ChemicalBook > CAS DataBase List > 2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE

2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE

Product Name
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE
CAS No.
82737-61-9
Chemical Name
2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE
Synonyms
Davy;DR-ME;DAVY REAGENT METHYL;DAVY REAGENT METHYL, TECH.;2-Butenoicacid,2-cyano-6-methyl-,ethylester;3H-Pyrazol-3-one,1,2-dihydro-1-(6-methylethyl)-;2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE;2,4-BIS(METHYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE;1,3,2,4-Dithiadiphosphetane, 2,4-bis(methylthio)-, 2,4-disulfide;2,4-bis (Methylthio) -1,3,2,4- two thiadiazole-phospha-2,4-disulfide
CBNumber
CB6328874
Molecular Formula
C2H6P2S6
Formula Weight
284.41
MOL File
82737-61-9.mol
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2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Property

Melting point:
165-166℃
Boiling point:
382.5±25.0 °C(Predicted)
Density 
1.69±0.1 g/cm3(Predicted)
Flash point:
105 °F
BRN 
4182442
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Safety

Hazard Codes 
Xn,N,F
Risk Statements 
22-51/53-10-61-50/53-11
Safety Statements 
61
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
13
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
FD41221
Product name
Davy reagent methyl
Packaging
2g
Price
$250
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD41221
Product name
Davy reagent methyl
Packaging
5G
Price
$400
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD41221
Product name
Davy reagent methyl
Packaging
10g
Price
$700
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0156512
Product name
DAVY REAGENT METHYL
Purity
95.00%
Packaging
25G
Price
$1256.41
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD41221
Product name
Davy reagent methyl
Packaging
25g
Price
$1500
Updated
2021/12/16
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2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Chemical Properties,Usage,Production

Description

2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE (Davy's reagent) is reagent for the conversion of carboxylic acids into dithioesters and carbonyl groups into thiocarbonyl groups.

storage

2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE should be stored in the cold with exclusion of moisture. It is very toxic and must be handled under a hood or in glove-boxes due to its intolerable odor and the hazardous  methanethiol which is easily liberated with moisture.

Purification Methods

It crystallises from *C6H6 in yellow plates or from hot trichlorobenzene. The low melting point reported in the literature (112o with gradual softening at 68-102o) has been attributed to the presence of elemental sulfur in the crystals. It has a foul odour and is a suspected carcinogen. [Yousif et al. Tetrahedron 40 2663 1984, Scott et al. J Org Chem 22 789 1957.]

2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE Suppliers

Carbosynth
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Email
sales@carbosynth.com
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United Kingdom
ProdList
6005
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58
CARBONE SCIENTIFIC CO.,LTD
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sales@carbonesci.com
Country
United Kingdom
ProdList
6666
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Apollo Scientific Ltd.
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Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
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88

82737-61-9, 2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDERelated Search:


  • DAVY REAGENT METHYL
  • DR-ME
  • 2,4-BIS(METHYLTHIO)-1,3,2,4-DITHIADIPHOSPHETANE-2,4-DISULFIDE
  • 2,4-BIS(METHYLTHIO)-1,3-DITHIA-2,4-DIPHOSPHETANE-2,4-DISULFIDE
  • Davy
  • DAVY REAGENT METHYL, TECH.
  • 1,3,2,4-Dithiadiphosphetane, 2,4-bis(methylthio)-, 2,4-disulfide
  • 2,4-bis (Methylthio) -1,3,2,4- two thiadiazole-phospha-2,4-disulfide
  • 2,4-Bis(methylthio)-1,3,2,4-dithiadiphosphetane-2,4-disulfide, DR-Me
  • Davy Reagent methyl,2,4-Bis(methylthio)-1,3,2,4-dithiadiphosphetane-2,4-disulfide, DR-Me
  • 2,4-bis(methylsulfanyl)-2,4-bis(sulfanylidene)-1,3,2lambda5,4lambda5-dithiadiphosphetane
  • 2-Butenoicacid,2-cyano-6-methyl-,ethylester
  • 3H-Pyrazol-3-one,1,2-dihydro-1-(6-methylethyl)-
  • 82737-61-9
  • C2H6P2S6
  • Synthetic Reagents
  • C-S Bond Formation
  • C-X Bond Formation (Non-Halogen)
  • API intermediates
  • Boron, Nitrile, Thio,& TM-Cpds
  • chem-chemical