6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE

Product Name: 6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE
CAS No.: 27452-17-1
Chemical Name: 6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE
Synonyms: 4-TETRAMETHYL-1;4-TETRAHYDRONAPHTHALENE;6-Bromo-1,1,4,4-tetramethyl-1,;6-Bromo-1,1,4,4-tetramethyltetralin;6-Bromo-1,1,4,4-tetramethyl-2,3-dihydronaphthalene;6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphene;6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDROPHTHALENE;6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE;6-Bromo-1,2,3,4-tetrahydro-1,1,4,4,-tertramethylnaphthalene;Naphthalene, 6-bromo-1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-
CBNumber: CB6357119
Molecular Formula: C14H19Br
Formula Weight: 267.2
MOL File: 27452-17-1.mol

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6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE Property

Melting point:: 34 °C
Boiling point:: 110-115°C
Density: 1.165±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: White to off-white Solid
Water Solubility: Insoluble in water
InChI: InChI=1S/C14H19Br/c1-13(2)7-8-14(3,4)12-9-10(15)5-6-11(12)13/h5-6,9H,7-8H2,1-4H3
InChIKey: NLOOVMVNNNYLFS-UHFFFAOYSA-N
SMILES: C1(C)(C)C2=C(C=C(Br)C=C2)C(C)(C)CC1

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 23-26-36/37/39
Hazard Note: Harmful
HS Code: 2902900000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Matrix Scientific

Product number: 084099
Product name: 6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene
Packaging: 1.00g
Price: $130
Updated: 2026/05/18

Matrix Scientific

Product number: 084099
Product name: 6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene
Packaging: 10.00g
Price: $924
Updated: 2026/05/18

Synthonix

Product number: B57823
Product name: 6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene
Purity: 97+%
Packaging: 250mg
Price: $34
Updated: 2026/05/06

Synthonix

Product number: B57823
Product name: 6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene
Purity: 97+%
Packaging: 1g
Price: $38
Updated: 2026/05/06

Synthonix

Product number: B57823
Product name: 6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene
Purity: 97+%
Packaging: 5g
Price: $40
Updated: 2026/05/06

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6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE Chemical Properties,Usage,Production

Uses

6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene is used in Synthesis and evaluation of synthetic retinoid derivatives as inducers of stem cell differentiation.

Synthesis

108-86-1

6223-78-5

27452-17-1

The reactor was cooled to 0 °C under nitrogen protection. A mixture (90 mL) containing 2,5-dichloro-2,5-dimethylhexane (110 g, 600 mmol) and aluminum bromobenzenesulfonate (7 g, 52.5 mmol) was added slowly and dropwise to the reactor. After dropwise addition, stirring of the reaction mixture was continued for about 20 minutes. Subsequently, the reaction mixture was extracted with 1 L of a mixed solution of ether and hexane (1:1 v/v). The organic layer was washed sequentially with ice water, 10% hydrochloric acid and 100 mL of brine. After separation of the organic layer, the solvent was removed by concentration under reduced pressure. The residue was dried with magnesium sulfate to give a brown oil. Finally, the target product 6-bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene was purified by methanol crystallization to obtain 120 g in 80% yield.

References

[1] Journal of Medicinal Chemistry, 1994, vol. 37, # 18, p. 2930 - 2941
[2] Patent: US2005/4213, 2005, A1. Location in patent: Page 25
[3] Tetrahedron Letters, 2012, vol. 53, # 39, p. 5302 - 5305
[4] Patent: KR101515814, 2015, B1. Location in patent: Paragraph 0292; 0293
[5] Tetrahedron, 2005, vol. 61, # 20, p. 4755 - 4759

6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE Preparation Products And Raw materials

Raw materials

Preparation Products

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6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE Suppliers

Belgium 1 China 150 France 1 Germany 2 India 2 United Kingdom 4 United States 15 Global 175

Shaanxi Renheng Yide Biotechnology Co., Ltd

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View Lastest Price from 6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE manufacturers

Henan Fengda Chemical Co., Ltd

Product: 6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene 27452-17-1
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-30

Career Henan Chemical Co

Product: 6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE 27452-17-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 85.0-99.8%
Supply Ability: 20 tons
Release date: 2019-12-25

27452-17-1, 6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENERelated Search:

Molybdenum 2-bromotetralin 6-BROMO-1,1,4,4,7-PENTAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE 6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE

6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE

6-Bromo-1,1,4,4-tetramethyl-2,3-dihydronaphthalene

6-Bromo-1,1,4,4-tetramethyl-1,

6-Bromo-1,1,4,4-tetramethyltetralin

6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDROPHTHALENE

Naphthalene, 6-bromo-1,2,3,4-tetrahydro-1,1,4,4-tetramethyl-

6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene,97%

4-TETRAHYDRONAPHTHALENE

4-TETRAMETHYL-1

6-Bromo-1,2,3,4-tetrahydro-1,1,4,4,-tertramethylnaphthalene

6-BROMO-1,1,4,4-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE，98%min

6-Bromo-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphene

27452-17-1

C14H19Br

Halides

Fused Ring Systems