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BENZENE CHROMIUM TRICARBONYL

Product Name
BENZENE CHROMIUM TRICARBONYL
CAS No.
12082-08-5
Chemical Name
BENZENE CHROMIUM TRICARBONYL
Synonyms
Benchrotrene;Benzenechromotricarbonyl;Benzentrikarbonylchromium;tricarbonylbenzenechromium;Tricarbonylbenzene chromium;(benzene)tricarbonyl-chromiu;CHROMIUM BENZENE TRICARBONYL;(BENZENE)TRICARBONYLCHROMIUM;BENZENE CHROMIUM TRICARBONYL;pi-benzenechromiumtricarbonyl
CBNumber
CB6389602
Molecular Formula
C9H6CrO36*
Formula Weight
214.14
MOL File
12082-08-5.mol
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BENZENE CHROMIUM TRICARBONYL Property

Melting point:
163-166 °C (lit.)
form 
crystal
color 
yellow
BRN 
3571699
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36/37
RIDADR 
2811
WGK Germany 
3
RTECS 
GB4700000
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
119318
Product name
Benzene-chromium(0) tricarbonyl
Purity
98%
Packaging
1g
Price
$152
Updated
2024/03/01
Strem Chemicals
Product number
24-0120
Product name
Benzene chromium tricarbonyl, 98%
Packaging
1g
Price
$132
Updated
2024/03/01
Strem Chemicals
Product number
24-0120
Product name
Benzene chromium tricarbonyl, 98%
Packaging
5g
Price
$519
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0002478
Product name
BENZENE CHROMIUM TRICARBONYL
Purity
95.00%
Packaging
1G
Price
$196.14
Updated
2021/12/16
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BENZENE CHROMIUM TRICARBONYL Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline powder

Uses

Catalyst for:

  • Oxidation of alkenes
  • Hydrogenation of alkynes

Purification Methods

Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.]

BENZENE CHROMIUM TRICARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZENE CHROMIUM TRICARBONYL Suppliers

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12082-08-5, BENZENE CHROMIUM TRICARBONYLRelated Search:


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  • (benzene)tricarbonyl-chromiu
  • (eta(sup6)-benzene)tricarbonyl-chromiu
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  • Catalysis and Inorganic Chemistry
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