(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
- Product Name
- (4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
- CAS No.
- 24589-89-7
- Chemical Name
- (4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
- Synonyms
- AKOS B005879;(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID;2-(4-bromo-2-formylphenoxy)acetic acid;Acetic acid, 2-(4-bromo-2-formylphenoxy)-;2-(4-bromo-2-methanoyl-phenoxy)ethanoic acid;3-Pyridinecarboxylicacid,2,7-dimethyl-,methylester
- CBNumber
- CB6291291
- Molecular Formula
- C9H7BrO4
- Formula Weight
- 259.05
- MOL File
- 24589-89-7.mol
(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Property
- Boiling point:
- 413.6±30.0 °C(Predicted)
- Density
- 1.699±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 2.96±0.10(Predicted)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 8265AD
- Product name
- 2-(4-Bromo-2-formylphenoxy)aceticacid
- Packaging
- 250mg
- Price
- $126
- Updated
- 2021/12/16
- Product number
- 038969
- Product name
- 2-(4-Bromo-2-formylphenoxy)acetic acid
- Packaging
- 500mg
- Price
- $126
- Updated
- 2021/12/16
- Product number
- 8265AD
- Product name
- 2-(4-Bromo-2-formylphenoxy)aceticacid
- Packaging
- 1g
- Price
- $239
- Updated
- 2021/12/16
- Product number
- HCH0042550
- Product name
- 2-(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $771.89
- Updated
- 2021/12/16
- Product number
- 61-0553
- Product name
- 2-(4-bromo-2-formylphenoxy)aceticacid
- Purity
- 95-98%
- Packaging
- 0.25g
- Price
- $1350
- Updated
- 2021/12/16
(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Chemical Properties,Usage,Production
Synthesis
51336-47-1
24589-89-7
Ethyl (4-bromo-2-formylphenoxy)acetate (60 g, 0.209 mol) was added to a mixture of LiOH (7.5 g, 0.31 mol), THF (250 mL) and water (100 mL) and stirred for 24 h at room temperature. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure and the residue was acidified to pH=2 with 1.5 N HCl. The resulting solid precipitate was filtered and dried to afford (4-bromo-2-formylphenoxy)acetic acid (50 g, 94% yield).
References
[1] Patent: WO2004/7491, 2004, A1. Location in patent: Page 51
[2] Organic Letters, 2015, vol. 17, # 23, p. 5824 - 5827
[3] European Journal of Medicinal Chemistry, 1999, vol. 34, # 12, p. 1061 - 1070
(4-BROMO-2-FORMYLPHENOXY)ACETIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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