TRIBUTYLSTANNYLTRIMETHYLSILANE
- Product Name
- TRIBUTYLSTANNYLTRIMETHYLSILANE
- CAS No.
- 17955-46-3
- Chemical Name
- TRIBUTYLSTANNYLTRIMETHYLSILANE
- Synonyms
- SKL1120;(TRIMETHYLSILYL)TRIBUTYLTIN;TRIMETHYLSILYLTRI-N-BUTYLTIN;TRIBUTYLSTANNYLTRIMETHYLSILANE;(TRIMETHYLSILYL)TRIBUTYLSTANNANE;TRIMETHYL(TRIBUTYLSTANNYL)SILANE;Trimethylsilyltri-n-butyltin 97%;Tributyl(trimethylsilyl)stannane;TRI-n-BUTYLSTANNYLTRIMETHYLSILANE;Stannane, tributyl(trimethylsilyl)-
- CBNumber
- CB6322630
- Molecular Formula
- C15H36SiSn
- Formula Weight
- 363.24
- MOL File
- 17955-46-3.mol
TRIBUTYLSTANNYLTRIMETHYLSILANE Property
- Boiling point:
- 102-103 °C0.5 mm Hg(lit.)
- Density
- 1.04 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.488(lit.)
- Flash point:
- >230 °F
- storage temp.
- Store under Argon
- solubility
- soluble in THF, ether, CH2Cl2, MeOH, hexane, insoluble in water.
- Specific Gravity
- 1.040
- Hydrolytic Sensitivity
- 1: no significant reaction with aqueous systems
- BRN
- 4127163
Safety
- Hazard Codes
- T,N
- Risk Statements
- 21-25-36/38-48/23/25-50/53
- Safety Statements
- 35-36/37/39-45-60-61
- RIDADR
- UN 2788 6.1/PG 3
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P202Do not handle until all safety precautions have been read and understood.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 367265
- Product name
- Trimethyl(tributylstannyl)silane
- Purity
- 97%
- Packaging
- 5g
- Price
- $260
- Updated
- 2024/03/01
- Product number
- T896365
- Product name
- Tributyl(trimethylsilyl)stannane
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 115409
- Product name
- Tributylstannyltrimethylsilane
- Purity
- 96%
- Packaging
- 1g
- Price
- $49
- Updated
- 2021/12/16
- Product number
- 115409
- Product name
- Tributylstannyltrimethylsilane
- Purity
- 96%
- Packaging
- 5g
- Price
- $198
- Updated
- 2021/12/16
- Product number
- Y8036
- Product name
- (Tributylstannyl)trimethylsilane
- Packaging
- 5g
- Price
- $327
- Updated
- 2021/12/16
TRIBUTYLSTANNYLTRIMETHYLSILANE Chemical Properties,Usage,Production
Physical properties
colorless liquid. bp 88 °C (0.2 mmHg).
Uses
Trimethylsilyltributylstannane is used for the vicinal bis-functionalization of alkynes, dienes, allenes, activated olefins, 1,1-addition to isonitriles, for generation of metal-free aryl and vinyl anions, for generation of benzynes and quinonedimethanes; stereoselective bis-functionalization-cyclization of diynes, eneynes, bis-allenes, alleneynes, and allenealdehydes; silylation of allylic, propargylic derivatives, and aryl bromides; formation of silyl and stannyl cuprates.It takes part in the reactions of Addition to Alkynes, Synthetic Applications of β-Trialkylsilylvinylstannanes, Addition to Isonitriles, Addition to Alkenes and 1,3-Dienes, Addition to Activated Double Bonds, Addition to Allenes, etc.
Preparation
By treating freshly distilled tri-n-butylstannane with LDA followed by quenching with chlorotrimethylsilane.
TRIBUTYLSTANNYLTRIMETHYLSILANE Preparation Products And Raw materials
Raw materials
Preparation Products
TRIBUTYLSTANNYLTRIMETHYLSILANE Suppliers
- Tel
- --
- Fax
- --
- sales@apolloscientific.co.uk
- Country
- United Kingdom
- ProdList
- 6084
- Advantage
- 88
- Tel
- --
- Fax
- --
- kevinbanks@molekula.com
- Country
- United Kingdom
- ProdList
- 6140
- Advantage
- 66
- Tel
- --
- Fax
- --
- vernam@fluorochem.co.uk
- Country
- United Kingdom
- ProdList
- 6375
- Advantage
- 65
- Tel
- --
- Fax
- --
- enquiries@fluorochem.co.uk
- Country
- United Kingdom
- ProdList
- 6401
- Advantage
- 74
View Lastest Price from TRIBUTYLSTANNYLTRIMETHYLSILANE manufacturers
- Product
- TRIBUTYLSTANNYLTRIMETHYLSILANE 17955-46-3
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-14