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trans-1,3-Dichloropropene

Product Name
trans-1,3-Dichloropropene
CAS No.
10061-02-6
Chemical Name
trans-1,3-Dichloropropene
Synonyms
(e)-1,3-dichloroprop-1-ene;D-D;DICHLOROPROPYLENE;(E)-1,3-Dichloropropene;Trans-1,3-Dichloropropane;TELONE;NEMATOX;TELONE(R);di-trapex;trans-1.3-Dich
CBNumber
CB6324649
Molecular Formula
C3H4Cl2
Formula Weight
110.97
MOL File
10061-02-6.mol
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trans-1,3-Dichloropropene Property

Boiling point:
97-112 °C(lit.)
Density 
1.198 g/mL at 25 °C(lit.)
vapor pressure 
79.1 at 50 °C, 523.5 at 100 °C (Wilding et al., 2002)
refractive index 
n20/D 1.472(lit.)
Flash point:
78 °F
storage temp. 
0-6°C
solubility 
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane.
color 
Colorless to Light yellow to Light orange
Specific Gravity
1.217
Water Solubility 
2.8g/L(20 ºC)
Merck 
14,3075
Henry's Law Constant
1.3 x 10-3 atm?m3/mol (Pankow and Rosen, 1988) 0.793 x 10-3 atm?m3/mol at 20 °C, 1.87 at 40 °C (static headspace-GC, Kim et al., 2003)
Exposure limits
ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
Stability:
Stable. Flammable. Incompatible with strong oxidizing agents, aluminium, aluminium alloys, some metal salts and halogens. May be light sensitive.
CAS DataBase Reference
10061-02-6(CAS DataBase Reference)
NIST Chemistry Reference
1-Propene, 1,3-dichloro-, (E)-(10061-02-6)
EPA Substance Registry System
trans-1,3-Dichloropropene (10061-02-6)
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Safety

Hazard Codes 
T,N,Xn,F
Risk Statements 
10-20/21-25-36/37/38-43-50/53-40-22-39/23/24/25-23/24/25-11-52/53-65-24/25-20
Safety Statements 
36/37-45-60-61-16-7
RIDADR 
UN 1992 3/PG 3
WGK Germany 
3
RTECS 
UC8310000
HazardClass 
3.2
PackingGroup 
III
HS Code 
29032990
Hazardous Substances Data
10061-02-6(Hazardous Substances Data)
Toxicity
LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats 713 and 470 mg/kg, respectively (Verschueren, 1983).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
47793
Product name
trans-1,3-Dichloropropene
Purity
analytical standard
Packaging
100mg
Price
$286
Updated
2024/03/01
Sigma-Aldrich
Product number
47369
Product name
trans-1,3-Dichloropropene solution
Purity
certified reference material, 2000?μg/mL in methanol
Packaging
1mL
Price
$40.5
Updated
2022/05/15
TCI Chemical
Product number
D2346
Product name
trans-1,3-Dichloropropene
Purity
>98.0%(GC)
Packaging
5mL
Price
$140
Updated
2024/03/01
TCI Chemical
Product number
D2346
Product name
trans-1,3-Dichloropropene
Purity
>98.0%(GC)
Packaging
25mL
Price
$420
Updated
2024/03/01
GFS CHEMICALS
Product number
33391
Product name
TRANS-1,3-DICHLOROPROPENE
Packaging
5G
Price
$226.9
Updated
2021/12/16
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trans-1,3-Dichloropropene Chemical Properties,Usage,Production

Description

Trans-1,3-dichloropropene appears as a clear colorless liquid with chloroform odor. Flash point 95 °F. Density 1.225 g/cm3 and insoluble in water. Hence sinks in water. A strong irritant. Used as a soil fumigant. It is used as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides.

Chemical Properties

colourless liquid

Chemical Properties

1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.

Physical properties

Colorless to pale yellow liquid with a chloroform-like odor. Evaporates quickly when spilled.

Uses

The isomer mixture is used as a soil fumigant and a nematocide.

Definition

ChEBI: (E)-1,3-dichloropropene is a 1,3-dichloropropene with a (E)-configuration. It has a role as a fumigant. It is a 1,3-dichloropropene and a chloroalkene. It derives from a hydride of a propene.

General Description

A clear colorless liquid with chloroform odor . Flash point 95°. Density 1.225 g / cm3 and insoluble in water. Hence sinks in water. A strong irritant. Used as a soil fumigant.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

trans-1,3-Dichloropropene reacts with aluminum, aluminum alloys, with other active metals and with some metal salts and halogens. Can react vigorously with oxidizing materials. .

Fire Hazard

Flash point data for trans-1,3-Dichloropropene are not available, however literature indicates that trans-1,3-Dichloropropene is flammable.

Potential Exposure

Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.

Environmental Fate

Biological. The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Chemical/Physical. Hydrolysis in distilled water at 25°C produced trans-3-chloro-2- propen-1-ol and hydrochloric acid. The reported half-life for this reaction is only 2 days (Kollig, 1993; Milano et al., 1988). trans-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen-1-ol and can be biologically oxidized to 3-chloropropenoic acid which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at approximately 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene and hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of trans-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 24.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).

Solubility in water

Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane.

Shipping

UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.

Waste Disposal

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

trans-1,3-Dichloropropene Preparation Products And Raw materials

Raw materials

Preparation Products

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trans-1,3-Dichloropropene Suppliers

Nanjing Xiezun Chemical Co., Ltd.
Tel
025-85629050 13912997845
Fax
025-85620080
Email
179109486@qq.com
Country
China
ProdList
25
Advantage
60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9513
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Wuhan Fortuna Chemical Co., Ltd
Tel
027-59207852 13308628970
Fax
QQ3130921841
Email
buy@fortunachem.com
Country
China
ProdList
2866
Advantage
58
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View Lastest Price from trans-1,3-Dichloropropene manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
trans-1,3-Dichloropropene 10061-02-6
Price
US $50.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-12-03
shandong perfect biotechnology co.ltd
Product
Pesticide herbicides and pharmaceutical intermediates 10061-02-6
Price
US $0.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
2000kgs
Release date
2023-07-07
shandong perfect biotechnology co.ltd
Product
E-1,3-Dichloropropene 10061-02-6
Price
US $0.00/g
Min. Order
1g
Purity
98% HPLC
Supply Ability
100kg
Release date
2023-07-21

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