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BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE

Product Name
BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE
CAS No.
12116-66-4
Chemical Name
BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE
Synonyms
bis(cyclopentadienyl)hafnium(iv) dichloride;HAFNOCENE DICHLORIDE;dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-hafniu;HafnoceneDichloride>Hafnocene dichloride,98%;HAFNOCENE DICHLORIDE 97+%;Dichlorodicyclopentadienylhafnium;hafniumdicyclopentadienedichloride;Hafnium dicyclopentadiene dichloride;Dichlorodi-p-cyclopentadienylhafnium
CBNumber
CB6450654
Molecular Formula
C10H10Cl2Hf10*
Formula Weight
379.58
MOL File
12116-66-4.mol
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BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Property

Melting point:
230-233 °C
Boiling point:
339.81°C (rough estimate)
solubility 
Soluble in aromatic solvents, chloroform; slightly soluble in THF, ether. Insolble in hexanes.
form 
crystal
color 
off-white
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Exposure limits
ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
CAS DataBase Reference
12116-66-4(CAS DataBase Reference)
NIST Chemistry Reference
Bis(«eta»5-cyclopentadienyl)hafnium dichloride(12116-66-4)
EPA Substance Registry System
Hafnium, dichlorobis(.eta.5-2,4-cyclopentadien-1-yl)- (12116-66-4)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-37/39
RIDADR 
UN3261
WGK Germany 
3
RTECS 
MG4815000
10-21
TSCA 
Yes
HS Code 
2931.90.9051
HazardClass 
8
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
119334
Product name
Bis(cyclopentadienyl)hafnium(IV) dichloride
Purity
98%
Packaging
1g
Price
$67.6
Updated
2024/03/01
Sigma-Aldrich
Product number
119334
Product name
Bis(cyclopentadienyl)hafnium(IV) dichloride
Purity
98%
Packaging
10g
Price
$360
Updated
2024/03/01
TCI Chemical
Product number
H0914
Product name
Hafnocene Dichloride
Purity
>98.0%(T)
Packaging
1g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
H0914
Product name
Hafnocene Dichloride
Purity
>98.0%(T)
Packaging
5g
Price
$165
Updated
2024/03/01
Alfa Aesar
Product number
036105
Product name
Bis(cyclopentadienyl)hafnium dichloride
Packaging
1g
Price
$56.4
Updated
2023/06/20
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BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Chemical Properties,Usage,Production

Chemical Properties

white to light brown crystals or crystalline

Uses

Starting material to prepare many kinds of hafnocene(II or IV) derivatives; in combination with AgI salt, is an effective activator for glycosyl fluoride. Pharmaceutical intermediates and alos used in chemical research.

reaction suitability

core: hafnium
reagent type: catalyst

BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE Suppliers

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12116-66-4, BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDERelated Search:


  • dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-hafniu
  • dichlorobis(eta5-2,4-cyclopentadien-1-yl)-hafniu
  • Dichlorobis(eta-cyclopentadienyl)hafnium
  • Dichlorodicyclopentadienylhafnium
  • dichlorodi-pi-cyclopentadienyl-hafniu
  • Dichlorodi-pi-cyclopentadienylhafnium
  • Hafnium dicyclopentadiene dichloride
  • Hafnium, dichlorobis(eta(5)-2,4-cyclopentadien-1-yl)-
  • Hafnium, dichlorodi-pi-cyclopentadienyl-
  • hafniumdicyclopentadienedichloride
  • Hafnocene dichloride (dichlorodicyclopentadienyl)hafnium
  • Bis(cyclopentadienyl)hafniumdichloride,min.98%(Hafnocenedichloride)
  • dichlorobis(eta5-cyclopenta-2,4-dien-1-yl)hafnium
  • Bis(cyclopentadienyl)hafnium dichloride, (Hafnocene dichloride)
  • HAFNOCENE DICHLORIDE 97+%
  • BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE
  • DI(CYCLOPENTA-DIENYL)HAFNIUM DICHLORIDE
  • HAFNOCENE DICHLORIDE
  • bis(cyclopentadienyl)hafnium(iv) dichloride
  • di(cyclopentadienyl)hafnium(iv) dichloride
  • Bis(cyclopentadienyl)hafnium dichloride, Di(cyclopentadienyl)hafnium dichloride
  • Di(cyclopentadienyl)hafnium(IV) dichloride, Hafnocene dichloride
  • Hafnocene dichloride,98%
  • dichlorobis(η5-cyclopenta-2,4-dien-1-yl)hafnium
  • Hafnocene dichloride,Bis(cyclopentadienyl)hafnium dichloride, Di(cyclopentadienyl)hafnium dichloride
  • Bis(cyclopentadienyl)hafnium(IV) dichloride,Di(cyclopentadienyl)hafnium(IV) dichloride, Hafnocene dichloride
  • Bis(cyclopentadienyl)hafnium dichloride, 98+% (Hafnocene dichloride)
  • Bis(cyclopentadienyl)hafnium(IV) dichloride 98%
  • bis(η-cyclopentadienyl)-hafniumchloride
  • Dichloro[di(2,4-cyclopentadien-1-yl)]hafnium
  • HafnoceneDichloride&gt
  • BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE ISO 9001:2015 REACH
  • hafnium(4+) bis(cyclopenta-2,4-dien-1-ide) dichloride
  • Di(cyclopenta-1,3-dien-1-yl)hafnium(IV) Chloride
  • Dichlorodi-p-cyclopentadienylhafnium
  • 12116-66-4
  • C10H10Cl2Hf
  • C5H52HfCl2
  • Hafnium
  • Catalysis and Inorganic Chemistry
  • metallocene
  • Biochemistry
  • Classes of Metal Compounds
  • Hf (Hafnium) Compounds
  • Metallocenes
  • Reagents for Oligosaccharide Synthesis
  • Titanocene, etc.
  • Transition Metal Compounds