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2-bromotetralin

Product Name
2-bromotetralin
CAS No.
6134-56-1
Chemical Name
2-bromotetralin
Synonyms
6-Bromotetralin;2-bromotetralin;Naphthalene, 6-bromo-1,2,3,4-tetrahydro-
CBNumber
CB61570391
Molecular Formula
C10H11Br
Formula Weight
211.1
MOL File
6134-56-1.mol
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2-bromotetralin Property

Boiling point:
241 °C
Density 
1.384±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
T263664
Product name
6-BROMO-1,2,3,4-TETRAHYDRONAPHTHALENE
Purity
AldrichCPR
Packaging
5MG
Price
$113
Updated
2025/07/31
Biosynth Carbosynth
Product number
FB143454
Product name
6-Bromo-1,2,3,4-tetrahydronaphthalene
Packaging
250mg
Price
$50
Updated
2021/12/16
AK Scientific
Product number
9184AB
Product name
6-Bromo-1,2,3,4-tetrahydronaphthalene
Packaging
100mg
Price
$139
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB143454
Product name
6-Bromo-1,2,3,4-tetrahydronaphthalene
Packaging
1g
Price
$155
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB143454
Product name
6-Bromo-1,2,3,4-tetrahydronaphthalene
Packaging
2g
Price
$269
Updated
2021/12/16
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2-bromotetralin Chemical Properties,Usage,Production

Synthesis

6340-79-0

6134-56-1

General procedure for the synthesis of 6-bromo-1,2,3,4-tetrahydro-naphthalene from 3-(4-bromobenzoyl)propionic acid: Freshly distilled chloroform (0.6 mL) was added to a screw-capped vial fitted with a magnetic stirring bar under the protection of nitrogen, and In(OAc)3 (0.0060 mmol, 1.8 mg), I2 (0.600 mmol, 152 mg), 3 -(4-bromobenzoyl)propionic acid (0.6 mmol) and Me2PhSiH (3.90 mmol, 600 μL). The vial was sealed with a cap with a PTFE septum. The reaction vial was heated in an oil bath and the progress of the reaction was monitored by gas chromatography (GC) and thin layer chromatography (TLC) until the carboxylic acid was completely consumed. Upon completion of the reaction, the mixture was cooled to room temperature and the reaction was quenched with 2 mL of aqueous HCl. The aqueous layer was extracted with hexane (5 mL × 3). The organic phases were combined, dried with anhydrous Na2SO4, and the solvent was evaporated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane) to afford the target product 6-bromo-1,2,3,4-tetrahydro-naphthalene. If necessary, the product can be further purified by gel permeation chromatography (eluent: CHCl3).

References

[1] Chemistry Letters, 2015, vol. 44, # 11, p. 1503 - 1505

2-bromotetralin Preparation Products And Raw materials

Raw materials

Preparation Products

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