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TITANIUM(III) FLUORIDE

Product Name
TITANIUM(III) FLUORIDE
CAS No.
13470-08-1
Chemical Name
TITANIUM(III) FLUORIDE
Synonyms
TiF3;TSCS(13470-08-1);TITANIUM FLUORIDE;TITANIUM TRIFLUORIDE;itanium(III)fluoride;TITANIUM(III) FLUORIDE;titaniumfluoride(tif3);Titanium fluoride(F3Ti);Titanium fluoride (TiF3);Titanium(III)fluoride99%
CBNumber
CB6377711
Molecular Formula
F3Ti
Formula Weight
104.86
MOL File
13470-08-1.mol
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TITANIUM(III) FLUORIDE Property

Melting point:
1200 °C
Boiling point:
1400 °C
Density 
3.4 g/mL at 25 °C(lit.)
solubility 
insoluble in H2O, dilute acid solutions, alkaline solutions
form 
Crystalline Powder
Specific Gravity
3.4
color 
Red to brown
Water Solubility 
Sparingly soluble. It hydrolyses in water.
Sensitive 
Air & Moisture Sensitive
Crystal Structure
VF3 type
crystal system
Three sides
Space group
R3c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.5430.5431.36490901200.3488
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
CAS DataBase Reference
13470-08-1(CAS DataBase Reference)
EPA Substance Registry System
Titanium fluoride (TiF3) (13470-08-1)
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Safety

Hazard Codes 
C
Risk Statements 
20/21/22-34-32-14
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
F 
10
Hazard Note 
Corrosive
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
28261990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
399817
Product name
Titanium(III) fluoride
Packaging
5g
Price
$63.7
Updated
2024/03/01
Alfa Aesar
Product number
013079
Product name
Titanium(III) fluoride
Packaging
10g
Price
$57.65
Updated
2024/03/01
Alfa Aesar
Product number
013079
Product name
Titanium(III) fluoride
Packaging
50g
Price
$273
Updated
2023/06/20
Strem Chemicals
Product number
93-2224
Product name
Titanium(III) fluoride, min. 98%
Packaging
5g
Price
$41
Updated
2024/03/01
Strem Chemicals
Product number
93-2224
Product name
Titanium(III) fluoride, min. 98%
Packaging
25g
Price
$149
Updated
2024/03/01
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TITANIUM(III) FLUORIDE Chemical Properties,Usage,Production

Chemical Properties

Red to brown crystalline powder
Blue rhombic crystals are stable in air and unusually resistant to acids and bases. Sublimation begins at about 930°C in a less than 0.1 mm vacuum. M.p. >1100°C; d%5 2.98. Insoluble in water and alcohol. Disproportionation to TiF4 and Ti begins at 950°C.

Uses

It is used as a laboratory chemicals & for manufacture of chemicals.

Production Methods

Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%. 

reaction suitability

core: titanium
reagent type: catalyst

TITANIUM(III) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TITANIUM(III) FLUORIDE Suppliers

Belgium 1 China 43 Europe 1 France 2 Germany 2 India 2 Japan 1 Switzerland 1 United Kingdom 8 United States 20 Global 81
J & K SCIENTIFIC LTD.
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13470-08-1, TITANIUM(III) FLUORIDERelated Search:

Hexafluorotitanic acid TITANIUM (III) SULFATE Magnesium fluoride Magnesium nitride Ferrous chloride Titanous chloride TITANIUM(IV) BROMIDE TITANIUM(III) CHLORIDE-ALUMINUM(III) CHLORIDE Titanium (IV) Sulfate Titanium TITANIUM(III) FLUORIDE 97% POTASSIUM TITANIUM FLUORIDE CERIUM(III) SULFATE OCTAHYDRATE SODIUM TITANIUM FLUORIDE Titanium fluoride (TiF4), (T-4)- TITANIUM(III) FLUORIDE ammonium titanium fluoride LITHIUM HEXAFLUOROTITANATE

  • TiF3
  • Titanium fluoride (TiF3)
  • titaniumfluoride(tif3)
  • TITANIUM TRIFLUORIDE
  • TITANIUM(III) FLUORIDE
  • TITANIUM FLUORIDE
  • Titanium(III)fluoride99%
  • Titanium(III) fluoride, min. 98%
  • Titanium(III) trifluoride
  • TSCS(13470-08-1)
  • Titanium(III)fluoride,min.98%
  • Titanium(III) fluoride,98%
  • Titanium fluoride(F3Ti)
  • itanium(III)fluoride
  • Carbon Graphite (C) Sputtering Targets
  • 13470-08-1
  • 3FTi
  • Catalysis and Inorganic Chemistry
  • Titanium
  • metal halide