Hafnium(IV) chloride

Product Name: Hafnium(IV) chloride
CAS No.: 13499-05-3
Chemical Name: Hafnium(IV) chloride
Synonyms: HfCl4;HAFNIUM TETRACHLORIDE;HAFNIUM CHLORIDE;Hafnium chloride(HfCl4);1.0% Zr);0.05% Zr);JACS-13499-05-3;Hafnium(IV) chL;Tetrachlorohafnium;Hafniumtetrachlorid
CBNumber: CB0731544
Molecular Formula: Cl4Hf
Formula Weight: 320.3
MOL File: 13499-05-3.mol

More

Less

Hafnium(IV) chloride Property

Melting point:: 432 °C (lit.)
Boiling point:: 315.47°C (estimate)
Density: 1.89 g/cm3
vapor pressure: 1 mm Hg ( 190 °C)
storage temp.: Inert atmosphere,Room Temperature
solubility: Soluble in methanol and acetone.
form: Powder
color: White
Water Solubility: Soluble in water, methanol and acetone.
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Sensitive: Moisture Sensitive
Merck: 14,4588
Exposure limits: ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
InChIKey: PDPJQWYGJJBYLF-UHFFFAOYSA-J
CAS DataBase Reference: 13499-05-3(CAS DataBase Reference)
EPA Substance Registry System: Hafnium chloride (HfCl4), (T-4)- (13499-05-3)

More

Less

Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
F: 9-21
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 28273985

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 258202
Product name: Hafnium(IV) chloride
Purity: 98%
Packaging: 10g
Price: $40.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 258202
Product name: Hafnium(IV) chloride
Purity: 98%
Packaging: 50g
Price: $120
Updated: 2024/03/01

Alfa Aesar

Product number: 011834
Product name: Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr <2.7%
Packaging: 2.5g
Price: $19.1
Updated: 2023/06/20

Alfa Aesar

Product number: 011834
Product name: Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr <2.7%
Packaging: 25g
Price: $62.9
Updated: 2023/06/20

Strem Chemicals

Product number: 72-0751
Product name: Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr)
Packaging: 10g
Price: $70
Updated: 2024/03/01

More

Less

Hafnium(IV) chloride Chemical Properties,Usage,Production

Chemical Properties

Hafnium(IV) chloride is the inorganic compound with the formula HfCl4. This colourless solid is the precursor to most hafnium organometallic compounds. It has a variety of highly specialized applications, mainly in materials science and as a catalyst.

Physical properties

White monoclinic crystal; sublimes at 317°C; melts at 432°C at 33 atm (triple point); critical temperature 452.5°C; critical pressure 53.49 atm; critical volume 314 cm3/mol.

Uses

Hafnium tetrachloride is an important intermediate in production of hafnium metal. It also is used to prepare many hafnium compounds.

Uses

Hafnium chloride tetrahydrofuran complex is an efficient catalyst for the Diels-Alder cycloadditions, Ziegler-Natta polymerization of alkenes. It is used as control rods in nuclear reactors and in manufacture of light bulb filaments.

Uses

Hafnium (IV) chloride can be used to catalyze the direct ester condensation of carboxylic acids with alcohols effectively.

Preparation

Hafnium(IV) chloride can be prepared
(i) by chlorination of hafnium dioxide in the presence of carbon:
HfO₂ + 2Cl₂ + C → HfCl₄ + 2CO
It also may be prepared by several other methods, such as
(ii) reaction of carbon tetrachloride with hafnium dioxide above 450°C;
(iii) heating a mixture of hafnium dioxide and carbon above 700°C;
and (iv) reaction of chlorine with hafnium at elevated temperatures.

Reactions

Hafnium(IV) chloride hydrolyzes, evolving hydrogen chloride:
HfCl4 + H2O→ HfOCl2+ 2 HCl
Aged samples thus often are contaminated with oxychlorides, which are also colourless.
THF forms a monomeric 2:1 complex:
HfCl4+ 2 OC4H8→HfCl4(OC4H8)2

Flammability and Explosibility

Non flammable

Solubility in organics

Soluble in methanol, acetone, reacts strongly with water, highly hygroscopic, hydrolyzes in water.

Structure and conformation

This group 4 halide contains hafnium in the +4 oxidation state. Solid Hafnium(IV) chloride is a polymer with octahedral Hf centers. Of the six chloride ligands surrounding each Hf centre, two chloride ligands are terminal and four bridge to another Hf centre.

Hafnium(IV) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Hafnium(IV) chloride Suppliers

Belgium 1 CHINA 139 Germany 2 India 4 Japan 4 Russia 1 South Korea 1 Switzerland 1 United Kingdom 6 United States 21 Global 180

Henan Jiuke Chemical Co. LTD

Tel: 0370-2071226 17303700913
Fax: 0370-2071226
Email: 954866649@qq.com
Country: China
ProdList: 2987
Advantage: 58

Hubei Changxinsheng Pharm Co.,Ltd

Tel: 18971203904; 18971238634
Email: 2189484023@qq.com
Country: China
ProdList: 495
Advantage: 58

BeiJing Hwrk Chemicals Limted

Tel: 0757-86329057 18501085097
Fax: 010-89508210
Email: sales3.gd@hwrkchemical.com
Country: China
ProdList: 7583
Advantage: 55

Hangzhou Kaiyada Semiconductor Materials Co., LTD

Tel: 19817475709
Email: 751526170@qq.com
Country: China
ProdList: 474
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94838
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1937
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11714
Advantage: 57

More

Less

View Lastest Price from Hafnium(IV) chloride manufacturers

Hebei Saisier Technology Co., LTD

Product: HAFNIUM CHLORIDE 13499-05-3
Price: US $6.00/KG
Min. Order: 25KG
Purity: More than 99%
Supply Ability: 2000KG/Month
Release date: 2024-04-02

Hebei Jingbo New Material Technology Co., Ltd

Product: Hafnium(IV) chloride 13499-05-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000000
Release date: 2024-01-05

WUXI HONOR SHINE CHEMICAL CO.,LTD

Product: HAFMIUM TETRACHLORIDE Electrical grade 13499-05-3
Price: US $0.00/Kg/Drum
Min. Order: 10Kg/Drum
Purity: 99.5%
Supply Ability: 300tons
Release date: 2022-06-10

13499-05-3, Hafnium(IV) chlorideRelated Search:

Zirconium tetrachloride Zirconyl chloride octahydrate Hafnium oxide Titanium tetrachloride Carbon tetrachloride VANADIUM(III) CHLORIDE HAFNIUM OXYCHLORIDE BIS(PENTAMETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(ISOPROPYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE HAFNIUM DICHLORIDE OXIDE Pentamethylcyclopentadienylhafnium trichloride CYCLOPENTADIENYLHAFNIUM TRICHLORIDE BIS(T-BUTYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(ETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE Hafnium(IV) chloride HAFNIUM HAFNIUM CHLORIDE TETRAHYDROFURAN COMPLEX (1:2) Hafnium Chloride

Hafnium Chloride 98+%

HafniuM(IV) chloride, -80 Mesh, 99% 25GR

HafniuM(IV) chloride 98%

HafniuM(IV) chloride purified by subliMation, 99.9% trace Metals basis

Hafnium(IV) chloride, 99.9% trace metals basis excluding Zr

Hafnium(IV) chloride, 98% trace metals basis excluding Zr

HAFNIUM(IV) CHLORIDE

HAFNIUM CHLORIDE

HAFNIUM TETRACHLORIDE

JACS-13499-05-3

(beta-4)-hafniumchloride(hfcl4

Hafnium chloride (HfCl4), (T-4)-

HfCl4

HAFNIUM CHLORIDE, SUBLIMED, 99.9%

HAFNIUM (IV) CHLORIDE ANHYDROUS 98+% (1-3% ZR)

HAFNIUM (IV) CHLORIDE SUBLIMED GRADE (99.9+%-HF, <1.0% ZR)

HAFNIUM (IV) CHLORIDE, SUBLIMED GRATE (99.9+%-HF, <0.5% ZR)

HAFNIUM CHLORIDE ANHYDROUS

Hafnium(IV) chloride, -80 mesh, 99%

Hafnium(IV)chloride,sublimedgrade(99.9+%-Hf,<0.05%Zr)

HAFNIUM(IV) CHLORIDE, ANHYDROUS (1-3% ZR)

Hafnium chloride, 98+% (metals basis excluding Zr), Zr 2.7%

Hafnium tetrachloride, sublimed: 99.95% (Hf+Zr)Cl4ü

Hafnium chloride, 99%, 80 mesh

Hafnium chloride(HfCl4)

Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr 2.7%

HAFNIUM CHLORIDE, 98.5%

Hafnium(IV) chloride,99%,-80 mesh

Hafnium(IV) chloride, 99.9% (metals basis), Zr<0.5%

HAFNIUMANDITSCOMPOUNDS

(beta-4)-hafnium chloride

Hafnium(IV) chloride 98+%

Hafniumtetrachlorid

Hafnium tetrachloride(HfCl4)

Hafnium(Ⅳ) Chloride, 99.5%

Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, &lt

1.0% Zr)

0.05% Zr)

Hafnium(IV) chL

Hafnium chloride powder (HfCl4)

Tetrachlorohafnium

HAFMIUM TETRACHLORIDE Electrical grade

Hafnium chloride, 99.9%

Hafnium chloride lump (HfCl4)

HAFNIUM CHLORIDE 13499-05-3

13499-05-3

Cl4Hf

Crystal Grade Inorganics

HafniumMetal and Ceramic Science

Hafnium Salts

Metal and Ceramic Science

Salts

straight chain compounds

metal halide