ChemicalBook > CAS DataBase List > 4-ACETAMIDOBENZYL ALCOHOL

4-ACETAMIDOBENZYL ALCOHOL

Product Name
4-ACETAMIDOBENZYL ALCOHOL
CAS No.
16375-88-5
Chemical Name
4-ACETAMIDOBENZYL ALCOHOL
Synonyms
N-(4-(Hydroxymethyl);4-ACETAMIDOBENZYL ALCOHOL;4-acetaminobenzyl alcohol;Chloramphenicol Impurity 17;4-Acetamidobenzylalcohol,97%;4-(Acetylamino)benzyl alcohol;N-[4-(HYDROXYMETHYL)PHENYL]ACETAMIDE;Acetamide, N-[4-(hydroxymethyl)phenyl]-
CBNumber
CB6358510
Molecular Formula
C9H11NO2
Formula Weight
165.19
MOL File
16375-88-5.mol
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4-ACETAMIDOBENZYL ALCOHOL Property

Melting point:
120-122°C
Boiling point:
120-122
Density 
1.211±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
14.37±0.10(Predicted)
color 
Off-White
λmax
246nm(MeOH)(lit.)
InChI
InChI=1S/C9H11NO2/c1-7(12)10-9-4-2-8(6-11)3-5-9/h2-5,11H,6H2,1H3,(H,10,12)
InChIKey
XEYORFKUJZEQCH-UHFFFAOYSA-N
SMILES
C(NC1=CC=C(CO)C=C1)(=O)C
CAS DataBase Reference
16375-88-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2906290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
H1605
Product name
N-[4-(Hydroxymethyl)phenyl]acetamide
Purity
>98.0%(GC)
Packaging
1g
Price
$49
Updated
2025/07/31
TCI Chemical
Product number
H1605
Product name
N-[4-(Hydroxymethyl)phenyl]acetamide
Purity
>98.0%(GC)
Packaging
5g
Price
$144
Updated
2025/07/31
TRC
Product number
B400633
Product name
4-AcetamidobenzylAlcohol
Packaging
500mg
Price
$70
Updated
2021/12/16
Matrix Scientific
Product number
003148
Product name
4-Acetamidobenzyl alcohol
Packaging
1g
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA70499
Product name
4-Acetamidobenzyl alcohol
Packaging
25g
Price
$75
Updated
2021/12/16
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4-ACETAMIDOBENZYL ALCOHOL Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder

Uses

4-Acetamidobenzyl Alcohol is a useful research chemical, a metabolites of a blocked chloramphenicol producer. It can be used to regulate plant growth.

Synthesis

122-85-0

16375-88-5

4-Acetamidobenzaldehyde (10 g, 61.3 mmol) was dissolved in methanol (100 mL) at room temperature, followed by batchwise addition of sodium borohydride (800 mg). The reaction mixture was stirred overnight at room temperature and the reaction progress was monitored by thin layer chromatography (TLC) using 4:1 hexane:ethyl acetate as eluent. Completion of the reduction reaction was indicated when TLC showed complete disappearance of the feedstock. Subsequently, the reaction mixture was concentrated using a rotary evaporator. The concentrated residue was partitioned between water (25 mL) and ethyl acetate (4 x 50 mL), and the organic layer was separated and washed with brine (25 mL). The organic layer was dried over anhydrous sodium sulfate and the solvent was removed under reduced pressure to give the light yellow solid product N-[4-(hydroxymethyl)phenyl]acetamide. The product was dried under high vacuum to give a final 8.6 g (85% yield). The structure of the product was confirmed by 1H NMR (DMSO-d6): δ 2.0 (s, 3H), 4.5 (d, 2H), 5.2 (t, 1H), 7.25 (d, 2H), 7.55 (d, 2H), 9.95 (s, 1H).

References

[1] Advanced Synthesis and Catalysis, 2018, vol. 360, # 4, p. 676 - 681
[2] Chemical Communications, 2015, vol. 51, # 46, p. 9567 - 9570
[3] Organic Letters, 2017, vol. 19, # 13, p. 3656 - 3659
[4] Catalysis Science and Technology, 2013, vol. 3, # 1, p. 81 - 84
[5] Patent: US2007/149462, 2007, A1. Location in patent: Page/Page column 22

4-ACETAMIDOBENZYL ALCOHOL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-ACETAMIDOBENZYL ALCOHOL Suppliers

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View Lastest Price from 4-ACETAMIDOBENZYL ALCOHOL manufacturers

Career Henan Chemical Co
Product
4-ACETAMIDOBENZYL ALCOHOL 16375-88-5
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-30

16375-88-5, 4-ACETAMIDOBENZYL ALCOHOLRelated Search:

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  • N-[4-(HYDROXYMETHYL)PHENYL]ACETAMIDE
  • 4-acetaminobenzyl alcohol
  • 4-ACETAMIDOBENZYL ALCOHOL
  • 4-(Acetylamino)benzyl alcohol
  • N-(4-(Hydroxymethyl)
  • Acetamide, N-[4-(hydroxymethyl)phenyl]-
  • Chloramphenicol Impurity 17
  • 4-Acetamidobenzylalcohol,97%
  • 16375-88-5
  • Benzhydrols, Benzyl & Special Alcohols