Rhodium(III) nitrate

Product Name: Rhodium(III) nitrate
CAS No.: 10139-58-9
Chemical Name: Rhodium(III) nitrate
Synonyms: RHODIUM NITRATE;rhodiumtrinitrate;RHODIUM(+3)NITRATE;RHODIUM(III) NITRATE;Solutioninnitricacid;RhodiuM nitrate soluti;RhodiuM nitrate liquid;Rhodium nitrate solution;nitric acid, rhodium salt;Nitricacid,rhodium(3+)salt
CBNumber: CB6384874
Molecular Formula: HNO3Rh
Formula Weight: 165.92
MOL File: 10139-58-9.mol

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Rhodium(III) nitrate Property

Boiling point:: 100 °C
Density: 1.41 g/mL at 25 °C
storage temp.: 0-6°C
solubility: insoluble in H2O
form: Solution
color: Dark orange-brown to red-brown solution
Water Solubility: Soluble in alcohol, water, acetone
Exposure limits: ACGIH: TWA 0.01 mg/m3
NIOSH: IDLH 2 mg/m3; TWA 0.001 mg/m3
InChIKey: VXNYVYJABGOSBX-UHFFFAOYSA-N
CAS DataBase Reference: 10139-58-9(CAS DataBase Reference)
EPA Substance Registry System: Nitric acid, rhodium(3+) salt (10139-58-9)

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Safety

Hazard Codes: C,Xi,O
Risk Statements: 8-34-35-36/38
Safety Statements: 26-45-36-23-36/37/39-17-15
RIDADR: UN 3085 5.1/PG 3
WGK Germany: 3
RTECS: VI9316000
F: 3-10
TSCA: Yes
HazardClass: 5.1
PackingGroup: II
HS Code: 28439090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 83750
Product name: Rhodium(III) nitrate hydrate
Purity: ~36% rhodium (Rh) basis
Packaging: 250mg
Price: $250
Updated: 2025/07/31

Sigma-Aldrich

Product number: 83750
Product name: Rhodium(III) nitrate hydrate
Purity: ~36% rhodium (Rh) basis
Packaging: 1g
Price: $625
Updated: 2025/07/31

Strem Chemicals

Product number: 45-1808
Product name: Rhodium(III) nitrate, solution in water (10% Rh)
Packaging: 1g
Price: $352
Updated: 2024/03/01

Strem Chemicals

Product number: 45-1808
Product name: Rhodium(III) nitrate, solution in water (10% Rh)
Packaging: 5g
Price: $1404
Updated: 2024/03/01

Strem Chemicals

Product number: 45-1808
Product name: Rhodium(III) nitrate, solution in water (10% Rh)
Packaging: 25g
Price: $1899
Updated: 2021/12/16

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Rhodium(III) nitrate Chemical Properties,Usage,Production

Chemical Properties

Rhodium nitrate is a dark orange-brown solution with strong corrosive properties. It remains relatively stable at ambient temperatures but begins to decompose when heated to 255 degrees Celsius. It is insoluble in water but dissolves in ammonia solutions, hydroxides, carbonates, and organic acids such as acetic acid, gluconic acid, citric acid, and malic acid. Its primary application is in the manufacture of various catalysts, including hydrogenation catalysts, oxidation catalysts, desulfurization catalysts, and alkylation catalysts.

Uses

It acts as a chemical catalyst, it is used as a slurry bed in Hydrogenation reaction. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals industries.

Preparation

Rhodium nitrate is prepared by reacting rhodium with nitric acid, or by dissolving rhodium(III) oxide pentahydrate in nitric acid and evaporating the solution to dryness over a water bath.

Application

Rhodium(III) nitrate hydrate can be used as a precursor:
To synthesize Rh-doped catalysts for various chemical transformations.
With iron(III) nitrate nonahydrate to synthesis Fe–Rh/TiO2 catalysts for hydrogenation reaction.[1]
For Ethene Hydroformylation, a bimetallic Rh/Co catalyst is synthesized by combining Rhodium(III) nitrate hydrate with Co(NO3)2 .6H2O.[2]
For the simultaneous electrodeposition of Cu and Rh from an aqueous nitrate solution.[3]

Flammability and Explosibility

Not classified

References

[1] ROBERT M. PALOMINO . The effect of Fe–Rh alloying on CO hydrogenation to C2+ oxygenates[J]. Journal of Catalysis, 2015, 329: Pages 87-94. DOI:10.1016/j.jcat.2015.04.033.
[2] NING HUANG. Insights into the Bimetallic Effects of a RhCo Catalyst for Ethene Hydroformylation: Experimental and DFT Investigations[J]. Industrial & Engineering Chemistry Research, 2020, 59 42: 18771-18780. DOI:10.1021/acs.iecr.0c03437.
[3] DIMITRA ANASTASIADOU. A Study of Cu-Rh Electrodeposition**[J]. ChemElectroChem, 2022, 10 1. DOI:10.1002/celc.202200842.
[4] R. CAMINITI. Structure of rhodium(III) nitrate aqueous solutions. An investigation by x-ray diffraction and Raman spectroscopy[J]. The Journal of Physical Chemistry , 1986, 90 2: 238-243. DOI:10.1021/j100274a007.

Rhodium(III) nitrate Preparation Products And Raw materials

Raw materials

Preparation Products

Rhodium

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Rhodium(III) nitrate Suppliers

Belgium 3 China 93 France 1 Germany 7 India 9 Japan 3 Russia 1 South Africa 1 Switzerland 2 The Netherlands 1 United Kingdom 3 United States 21 Global 145

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View Lastest Price from Rhodium(III) nitrate manufacturers

henan kanbei chemical co.,ltd

Product: Rhodium(III) nitrate 10139-58-9
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-21

Zhuozhou Wenxi import and Export Co., Ltd

Product: Rhodium(III) nitrate 10139-58-9
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: Rhodium(III) nitrate 10139-58-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 25kg
Release date: 2019-07-11

10139-58-9, Rhodium(III) nitrateRelated Search:

Ruthenium(III) chloride Palladium nitrate Rhodium(III) nitrate dihydrate rhodium(3+) acetate Rhodium (III) chloride trihydrate Cupric nitrate trihydrate Rhodium(III) Chloride Ammonium hexachlororhodate(III) Rhodium(III) chloride hydrate Neodymium(III) nitrate hydrate DYSPROSIUM NITRATE Platinum nitrate Copper dinitrate Lanthanum(III) nitrate hexahydrate NITRONIUM TETRAFLUOROBORATE Miconazole Nitrate Aluminium nitrate nonahydrate Thiamine nitrate

RhodiuM nitrate liquid

RhodiuM nitrate soluti

RhodiuM(Ⅲ) nitrate solution

Rhodium(III) nitrate hydrate ~36% rhodium (Rh) basis

Rhodium(III) nitrate solution, 10-15 wt. % in water (cont. Rh)

Nitric acid,rhodium(3+) salt (3:1)

Rhodium(III)nitrate, Solution, ca.10% (w/w) Rh in 20-25 weight% HNO

Rhodium(III) nitrate, solution in water (10% Rh)

Rh5%Rhodium nitrate solution

RHODIUM(+3)NITRATE

RHODIUM NITRATE

RHODIUM(III) NITRATE

Rhodium nitrate solution

Rhodium ICP standard solution Fluka

Rhodium internal ICP-MS Standard Fluka

RHODIUM(III) NITRATE SOLUTION, CA. 10% ( WT/WT) RH IN >5 WT. % HNO3

Solutioninnitricacid

Rhodium(III)nitrate, solution, ca. 10% (wt/wt) Rh in 20-25 wt% HNO3

Trinitric acid rhodium(III) salt

Rhodium(III) nitrate solution, Rh 10-15% w/w (cont. Rh)

Rhodium(III)nitrate, solution, ca. 10% (w/v) Rh in 20-25 wt% HNO3

Rhodium(III)nitrate,solution(10%Rh)

nitric acid, rhodium salt

Nitricacid,rhodium(3+)salt

nitricacid,rhodium(3++)salt

rhodiumtrinitrate

Rhodium(III) nitrate ISO 9001：2015 REACH

Rhodium(III) nitrate, hydrate, ~36% (Rh) basis

Rhodium (III) Nitrate in aqueous solution

rhodium(+2) cation trinitrate

10139-58-9

RhNO33

RhH2OOH3yNO3yy23

N3O9Rh

ICP-OES/-MS

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