ChemicalBook > CAS DataBase List > 1,3-Bis(aminomethyl)benzene

1,3-Bis(aminomethyl)benzene

Product Name
1,3-Bis(aminomethyl)benzene
CAS No.
1477-55-0
Chemical Name
1,3-Bis(aminomethyl)benzene
Synonyms
MXDA;M-XYLYLENEDIAMINE;1,3-PhenylenediMethanaMine;1,3-Benzenedimethanamine;meta-Xylenediamine;MXD;XYLYLENEDIAMINE;M-XYLENE DIAMINE;1,3-di(aminomethyl)benzene;m-phenylenebis(methylamine)
CBNumber
CB6307422
Molecular Formula
C8H12N2
Formula Weight
136.19
MOL File
1477-55-0.mol
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1,3-Bis(aminomethyl)benzene Property

Melting point:
14°C
Boiling point:
265 °C745 mm Hg(lit.)
Density 
1.032 g/mL at 25 °C(lit.)
vapor pressure 
15 mm Hg ( 145 °C)
refractive index 
n20/D 1.571(lit.)
Flash point:
>230 °F
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
pka
9.37±0.10(Predicted)
color 
Clear slightly yellow
Water Solubility 
Miscible
BRN 
1099911
LogP
0.18 at 25℃
CAS DataBase Reference
1477-55-0(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Benzenedimethanamine(1477-55-0)
EPA Substance Registry System
m-Xylylenediamine (1477-55-0)
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Safety

Hazard Codes 
T,C
Risk Statements 
21/22-23-34-43-52/53-20/22
Safety Statements 
26-36/37/39-45-61-28A
RIDADR 
UN 2735 8/PG 2
OEL
Ceiling: 0.1 mg/m3 [skin]
WGK Germany 
2
RTECS 
PF8970000
F 
2-9
HazardClass 
8
PackingGroup 
II
HS Code 
29215900
Hazardous Substances Data
1477-55-0(Hazardous Substances Data)
Toxicity
rabbit,LD50,skin,2gm/kg (2000mg/kg),"Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 5, Pg. 638, 1986.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
X1202
Product name
m-Xylylenediamine
Purity
99%
Packaging
5g
Price
$18.7
Updated
2024/03/01
Sigma-Aldrich
Product number
X1202
Product name
m-Xylylenediamine
Purity
99%
Packaging
100g
Price
$36.6
Updated
2024/03/01
TCI Chemical
Product number
D0127
Product name
m-Xylylenediamine
Purity
>99.0%(GC)
Packaging
25g
Price
$24
Updated
2024/03/01
TCI Chemical
Product number
D0127
Product name
m-Xylylenediamine
Purity
>99.0%(GC)
Packaging
100g
Price
$45
Updated
2024/03/01
Sigma-Aldrich
Product number
X1202
Product name
m-Xylylenediamine
Purity
99%
Packaging
500g
Price
$116
Updated
2024/03/01
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1,3-Bis(aminomethyl)benzene Chemical Properties,Usage,Production

Description

m-Xylene-α,α0-diamine is a colorless liquid.Molecular weight=136.22; Specific gravity (H2O:1)=1.032 at 25℃; Boiling point = 247.2℃; Freezing/Meltingpoint =15℃; Vapor pressure = 0.03 mmHg at 25℃; Flashpoint = 117℃. Hazard Identification (based on NFPA-704M Rating System): Health 3, Flammability 0, Reactivity 0.Soluble in water.

Chemical Properties

CLEAR SLIGHTLY YELLOW LIQUID

Chemical Properties

m-Xylene-α,α0-diamine is a colorless liquid.

Uses

Manufacture of polyamide fibers and resins, as a curing agent.

Uses

m-Xylylenediamine can be used:

  • As a monomer for the synthesis of poly(vinylogous urethane) vitrimers.
  • As a starting material for the synthesis of carbamate-protected multisubstituted bis-guanidine.
  • For the synthesis of polyamides by catalytic dehydrogenation with diols.

General Description

Colorless liquid with an amine smell. Mp: 14.1°C; bp: 273°C . Water soluble.

Reactivity Profile

1,3-Bis(aminomethyl)benzene is combustible (Flash point 139°C). Incompatible with acids, acid chlorides, acid anhydrides.

Hazard

Moderately toxic by skin contact and ingestion. Mildly toxic by inhalation. A severe skin, eye, and gastrointestinal irritant.

Safety Profile

Moderately toxic by skin contact and ingestion. Mildly toxic by inhalation. A severe skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx. Used to make polyamide fibers and resins and as a curing agent.

Potential Exposure

m-Xylene-α,α0-diamine is a source of m-xylene di-isocyanate and used as an intermediate in the manufacture of epoxy and polyamide resins.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least30 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, getmedical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—White: Corrosive or Contact Hazard;Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Store separately in a corrosion-resistantlocation. Prior to working with this chemical you should betrained on its proper handling and storage. Store in tightlyclosed containers in a cool, well-ventilated area away fromoxidizers (such as perchlorates, peroxides, permanganates,chlorates, and nitrates) and strong acids (such as hydrochloride, sulfuric, and nitric). Store in tightly closed containersin a cool, well-ventilated area away from heat. Sources ofignition, such as smoking and open flames, are prohibitedwhere this chemical is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard. Metalcontainers involving the transfer of 5 gallons or more ofthis chemical should be grounded and bonded. Drums mustbe equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof this chemical.

Shipping

UN 2735A mines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3267 Corrosive liquid, basic, organic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

Combustible; vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides.

1,3-Bis(aminomethyl)benzene Preparation Products And Raw materials

Raw materials

P-XYLENE Motor benzol m-xylenediamine 1,4-Dicyanobenzene

Preparation Products

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1,3-Bis(aminomethyl)benzene Suppliers

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View Lastest Price from 1,3-Bis(aminomethyl)benzene manufacturers

Shandong Deshang Chemical Co., Ltd.
Product
1,3-Bis(aminomethyl)benzene 1477-55-0
Price
US $8.00-6.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-06-24
Hebei Weibang Biotechnology Co., Ltd
Product
1,3-Bis(aminomethyl)benzene 1477-55-0
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-07
Hebei Weibang Biotechnology Co., Ltd
Product
1,3-Bis(aminomethyl)benzene 1477-55-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-31

1477-55-0, 1,3-Bis(aminomethyl)benzeneRelated Search:

1,3-Bis(isocyanatomethyl)benzene DCAF 1,3-BIS(2-ISOCYANATO-2-PROPYL)BENZENE PYROMELLITIC DIIMIDE Isophthalic dihydrazide 1,3-Bis(aminomethyl)benzene Iohexol ISOPHTHALAMIDE m-Xylenebisacrylamide Alcian Blue pyridine variant 2,3,5,6-Tetrafluoro-1,4-benzenedimethanamine Hexanedioic acid, polymer with 1,3-benzenedimethanamine N-AMINOPHTHALIMIDE Formaldehyde, polymer with 1,3-benzenedimethanamine and phenol N,N,N',N'-tetrakis(2,3-epoxypropyl)-m-xylene-alpha,alpha'-diamine M-XYLYLENEDIAMINE/ACRYLONITRILE ADDUCT 1,2-bis-(Aminomethyl)benzene,1,4-BIS(AMINOMETHYL)-BENZENE,1,4-BIS(AMINOMETHYL)-BENZENE FOR SYNTHESIS 98+%,1,4-Bis(aminomethyl)benzene, α,αμ-Diamino-p-xylene m-Xylene

  • LABOTEST-BB LT00053687
  • 1,3-BIS(AMINOMETHYL)BENZENE
  • 1,3-Benzenedimethanamine
  • ALPHA,ALPHA'-DIAMINO-M-XYLENE
  • RARECHEM AL BW 0017
  • OMEGA,OMEGA'-DIAMINO-M-XYLENE
  • M-XYLENE-ALPHA,ALPHA'-DIAMINE
  • M-XYLENE-A,A'-DIAMINE
  • M-XYLENE DIAMINE
  • M-XYLYLENE-ALPHA,ALPHA'-DIAMINE
  • 3-(Aminomethyl)benzylamine
  • 3-Xylenediamine
  • alpha,alpha'-m-Xylenediamine
  • m-Diaminoxylene
  • Methylamine, m-phenylenebis-
  • m-phenylenebis-methylamin
  • MXDA
  • m-Xylylendiamin
  • m-xylylendiamin(czech)
  • m-Xylylene amine
  • meta-Xylenediamine
  • m-xylen-alpha,alpha-ylenediamine
  • Xylylenediamine,98%
  • M-xylylenediamine,MXDA
  • M-Xylenediamine (MXDA)
  • 3-Xylylenediamine
  • m-Xylylenediamine 99%
  • 3-Bis(aminomethyl)benzene
  • M-XYLYLENEDIAMINE
  • m-phenylenebis(methylamine)
  • ,’-Diamino-m-xylene
  • 1,3-Bis-aminomethylbenzen
  • 1,3-bis-aminomethylbenzen(czech)
  • 1,3-di(aminomethyl)benzene
  • 1,3-phenylenebismethylamine
  • 1,3-xylenediamine
  • 1,3-Xylylenediamine
  • M-XYLYLENEDIAMINE 98+%
  • MXD
  • M-Xylelenediamine
  • META XYLYLENE DIAMINE
  • XYLYLENEDIAMINE
  • METAXYLENALPHAALPHAYLENEDIAMINE
  • m-Phenylenbis(methylamin)
  • -phenylenebis(methylamine)
  • M-XYLYLENEDIAMINE (ALPHA,ALPHA''-DIAMINO-M-XYLENE)
  • A,A -DIAMINO-M-XYLENE
  • benzene-1,3-dimethanamine
  • 1,3-Bis(aminomethyl)benzene, α,αμ-Diamino-m-xylene
  • m-Xylylenediamine,99%
  • M-XylylenediaMine, 99% 100ML
  • M-XylylenediaMine, 99% 5ML
  • Meta-XylylenediaMine(MXDA)
  • alpha,alpha'-Diamino-m-xylene m-Xylene Diamine 3-(Aminomethyl)benzylamine
  • 1,3-PhenylenediMethanaMine
  • 1,3-Bis(aMinoMethyl)benzene (MXDA)
  • MXDA)M-Xylylenedia
  • Between benzene diMethylaMine