ChemicalBook > CAS DataBase List > 2-BROMO-N,N-DIMETHYLANILINE

2-BROMO-N,N-DIMETHYLANILINE

Product Name
2-BROMO-N,N-DIMETHYLANILINE
CAS No.
698-00-0
Chemical Name
2-BROMO-N,N-DIMETHYLANILINE
Synonyms
2-Bromo-N,N-dimethyL;2-bromo-N,N-dimethylben;2-BroMo-N,N-diMrthylaniline;n,n-dimethyl-2-bromoaniline;2-BROMO-N,N-DIMETHYLANILINE;O-BROMO-N,N-DIMETHYLANILINE;O-BROMO-N,N'-DIMETHYLANILINE;2-broMo-N,N-diMethylbenzenaMin;(2-bromophenyl)-dimethyl-amine;1-Bromo-2-dimethylaminobenzene
CBNumber
CB6437839
Molecular Formula
C8H10BrN
Formula Weight
200.08
MOL File
698-00-0.mol
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2-BROMO-N,N-DIMETHYLANILINE Property

Boiling point:
108°C 14mm
Density 
1.388
refractive index 
1.5745
Flash point:
108°C/14mm
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
clear liquid
pka
4.40±0.18(Predicted)
color 
Colorless to Light orange to Yellow
BRN 
2205741
InChI
InChI=1S/C8H10BrN/c1-10(2)8-6-4-3-5-7(8)9/h3-6H,1-2H3
InChIKey
ONMSBNJJCUCYED-UHFFFAOYSA-N
SMILES
C1(N(C)C)=CC=CC=C1Br
CAS DataBase Reference
698-00-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,N,T
Risk Statements 
36/37/38-42/43-50/53-40-36-33-23/24/25
Safety Statements 
26-36-61-60-36/37
RIDADR 
2810
WGK Germany 
3
HazardClass 
IRRITANT
PackingGroup 
Ⅲ
HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H319Causes serious eye irritation

H351Suspected of causing cancer

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
590517
Product name
2-Bromo-N,N-dimethylaniline
Purity
97%
Packaging
5g
Price
$24.64
Updated
2025/07/31
TCI Chemical
Product number
B3243
Product name
2-Bromo-N,N-dimethylaniline
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$64
Updated
2025/07/31
TCI Chemical
Product number
B3243
Product name
2-Bromo-N,N-dimethylaniline
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$190
Updated
2025/07/31
TRC
Product number
B700543
Product name
2-Bromo-N,N-dimethylaniline
Packaging
10mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J56736
Product name
2-Bromo-N,N-dimethylaniline
Packaging
10g
Price
$60
Updated
2021/12/16
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2-BROMO-N,N-DIMETHYLANILINE Chemical Properties,Usage,Production

Chemical Properties

Light yellow liquid

Uses

2-Bromo-N,N-dimethylaniline may be used in the synthesis of the following:

  • bis[(2-dimethylamino)phenyl]amine via a multi-step reaction procedure
  • 2-(N,N-dimethylaminophenyl)-bis(diethylamino)phosphine
  • 6-[2-(dimethylamino)phenyl]-2,2-bipyridine obtained via lithiation followed by reaction with 2,2-bipyridine
  • 1-(2′-(dimethylamino)phenyl)-2-diphenylphosphino-3-methylimidazolium trifluoromethanesulfonate via a multi-step reaction procedure

Uses

suzuki reaction

Synthesis

615-36-1

74-88-4

698-00-0

In a 250 mL round bottom flask, 4.0 g (23.3 mmol) of o-bromoaniline, 16.1 g (116.5 mmol) of anhydrous potassium carbonate, 7.3 mL (116.5 mmol) of iodomethane, and 50 mL of acetonitrile were added sequentially. The reaction mixture was heated to 70 °C and stirred at this temperature for 18 hours. Upon completion of the reaction, the mixture was cooled to room temperature. Subsequently, extraction was carried out with 100 mL of deionized water and 100 mL of diethyl ether. After separation of the organic phase, the aqueous phase was further washed with 3 x 50 mL of ether. All organic phases were combined and washed with 5 x 50 mL saturated saline. The organic phase was dried over anhydrous magnesium sulfate and then distilled under reduced pressure to remove the volatile solvent to obtain the crude product. The crude product was purified by silica gel column chromatography with the eluent of ether/hexane (5/95 v/v), resulting in 2.7 g of light yellow oily liquid product in 69% yield. The characterization data of the obtained product were consistent with those reported in the literature.

References

[1] Organic Letters, 2009, vol. 11, # 22, p. 5130 - 5133
[2] Organic Letters, 2014, vol. 16, # 14, p. 3832 - 3835
[3] Journal of Organic Chemistry, 2008, vol. 73, # 16, p. 6330 - 6340
[4] Patent: CN108586536, 2018, A. Location in patent: Paragraph 0011-0012; 0034-0036; 0038
[5] Chemische Berichte, 1907, vol. 40, p. 2528

2-BROMO-N,N-DIMETHYLANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-N,N-DIMETHYLANILINE Suppliers

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View Lastest Price from 2-BROMO-N,N-DIMETHYLANILINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
2-Bromo-N,N-dimethylaniline 698-00-0
Price
US $2.20-8.80/kg
Min. Order
1kg
Purity
99%min
Supply Ability
100kg
Release date
2025-08-29
Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
2-bromo-N,N-dimethylaniline 698-00-0
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-08-16
Longyan Tianhua Biological Technology Co., Ltd
Product
2-BROMO-N,N-DIMETHYLANILINE 698-00-0
Price
US $750.00/KG
Min. Order
1KG
Purity
99
Supply Ability
10000KG
Release date
2020-11-09

698-00-0, 2-BROMO-N,N-DIMETHYLANILINERelated Search:

1-(2-BROMO-PHENYL)-PYRROLE-2,5-DIONE 2-BROMO-N,N-DIMETHYLANILINE 3-BROMO-N,N-DIMETHYLANILINE 2-BROMO-4,6-DIMETHYLANILINE,2-Bromo-4,6-dimethylaniline, 98+%,6-Bromo-2,4-dimethylaniline 4-BROMO-N,N-DIMETHYLANILINE 98.5+%,4-Bromo-N,N-dimethylaniline, 98+%,P-BROMO-N,N-DIMETHYLANILINE,4-BROMO-N,N-DIMETHYLANILINE 4-BROMO-2,5-DIMETHYLANILINE,4-Bromo-2,5-dimethylaniline 96% 2,4-DIBROMO-3,6-DIMETHYLANILINE 4-Bromo-2,3-dimethylaniline 98%,4-BROMO-2,3-DIMETHYLANILINE 4-bromo-2,6-dimethylaniline,98 DIMETHYLANILINE 1-(2-bromophenyl)pyrrolidin-2-one 3-bromo-4-dimethylamino-benzaldehyde 2-bromo-N,N-dimethyl-4-nitroaniline N-(2-BROMOPHENYL)PHTHALIMIDE CHEMBRDG-BB 5226017 4-BROMO-2,5-DIMETHYLANILINE HYDROCHLORIDE 4-bromo-N,2-dimethylaniline 5-BROMO-2,4-DIMETHYLANILINE

  • Benzenamine, 2-bromo-N,N-dimethyl-
  • O-BROMO-N,N'-DIMETHYLANILINE
  • O-BROMO-N,N-DIMETHYLANILINE
  • 2-BROMO-N,N-DIMETHYLANILINE
  • (2-bromophenyl)-dimethyl-amine
  • n,n-dimethyl-2-bromoaniline
  • 2-Bromo-N,N-dimethylaniline, 98+%
  • 2-bromo-N,N-dimethylbenzenamine
  • 2-BroMo-N,N-diMrthylaniline
  • 2-broMo-N,N-diMethylbenzenaMin
  • 2-broMo -N,aretwo Methyl aniline
  • 2-Bromo-N,N-dimethylaniline 97%
  • 1-Bromo-2-dimethylaminobenzene
  • 2-bromo-N,N-dimethylben
  • 2-Bromo-N,N-dimethyL
  • 2-Bromo-N,N-dimethylaniline &gt
  • 2-BROMO-N,N-DIMETHYLANILINE ISO 9001：2015 REACH
  • 2-Bromo-<i>N</i>,<i>N</i>-dimethylaniline
  • 2-Bromo-N,N-dimethylaniline, 97%
  • 698-00-0
  • C8
  • Amines
  • Building Blocks
  • Organic Building Blocks
  • Nitrogen Compounds
  • Amines
  • C8
  • Nitrogen Compounds