2-bromotetralin
- Product Name
- 2-bromotetralin
- CAS No.
- 6134-56-1
- Chemical Name
- 2-bromotetralin
- Synonyms
- 6-Bromotetralin;2-bromotetralin;Naphthalene, 6-bromo-1,2,3,4-tetrahydro-
- CBNumber
- CB61570391
- Molecular Formula
- C10H11Br
- Formula Weight
- 211.1
- MOL File
- 6134-56-1.mol
2-bromotetralin Property
- Boiling point:
- 241 °C
- Density
- 1.384±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- T263664
- Product name
- 6-BROMO-1,2,3,4-TETRAHYDRONAPHTHALENE
- Purity
- AldrichCPR
- Packaging
- 5MG
- Price
- $113
- Updated
- 2025/07/31
- Product number
- FB143454
- Product name
- 6-Bromo-1,2,3,4-tetrahydronaphthalene
- Packaging
- 250mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- 9184AB
- Product name
- 6-Bromo-1,2,3,4-tetrahydronaphthalene
- Packaging
- 100mg
- Price
- $139
- Updated
- 2021/12/16
- Product number
- FB143454
- Product name
- 6-Bromo-1,2,3,4-tetrahydronaphthalene
- Packaging
- 1g
- Price
- $155
- Updated
- 2021/12/16
- Product number
- FB143454
- Product name
- 6-Bromo-1,2,3,4-tetrahydronaphthalene
- Packaging
- 2g
- Price
- $269
- Updated
- 2021/12/16
2-bromotetralin Chemical Properties,Usage,Production
Synthesis
6340-79-0
6134-56-1
General procedure for the synthesis of 6-bromo-1,2,3,4-tetrahydro-naphthalene from 3-(4-bromobenzoyl)propionic acid: Freshly distilled chloroform (0.6 mL) was added to a screw-capped vial fitted with a magnetic stirring bar under the protection of nitrogen, and In(OAc)3 (0.0060 mmol, 1.8 mg), I2 (0.600 mmol, 152 mg), 3 -(4-bromobenzoyl)propionic acid (0.6 mmol) and Me2PhSiH (3.90 mmol, 600 μL). The vial was sealed with a cap with a PTFE septum. The reaction vial was heated in an oil bath and the progress of the reaction was monitored by gas chromatography (GC) and thin layer chromatography (TLC) until the carboxylic acid was completely consumed. Upon completion of the reaction, the mixture was cooled to room temperature and the reaction was quenched with 2 mL of aqueous HCl. The aqueous layer was extracted with hexane (5 mL × 3). The organic phases were combined, dried with anhydrous Na2SO4, and the solvent was evaporated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane) to afford the target product 6-bromo-1,2,3,4-tetrahydro-naphthalene. If necessary, the product can be further purified by gel permeation chromatography (eluent: CHCl3).
References
[1] Chemistry Letters, 2015, vol. 44, # 11, p. 1503 - 1505
2-bromotetralin Preparation Products And Raw materials
Raw materials
Preparation Products
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