BENZENE CHROMIUM TRICARBONYL

Product Name: BENZENE CHROMIUM TRICARBONYL
CAS No.: 12082-08-5
Chemical Name: BENZENE CHROMIUM TRICARBONYL
Synonyms: Benchrotrene;Benzenechromotricarbonyl;Benzentrikarbonylchromium;tricarbonylbenzenechromium;Tricarbonylbenzene chromium;(benzene)tricarbonyl-chromiu;CHROMIUM BENZENE TRICARBONYL;(BENZENE)TRICARBONYLCHROMIUM;BENZENE CHROMIUM TRICARBONYL;pi-benzenechromiumtricarbonyl
CBNumber: CB6389602
Molecular Formula: C9H6CrO36*
Formula Weight: 214.14
MOL File: 12082-08-5.mol

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BENZENE CHROMIUM TRICARBONYL Property

Melting point:: 163-166 °C (lit.)
form: crystal
color: yellow
BRN: 3571699

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 36/37
RIDADR: 2811
WGK Germany: 3
RTECS: GB4700000
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 119318
Product name: Benzene-chromium(0) tricarbonyl
Purity: 98%
Packaging: 1g
Price: $152
Updated: 2024/03/01

Strem Chemicals

Product number: 24-0120
Product name: Benzene chromium tricarbonyl, 98%
Packaging: 1g
Price: $132
Updated: 2024/03/01

Strem Chemicals

Product number: 24-0120
Product name: Benzene chromium tricarbonyl, 98%
Packaging: 5g
Price: $519
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ING0002478
Product name: BENZENE CHROMIUM TRICARBONYL
Purity: 95.00%
Packaging: 1G
Price: $196.14
Updated: 2021/12/16

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BENZENE CHROMIUM TRICARBONYL Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline powder

Uses

Catalyst for:

Oxidation of alkenes
Hydrogenation of alkynes

Preparation

For cases where large quantities are needed, benzene chromium tricarbonyl is easily prepared from the reaction of benzene with Hexacarbonylchromium.

Solubility in organics

benzene chromium tricarbonyl is soluble in THF, ether, benzene.

Purification Methods

Purify the complex by sublimation in vacuo. A possible impurity is 2-picoline which can be removed by washing with pentane and drying. It is then purified further by sublimation at 80-85o/10-3mm, or by recrystallisation from Et2O to give yellow crystals. 1H NMR in CDCl3 should give a single peak at 4.68. [Rausch J Org Chem 39 1787 1974, Pauson in Houben-Weyl Meth Org Chem V, E 18 Pt I p226 Theme Verlag, Stuttgart 1986, Beilstein 5 IV 625.]

BENZENE CHROMIUM TRICARBONYL Preparation Products And Raw materials

Raw materials

Chromium hexacarbonyl

Preparation Products

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BENZENE CHROMIUM TRICARBONYL Suppliers

Belgium 1 CHINA 28 Germany 2 Japan 2 South Korea 1 Switzerland 1 Ukraine 1 United States 10 Global 46

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12082-08-5, BENZENE CHROMIUM TRICARBONYLRelated Search:

Chromium hexacarbonyl Chromium (ETHYNYLBENZENE)TRICARBONYL CHROMIUM (METHYL BENZOATE)TRICARBONYLCHROMIUM CHROMIUM, TRICARBONYL[(1,2,3,4,5,6-ETA)-CHLOROBENZENE]- P-XYLENE CHROMIUM TRICARBONYL BENZENE CHROMIUM TRICARBONYL O-XYLENE CHROMIUM TRICARBONYL 1,3,5-TRIMETHYLBENZENE CHROMIUM TRICARBONYL

(6-Benzene)tricarbonylchromium

(benzene)tricarbonyl-chromiu

(eta(sup6)-benzene)tricarbonyl-chromiu

(η6-benzene)tricarbonylchromium

Benchrotrene

Benzene-chromium carbonyl complex

Benzenechromotricarbonyl

Benzentrikarbonylchromium

Chromium,(mu<sup>6</sup>-benzene)tricarbonyl-

eta(sup6)-Benzenetricarbonylchromium

eta6-Benzenetricarbonylchromium

pi-Benzenechromium tricarbonyl

pi-benzenechromiumtricarbonyl

pi-Benzenetricarbonylchromium

Tricarbonylbenzene chromium

tricarbonylbenzenechromium

CHROMIUM BENZENE TRICARBONYL

(BENZENE)TRICARBONYLCHROMIUM

(BENZENE)TRICARBONYLCHROMIUM(0)

BENZENE CHROMIUM TRICARBONYL

Benzene chroMiuM tricarbonyl, 98% 1GR

(BENZENE)TRICARBONYLCHROMIUM,98%

BENZENE CHROMIUM TRICARBONYL 98%

Benzenechromiumtricarbonyl,98%

benzene-chromium(0) tricarbonyl

Benzene-chromium(0) tricarbonyl 98%

BENZENE CHROMIUM TRICARBONYL ISO 9001：2015 REACH

Chromium, (η6-benzene)tricarbonyl-

12082-08-5

C9H6CrO3

C6H6CrCO3

Catalysis and Inorganic Chemistry

metal carbonyl complexes