Hafnium(IV) chloride

ChemicalBook > CAS DataBase List > Hafnium(IV) chloride

Hafnium(IV) chloride

Product Name: Hafnium(IV) chloride
CAS No.: 13499-05-3
Chemical Name: Hafnium(IV) chloride
Synonyms: HfCl4;HAFNIUM TETRACHLORIDE;HAFNIUM CHLORIDE;Hafnium chloride(HfCl4);1.0% Zr);0.05% Zr);Formula HfCl4;JACS-13499-05-3;Hafnium(IV) chL;Tetrachlorohafnium
CBNumber: CB0731544
Molecular Formula: Cl4Hf
Formula Weight: 320.3
MOL File: 13499-05-3.mol

Less

Hafnium(IV) chloride Property

Melting point:

432 °C (lit.)

Boiling point:

315.47°C (estimate)

Density

1.89 g/cm3

vapor pressure

1 mm Hg ( 190 °C)

storage temp.

Inert atmosphere,Room Temperature

solubility

Soluble in methanol and acetone.

form

Powder

color

White

Water Solubility

Soluble in water, methanol and acetone.

Sensitive

Moisture Sensitive

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

crystal system

Monoclinic

Merck

14,4588

Space group

P2/c

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.6327	0.7377	0.62	90	109.05	90	0.2735

Exposure limits

ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3

InChIKey

PDPJQWYGJJBYLF-UHFFFAOYSA-J

CAS DataBase Reference

13499-05-3(CAS DataBase Reference)

EPA Substance Registry System

Hafnium chloride (HfCl4), (T-4)- (13499-05-3)

Less

Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
F: 9-21
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 28273985

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 258202
Product name: Hafnium(IV) chloride
Purity: 98%
Packaging: 10g
Price: $40.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 258202
Product name: Hafnium(IV) chloride
Purity: 98%
Packaging: 50g
Price: $120
Updated: 2024/03/01

Alfa Aesar

Product number: 011834
Product name: Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr <2.7%
Packaging: 2.5g
Price: $19.1
Updated: 2023/06/20

Alfa Aesar

Product number: 011834
Product name: Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr <2.7%
Packaging: 25g
Price: $62.9
Updated: 2023/06/20

Strem Chemicals

Product number: 72-0751
Product name: Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr)
Packaging: 10g
Price: $70
Updated: 2024/03/01

Less

Hafnium(IV) chloride Chemical Properties,Usage,Production

Chemical Properties

Hafnium(IV) chloride is the inorganic compound with the formula HfCl4. This colourless solid is the precursor to most hafnium organometallic compounds. It has a variety of highly specialized applications, mainly in materials science and as a catalyst.

Physical properties

White monoclinic crystal; sublimes at 317°C; melts at 432°C at 33 atm (triple point); critical temperature 452.5°C; critical pressure 53.49 atm; critical volume 314 cm3/mol.

Uses

Hafnium tetrachloride is an important intermediate in production of hafnium metal. It also is used to prepare many hafnium compounds.

Uses

Hafnium chloride tetrahydrofuran complex is an efficient catalyst for the Diels-Alder cycloadditions, Ziegler-Natta polymerization of alkenes. It is used as control rods in nuclear reactors and in manufacture of light bulb filaments.

Uses

Hafnium (IV) chloride can be used to catalyze the direct ester condensation of carboxylic acids with alcohols effectively.

Preparation

Hafnium(IV) chloride can be prepared
(i) by chlorination of hafnium dioxide in the presence of carbon:
HfO₂ + 2Cl₂ + C → HfCl₄ + 2CO
It also may be prepared by several other methods, such as
(ii) reaction of carbon tetrachloride with hafnium dioxide above 450°C;
(iii) heating a mixture of hafnium dioxide and carbon above 700°C;
and (iv) reaction of chlorine with hafnium at elevated temperatures.

Reactions

Hafnium(IV) chloride hydrolyzes, evolving hydrogen chloride:
HfCl4 + H2O→ HfOCl2+ 2 HCl
Aged samples thus often are contaminated with oxychlorides, which are also colourless.
THF forms a monomeric 2:1 complex:
HfCl4+ 2 OC4H8→HfCl4(OC4H8)2

Flammability and Explosibility

Non flammable

Solubility in organics

Soluble in methanol, acetone, reacts strongly with water, highly hygroscopic, hydrolyzes in water.

Structure and conformation

This group 4 halide contains hafnium in the +4 oxidation state. Solid Hafnium(IV) chloride is a polymer with octahedral Hf centers. Of the six chloride ligands surrounding each Hf centre, two chloride ligands are terminal and four bridge to another Hf centre.

Hafnium(IV) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Less

Hafnium(IV) chloride Suppliers

Belgium 1 CHINA 162 Germany 2 India 4 Japan 4 Russia 1 South Korea 1 Switzerland 1 United Kingdom 6 United States 22 Global 204

Henan Jiuke Chemical Co. LTD

Tel: 0370-2071226 17303700913
Fax: 0370-2071226
Email: 954866649@qq.com
Country: China
ProdList: 2982
Advantage: 58

Hubei Changxinsheng Pharm Co.,Ltd

Tel: 18971238634
Email: 2189484023@qq.com
Country: China
ProdList: 490
Advantage: 58

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

Hangzhou Kaiyada Semiconductor Materials Co., LTD

Tel: 19817475709
Email: 751526170@qq.com
Country: China
ProdList: 474
Advantage: 58

Shanghai wechem chemical co., ltd

Tel: 18824865657
Fax: 021-6192 7501
Email: joey.lin@wechem.cn
Country: China
ProdList: 507
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1931
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11707
Advantage: 57

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

Beijing innoChem Science & Technology Co.,Ltd.

Tel: 400-810-7969 010-59572699
Fax: 010-59572688
Email: ningzi.li@inno-chem.com.cn
Country: China
ProdList: 6134
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Shanghai Meishui Chemical Technology Co., Ltd

Tel: 021-60549325 18616193163
Fax: 021-33250306
Country: China
ProdList: 4526
Advantage: 56

Shanghai DiBai Chemicals Co., Ltd.

Tel: 021-54359730 400-008-9730
Fax: 021-54353864
Email: info@chemxyz.com
Country: China
ProdList: 3991
Advantage: 60

WUXI HONORSHINE CHEMICAL CO.,LTD.

Tel: 0510-83593312 13665125081
Fax: 0510-83574508
Email: sales@honorshinechem.com
Country: China
ProdList: 52
Advantage: 60

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 16166
Advantage: 55

Hangzhou J&H Chemical Co., Ltd.

Tel: 0571-+86-571-87396432
Fax: 0571-87396431
Email: sales@jhechem.com
Country: China
ProdList: 11578
Advantage: 59

Chizhou Kailong Import and Export Trade Co., Ltd.

Tel
Fax: -
Email: xg01_gj@163.com
Country: China
ProdList: 9484
Advantage: 50

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51456
Advantage: 80

Forsman Scientific ( Beijing ) Co., Ltd.

Tel: 13811783941 18611317957
Fax: +86-10-64646568
Email: linwp@forsman.com.cn
Country: China
ProdList: 851
Advantage: 58

Hangzhou Dingyan Chem Co., LTD

Tel: 0571-87157530-8007 13868066926
Fax: 0571-87156470
Email: sales@dingyanchem.com
Country: China
ProdList: 2190
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2886750 13927877953
Fax: 0751-2886750
Email: 3005811397@qq.com
Country: China
ProdList: 13320
Advantage: 58

Shanghai Witofly Chemical Co. ,Ltd.

Tel: 021-5063062 15821189163
Email: sales@witofly.com
Country: China
ProdList: 1604
Advantage: 55

Taian Jiaye Biotechnology Co.Ltd

Tel: 13127280945
Email: 285424065@qq.com
Country: China
ProdList: 9976
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19800
Advantage: 60

Shanghai BaiShun Biological Technology Co., Ltd

Tel: 021-37581181
Fax: 021-57456066
Email: sales@chem-mall.com
Country: China
ProdList: 10330
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718 +86-13336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29793
Advantage: 60

Aikon International Limited

Tel: 025-66113011 18112977050
Fax: (5)02557626880
Email: cb6@aikonchem.com
Country: China
ProdList: 15494
Advantage: 58

Rhawn Reagent

Tel: 400-400-1332688 18019345275
Fax: 400-133-2688
Email: amy@rhawn.cn
Country: China
ProdList: 15497
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 18016230971
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 25004
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6037 18920794737
Email: sales@heowns.com
Country: China
ProdList: 22961
Advantage: 60

Henan Alfachem Co.,Ltd.

Tel: 0371-0371-55051623 18137891487
Fax: QQ：2853979817
Email: 2853979817@qq.com
Country: China
ProdList: 9936
Advantage: 58

3A Chemicals

Tel: 400-668-9898
Fax: 010-51582189
Email: service@3achem.com
Country: China
ProdList: 20557
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 4009004166/18616739031 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52693
Advantage: 58

Beijing OKA biological technology co., LTD

Tel: 010-010-010-62971590 18548936886
Fax: 010-62340519
Email: jack@oka-vip.com
Country: China
ProdList: 6897
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2815688 13927872512
Fax: 0751-8963795
Email: 3007421951@qq.com
Country: China
ProdList: 10057
Advantage: 58

SHANDONG ZHI SHANG CHEMICAL CO.LTD

Tel: +86 18953170293
Fax: +86 0531-67809011
Email: sales@sdzschem.com
Country: China
ProdList: 2930
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel
Country: China
ProdList: 11664
Advantage: 58

ANHUI WITOP BIOTECH CO., LTD

Tel: +8615255079626
Email: eric@witopchemical.com
Country: China
ProdList: 23541
Advantage: 58

ShanDong Look Chemical Co.,Ltd.

Tel: +8617653113219
Email: sales01@sdlookchemical.com
Country: China
ProdList: 2737
Advantage: 58

Hubei Ipure Biology Co., Ltd

Tel: +8613367258412
Fax: 18062427325
Email: ada@ipurechemical.com
Country: China
ProdList: 10319
Advantage: 58

Zhuoer Chemical Co., Ltd

Tel: 02120970332; +8613524231522
Fax: +86-21-58816016
Email: sales@zhuoerchem.com
Country: China
ProdList: 2904
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: China
ProdList: 52849
Advantage: 58

HONG KONG IPURE BIOLOGY CO.,LIMITED

Tel: 86 18062405514 18062405514
Email: ada@ipurechemical.com
Country: CHINA
ProdList: 3461
Advantage: 58

HUNAN CHEMFISH SCIENTIFIC CO.,LTD

Tel: +86-0731-85567275 18932438858
Fax: QQ:3554193828
Email: sales05@chemfish.com
Country: China
ProdList: 8305
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23912
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28172
Advantage: 58

Wuhan Hongde Yuexin Pharmatech Co.,Ltd

Tel: 027-83855393 15071227934
Fax: 027-83855393
Email: 3306264753@qq.com
Country: China
ProdList: 3227
Advantage: 58

Less

View Lastest Price from Hafnium(IV) chloride manufacturers

Hebei Longbang Technology Co., Ltd

Product: HAFNIUM CHLORIDE 13499-05-3
Price: US $5.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20TONS
Release date: 2024-05-11

Hebei Jingbo New Material Technology Co., Ltd

Product: Hafnium(IV) chloride 13499-05-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000000
Release date: 2024-01-05

WUXI HONOR SHINE CHEMICAL CO.,LTD

Product: HAFMIUM TETRACHLORIDE Electrical grade 13499-05-3
Price: US $0.00/Kg/Drum
Min. Order: 10Kg/Drum
Purity: 99.5%
Supply Ability: 300tons
Release date: 2022-06-10

13499-05-3, Hafnium(IV) chlorideRelated Search:

Zirconium tetrachloride Zirconyl chloride octahydrate Hafnium oxide Titanium tetrachloride Carbon tetrachloride VANADIUM(III) CHLORIDE HAFNIUM OXYCHLORIDE BIS(PENTAMETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(ISOPROPYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE HAFNIUM DICHLORIDE OXIDE Pentamethylcyclopentadienylhafnium trichloride CYCLOPENTADIENYLHAFNIUM TRICHLORIDE BIS(T-BUTYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE BIS(ETHYLCYCLOPENTADIENYL)HAFNIUM DICHLORIDE Hafnium(IV) chloride HAFNIUM HAFNIUM CHLORIDE TETRAHYDROFURAN COMPLEX (1:2) Hafnium Chloride

Hafnium Chloride 98+%

HafniuM(IV) chloride, -80 Mesh, 99% 25GR

HafniuM(IV) chloride 98%

HafniuM(IV) chloride purified by subliMation, 99.9% trace Metals basis

Hafnium(IV) chloride, 99.9% trace metals basis excluding Zr

Hafnium(IV) chloride, 98% trace metals basis excluding Zr

HAFNIUM(IV) CHLORIDE

HAFNIUM CHLORIDE

HAFNIUM TETRACHLORIDE

JACS-13499-05-3

(beta-4)-hafniumchloride(hfcl4

Hafnium chloride (HfCl4), (T-4)-

HfCl4

HAFNIUM CHLORIDE, SUBLIMED, 99.9%

HAFNIUM (IV) CHLORIDE ANHYDROUS 98+% (1-3% ZR)

HAFNIUM (IV) CHLORIDE SUBLIMED GRADE (99.9+%-HF, <1.0% ZR)

HAFNIUM (IV) CHLORIDE, SUBLIMED GRATE (99.9+%-HF, <0.5% ZR)

HAFNIUM CHLORIDE ANHYDROUS

Hafnium(IV) chloride, -80 mesh, 99%

Hafnium(IV)chloride,sublimedgrade(99.9+%-Hf,<0.05%Zr)

HAFNIUM(IV) CHLORIDE, ANHYDROUS (1-3% ZR)

Hafnium chloride, 98+% (metals basis excluding Zr), Zr 2.7%

Hafnium tetrachloride, sublimed: 99.95% (Hf+Zr)Cl4ü

Hafnium chloride, 99%, 80 mesh

Hafnium chloride(HfCl4)

Hafnium(IV) chloride, 98+% (metals basis excluding Zr), Zr 2.7%

HAFNIUM CHLORIDE, 98.5%

Hafnium(IV) chloride,99%,-80 mesh

Hafnium(IV) chloride, 99.9% (metals basis), Zr<0.5%

HAFNIUMANDITSCOMPOUNDS

(beta-4)-hafnium chloride

Hafnium(IV) chloride 98+%

Hafniumtetrachlorid

Hafnium tetrachloride(HfCl4)

Hafnium(Ⅳ) Chloride, 99.5%

Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, &lt

1.0% Zr)

0.05% Zr)

Hafnium(IV) chL

Hafnium chloride powder (HfCl4)

Tetrachlorohafnium

HAFMIUM TETRACHLORIDE Electrical grade

Hafnium chloride, 99.9%

Hafnium chloride lump (HfCl4)

HAFNIUM CHLORIDE 13499-05-3

Formula HfCl4

13499-05-3

Cl4Hf

Crystal Grade Inorganics

HafniumMetal and Ceramic Science

Hafnium Salts

Metal and Ceramic Science

Salts

straight chain compounds

metal halide