ChemicalBook > CAS DataBase List > AMMONIUM CERIUM(IV) SULFATE

AMMONIUM CERIUM(IV) SULFATE

Product Name
AMMONIUM CERIUM(IV) SULFATE
CAS No.
7637-03-8
Chemical Name
AMMONIUM CERIUM(IV) SULFATE
Synonyms
Dequaspon;Sterispon;Cerium Ammonium Sulp;CERIC AMMONIUM SULFATE;Ammonium sulfatocerate;CERIC AMMONIUM SULPHATE;CERIUM AMMONIUM SULFATE;AMMONIUM CERIC SULPHATE;Ammoniumcericsulfate,tetrah;AMMONIUM CERIUM(IV) SULFATE
CBNumber
CB6427715
Molecular Formula
CeH5NO4S
Formula Weight
255.22
MOL File
7637-03-8.mol
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AMMONIUM CERIUM(IV) SULFATE Property

solubility 
sol water, dil. H2SO4 ,dil. H2SO4-MeCN.
form 
Liquid
color 
Clear orange
CAS DataBase Reference
7637-03-8(CAS DataBase Reference)
EPA Substance Registry System
Sulfuric acid, ammonium cerium(4+) salt (4:4:1) (7637-03-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-36/38
Safety Statements 
26-36
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ING0003660
Product name
AMMONIUM CERIC SULPHATE
Purity
95.00%
Packaging
1L
Price
$6457.37
Updated
2021/12/16
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AMMONIUM CERIUM(IV) SULFATE Chemical Properties,Usage,Production

Uses

convenient reagent for oxidation of aromatic rings, and halophenols to quinones, for regioselective Baeyer–Villiger oxidation, and oxidative aromatization.

Reactions

Cerium(IV) ion is a potent one-electron oxidant. cerium(IV) ammonium nitrate (CAN), is the most widely utilized cerium(IV) oxidizing agent, but cerium(IV) ammonium sulfate (CAS) is a good substitute when complications due to the involvement of nitrate ligands occur, resulting in side products such as nitrate esters.
Synthesis of Quinones by Oxidation of Aromatic Rings.
The most important application of CAS is in the oxidation of aromatic rings. CAN oxidizes polycyclic aromatic hydrocarbons only in moderate yields (20–60%), and these reactions are often complicated by the formation of nitrate esters. In contrast, CAS generally oxidizes aromatic hydrocarbons to quinones in goodyields.Forexample,naphthalene is oxidized to 1,4-naphthoquinone in excellent yield by CAS in a dilute mixture of H2SO4 and MeCN (eq1).

storage

cerium(IV) ammonium sulfate is a stable reagent and precautions required for handling strong oxidizing agents such as potassium permanganate will be sufficient. Cerium is reputed to be of low toxicity.

AMMONIUM CERIUM(IV) SULFATE Preparation Products And Raw materials

Raw materials

Preparation Products

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AMMONIUM CERIUM(IV) SULFATE Suppliers

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View Lastest Price from AMMONIUM CERIUM(IV) SULFATE manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetraammoniumcerium(IV)sulfate 7637-03-8
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-02
Zhuozhou Wenxi import and Export Co., Ltd
Product
AMMONIUM CERIUM(IV) SULFATE 7637-03-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
AMMONIUM CERIUM(IV) SULFATE 7637-03-8
Price
US $1.00/KG
Min. Order
1KG
Purity
995
Supply Ability
25kg
Release date
2019-07-12

7637-03-8, AMMONIUM CERIUM(IV) SULFATERelated Search:

Cerium tetrahydroxide CERIUM (III) NITRATE CERIC SULFATE CERIUM(III) SULFATE N-HYDRATE CERIUM(III) CHLORIDE CERIUM CERIUM(III) PHOSPHATE Ceric ammonium nitrate CERIUM(III) NITRATE HEXAHYDRATE Ammonium sulfate CERIC SULFATE CERIUM AMMONIUM CERIUM(IV) SULFATE 4 H2O,AMMONIUM CERIUM(IV) SULFATE TETRAHYDRATE AMMONIUM CERIUM(IV) SULFATE TETRAHYDRATE AMMONIUM CERIUM(IV) SULFATE DIHYDRATE AMMONIUM CERIUM(IV) SULFATE SOLUTION AMMONIUM CERIUM(IV) SULFATE HYDRATE Cerium Ammonium Sulfate

  • Ammoniumcericsulfate,tetrah
  • Sulfuricacid,ammoniumcerium(4+)salt(4:4:1)
  • sulfuricacid,ammoniumcerium(4++)salt(4:4:1)
  • tetraammoniumceriumtetrakis(sulphate)
  • TETRAAMMONIUM CERIUM(IV) SULFATE
  • TETRA-AMMONIUM CERIUM(IV) SULPHATE
  • CERIUM (IV) AMMONIUM SULFATE
  • CERIUM AMMONIUM SULFATE
  • CERIUM(IV) TETRAAMMONIUM SULFATE
  • CERIC AMMONIUM SULPHATE
  • CERIC AMMONIUM SULFATE
  • CERIUM(+4)TETRAAMMONIUM SULFATE
  • AMMONIUM TETRASULFATO CERATE
  • AMMONIUM CERIC SULPHATE
  • AMMONIUM CERIUM (IV) SULPHATE
  • AMMONIUM CERIUM(IV) SULFATE
  • cerium(iv) ammonium sulfate solution
  • Ammonium cerium(IV) sulfate solution,Cerium(IV) ammonium sulfate solution
  • Cerium Ammonium Sulp
  • Ammonium sulfatocerate
  • Dequaspon
  • Sterispon
  • AMMoniuM ceriuM sulfate hydrate
  • PHLOROGLUCINOL (HCL/ETHANOL) DUTY PAID
  • Ammonium ceric sulfate hydrate
  • Ceric ammonium sulfate hydrate
  • Ceric ammonium sulfate standard solution
  • Ammonium cerium(IV) sulfate hydrate,99.95%
  • Ammonium cerium(Ⅳ) sulfate tetrahydrate
  • Ammonium cerium(IV) sulfate standard solutio
  • Ammonium cerium sulfate Analytical Titrant
  • 7637-03-8
  • 7637-3-8
  • CeNH44SO44xH2O
  • Ce4H3N4H2O4S
  • NH44CeSO44
  • Catalysis and Inorganic Chemistry
  • Cerium
  • Rare-Earth Metals
  • Inorganics
  • Catalysis and Inorganic Chemistry
  • Cerium Salts
  • CeriumMetal and Ceramic Science
  • Chemical Synthesis
  • Salts