ChemicalBook > CAS DataBase List > (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

Product Name
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
CAS No.
16854-32-3
Chemical Name
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Synonyms
thiomicamine;L-THIOMICAMINE;Einecs 240-878-4;(1S,2S)-(+)-THIOMICAMINE;(1S,2S)-(+)-Thiomicamine 99%;2-Amino-1-(4-methylthliophenyl)-1,3-propanediol;2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol;(1S,2S)-2-aMino-1-(4-(Methylthio)phenyl)propane-1,3-diol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol
CBNumber
CB6358080
Molecular Formula
C10H15NO2S
Formula Weight
213.3
MOL File
16854-32-3.mol
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(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Property

Melting point:
151-154 °C(lit.)
Boiling point:
428.2±45.0 °C(Predicted)
Density 
1.25±0.1 g/cm3(Predicted)
pka
11.75±0.45(Predicted)
optical activity
[α]25/D +25°, c = 1 in ethanol
CAS DataBase Reference
16854-32-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Apolloscientific
Product number
OR322203
Product name
(1s,2s)-(+)-Thiomicamine
Packaging
5g
Price
$140
Updated
2021/12/16
SynQuest Laboratories
Product number
8666-1-36
Product name
(1S,2S)-(+)-Thiomicamine
Packaging
5G
Price
$154
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0004486
Product name
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Purity
95.00%
Packaging
1G
Price
$626.08
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0004486
Product name
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Purity
95.00%
Packaging
5G
Price
$834.29
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0004486
Product name
(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
Purity
95.00%
Packaging
10G
Price
$1166.59
Updated
2021/12/16
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(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Chemical Properties,Usage,Production

Uses

(1S,2S)-(+)-Thiomicamine can be used:

  • As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
  • As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
  • As a chiral base in the resolution of an angiotensin II type 2 receptor [AT2R] antagonist named EMA401.

(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL Suppliers

China 26 Europe 2 Germany 1 India 1 Switzerland 1 United Kingdom 5 United States 15 Global 51
A.J Chemicals
Tel
--
Fax
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Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58

16854-32-3, (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOLRelated Search:

Propylene glycol 2-Amino-1,3-propanediol 2-Amino-1-[p-(methylthio)phenyl]-1,3-propanediol [S-(RR]-2-Amino-1-[4-(Methylthio)Phenyl]-1,3- Propanediol (1R,2R)-2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol,[R-(RR]-2-Amino-1-[4-(Methylthio)Phenyl]-1,3-Propanediol (1S,2S)-(+)-2-Amino-1-phenyl-1,3-propanediol 4-(Methylthio)benzyl alcohol Acetamide, 2,2-dichloro-N-(2-hydroxy-1-(hydroxymethyl)-2-(4-(methylsul fonyl)phenyl)ethyl)-, (S-(R*,R*))- 3-(4-METHYLSULFANYL-PHENYL)-PROPAN-1-OL D-P-METHYL SULFONE PHENYL ETHYL SERINATE (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

  • 2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol
  • [S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol
  • L-THIOMICAMINE
  • (1S,2S)-(+)-THIOMICAMINE
  • (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
  • thiomicamine
  • (1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol
  • (1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol
  • Einecs 240-878-4
  • (1S,2S)-2-Amino-1-[4-(methylsulfanyl)phenyl]propane-1,3-diol
  • (1S,2S)-2-aMino-1-(4-(Methylthio)phenyl)propane-1,3-diol
  • (1S,2S)-(+)-Thiomicamine 99%
  • 2-Amino-1-(4-methylthliophenyl)-1,3-propanediol
  • 1,3-Propanediol, 2-amino-1-[4-(methylthio)phenyl]-, (1S,2S)-
  • 16854-32-3
  • 4CH3SC6H4CHOHCHNH2CH2OH
  • AMINE
  • Amino Alcohols
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks