WO2004/7491, 2004, A1. Location in patent: Page 51
[2] Organic Letters, 2015, vol. 17, # 23, p. 5824 - 5827
[3] European Journal of Medicinal Chemistry, 1999, vol. 34, # 12, p. 1061 - 1070

(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Suppliers

China 43 Germany 1 Hungary 1 India 1 United Kingdom 1 United States 10 Global 57

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24589-89-7, (4-BROMO-2-FORMYLPHENOXY)ACETIC ACIDRelated Search:

(4-BROMO-2-CARBAMOYL-PHENOXY)ACETIC ACID (4-BROMO-2-FORMYL-6-METHOXY-PHENOXY)-ACETIC ACID ETHYL ESTER (4-BROMO-2-FORMYLPHENOXY)ACETIC ACID CHEMBRDG-BB 6763869 CHEMBRDG-BB 6702454 AKOS B005891 6-BROMOCHROMONE-2-CARBOXYLIC ACID 6,8-DIBROMOCHROMONE-2-CARBOXYLIC ACID (4-BROMO-2-FORMYL-PHENOXY)-ACETIC ACID TERT-BUTYL ESTER METHYL 6-BROMO-4-OXO-4H-CHROMENE-2-CARBOXYLATE AKOS B028939 METHYL (2,4-DIBROMO-6-CARBAMOYL-PHENOXY)ACETATE METHYL (4-BROMO-2-CARBAMOYL-PHENOXY)ACETATE AKOS B029178 AKOS B029015 6-BROMO-4-OXOCHROMANE-2-CARBOXYLIC ACID AKOS B005993 AKOS B005987

(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID

AKOS B005879

2-(4-bromo-2-formylphenoxy)acetic acid

2-(4-bromo-2-methanoyl-phenoxy)ethanoic acid

Acetic acid, 2-(4-bromo-2-formylphenoxy)-

3-Pyridinecarboxylicacid,2,7-dimethyl-,methylester

24589-89-7

C9H7BrO4