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BENZENE CHROMIUM TRICARBONYL

Product Name
BENZENE CHROMIUM TRICARBONYL
CAS No.
12082-08-5
Chemical Name
BENZENE CHROMIUM TRICARBONYL
Synonyms
Benchrotrene;Benzenechromotricarbonyl;Benzentrikarbonylchromium;tricarbonylbenzenechromium;Tricarbonylbenzene chromium;(benzene)tricarbonyl-chromiu;CHROMIUM BENZENE TRICARBONYL;(BENZENE)TRICARBONYLCHROMIUM;BENZENE CHROMIUM TRICARBONYL;pi-benzenechromiumtricarbonyl
CBNumber
CB6389602
Molecular Formula
C9H6CrO36*
Formula Weight
214.14
MOL File
12082-08-5.mol
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BENZENE CHROMIUM TRICARBONYL Property

Melting point:
163-166 °C (lit.)
form 
crystal
color 
yellow
BRN 
3571699
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36/37
RIDADR 
2811
WGK Germany 
3
RTECS 
GB4700000
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
119318
Product name
Benzene-chromium(0) tricarbonyl
Purity
98%
Packaging
1g
Price
$152
Updated
2024/03/01
Strem Chemicals
Product number
24-0120
Product name
Benzene chromium tricarbonyl, 98%
Packaging
1g
Price
$132
Updated
2024/03/01
Strem Chemicals
Product number
24-0120
Product name
Benzene chromium tricarbonyl, 98%
Packaging
5g
Price
$519
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0002478
Product name
BENZENE CHROMIUM TRICARBONYL
Purity
95.00%
Packaging
1G
Price
$196.14
Updated
2021/12/16
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BENZENE CHROMIUM TRICARBONYL Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline powder

Uses

Catalyst for:

  • Oxidation of alkenes
  • Hydrogenation of alkynes

Preparation

For cases where large quantities are needed, benzene chromium tricarbonyl is easily prepared from the reaction of benzene with Hexacarbonylchromium.

Solubility in organics

benzene chromium tricarbonyl is soluble in THF, ether, benzene.

Purification Methods

Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.]

BENZENE CHROMIUM TRICARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZENE CHROMIUM TRICARBONYL Suppliers

Fujian Wolfa Biotechnology Co., Ltd
Tel
1805-0950397 19396072537
Email
lyna@wolfabio.com
Country
China
ProdList
199
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6134
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65

12082-08-5, BENZENE CHROMIUM TRICARBONYLRelated Search:


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  • (benzene)tricarbonyl-chromiu
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  • 12082-08-5
  • C9H6CrO3
  • C6H6CrCO3
  • Catalysis and Inorganic Chemistry
  • metal carbonyl complexes