CERIUM(III) CHLORIDE
- Product Name
- CERIUM(III) CHLORIDE
- CAS No.
- 7790-86-5
- Chemical Name
- CERIUM(III) CHLORIDE
- Synonyms
- CeCl3;CERIUM CHLORIDE;cerium chloride anhydrous;Cerium trichloride heptahydrate;Cerium(III) trichloride;Anhydrous Cerium Chloride;CEROUS CHLORIDE;trichloroceriuM;Cerium(III) chL;ceriumtrichloride
- CBNumber
- CB0120131
- Molecular Formula
- CeCl3
- Formula Weight
- 246.48
- MOL File
- 7790-86-5.mol
CERIUM(III) CHLORIDE Property
- Melting point:
- 848 °C(lit.)
- Boiling point:
- 1727 °C
- Density
- 3.97 g/mL at 25 °C(lit.)
- Flash point:
- 1727°C
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- soluble in H2O, ethanol
- form
- beads
- color
- White to Pale Gray
- Specific Gravity
- 3.92
- Water Solubility
- Soluble in water, ethanol, acids and acetone.
- Sensitive
- Hygroscopic
- Crystal Structure
- UCl3 type
- crystal system
- Six sides
- Merck
- 14,1997
- Space group
- P63/m
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.745 0.745 0.431 90 90 120 0.2073 - Stability:
- Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
- InChIKey
- VYLVYHXQOHJDJL-UHFFFAOYSA-K
- CAS DataBase Reference
- 7790-86-5(CAS DataBase Reference)
- EPA Substance Registry System
- Cerium chloride (CeCl3) (7790-86-5)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 429406
- Product name
- Cerium(III) chloride
- Purity
- anhydrous, beads, 10 mesh, ≥99.99% trace metals basis
- Packaging
- 5g
- Price
- $158
- Updated
- 2024/03/01
- Product number
- 298190
- Product name
- Cerium(III) chloride
- Purity
- anhydrous, beads, 10 mesh, 99.9%
- Packaging
- 50g
- Price
- $439
- Updated
- 2024/03/01
- Product number
- C2058
- Product name
- Cerium(III) Chloride Anhydrous
- Purity
- >96.0%(T)
- Packaging
- 5g
- Price
- $42
- Updated
- 2024/03/01
- Product number
- C2058
- Product name
- Cerium(III) Chloride Anhydrous
- Purity
- >96.0%(T)
- Packaging
- 25g
- Price
- $117
- Updated
- 2024/03/01
- Product number
- 021112
- Product name
- Cerium(III) chloride, anhydrous, 99.5% (REO)
- Packaging
- 10g
- Price
- $83.9
- Updated
- 2024/03/01
CERIUM(III) CHLORIDE Chemical Properties,Usage,Production
Chemical Properties
Cerium(III) chloride is a white powder and is used for incandescent gas mantles, spectrography and polymerization of olefins.
Cerium(III) chloride is mainly used as catalyst for petroleum,automobile exhaust catalyst , also used as a raw material for the production of cerium metal and other cerium compounds.
Physical properties
White, very fine powder; hexagonal crystal system; heptahydrate is yellow orthogonal crystal and hygroscopic; density of anhydrous salt 3.97 g/cm3; melts at 817°C; vaporizes at 1,727°C; heptahydrate begins to lose water above 90°C and becomes anhydrous at about 230°C; soluble in water and alcohol; hexahydrate has greater solubility in these solvents.
Uses
Cerium(III) chloride is used in incandescent gas mantles, spectrography and polymerization of olefins. It acts as a Lewis acid and used in Friedel-Crafts alkylation and acylation reactions in organic synthesis. It is used as a precursor for the preparation of other cerium salts, such as cerium(III) trifluoromethanesulfonate.
Production Methods
Cerium(III) chloride is prepared by the reaction of hydrochloric acid with a cerium salt, such as cerium hydroxide or carbonate, followed by crystallization;
Ce(OH)3 + 3HCl → CeCl3 + 3H2O
Ce2(CO3)3 + 6HCl → 2CeCl3 + 3CO2 + 3H2O.
Flammability and Explosibility
Non flammable
reaction suitability
reagent type: catalyst
core: cerium
Safety Profile
Poison by intravenous, intraperitoneal, and subcutaneous routes. Moderately toxic by ingestion. See also CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-
CERIUM(III) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from CERIUM(III) CHLORIDE manufacturers
- Product
- Cerium Chloride Anhydrous 7790-86-5
- Price
- US $30.00/kg
- Min. Order
- 1kg
- Purity
- 99.99
- Supply Ability
- 500
- Release date
- 2024-09-03
- Product
- CERIUM(III) CHLORIDE 7790-86-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-10-28
- Product
- CERIUM(III) CHLORIDE 7790-86-5
- Price
- US $3.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10000
- Release date
- 2024-08-08