ChemicalBook > CAS DataBase List > METHYL 2-FLUOROBENZOATE

METHYL 2-FLUOROBENZOATE

Product Name
METHYL 2-FLUOROBENZOATE
CAS No.
394-35-4
Chemical Name
METHYL 2-FLUOROBENZOATE
Synonyms
RARECHEM AL BF 0016;METHYL 2-FLUOROBENZO;METHYL O-FLUOROBENZOATE;METHYL 2-FLUOROBENZOATE;Methyl2-fluorobenzoate,98%;Methyl 2-fluorobenzoate 98%;Methyl 2-fluorobenzoic acid;2-fluoro-benzoicacimethylester;2-FLUOROBENZOIC ACID METHYL ESTER;o-Fluorobenzoic acid, methyl ester
CBNumber
CB6478681
Molecular Formula
C8H7FO2
Formula Weight
154.14
MOL File
394-35-4.mol
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METHYL 2-FLUOROBENZOATE Property

Melting point:
93°C
Boiling point:
109-110 °C/35 mmHg (lit.)
Density 
1.21 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.502(lit.)
Flash point:
201 °F
storage temp. 
Sealed in dry,Room Temperature
form 
clear liquid
Specific Gravity
1.210
color 
Colorless to Almost colorless
BRN 
1862493
InChI
InChI=1S/C8H7FO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3
InChIKey
QAFJIJWLEBLXHH-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC=C1F
CAS DataBase Reference
394-35-4(CAS DataBase Reference)
EPA Substance Registry System
Benzoic acid, 2-fluoro-, methyl ester (394-35-4)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
36/38
Safety Statements 
26-36/37/39-37
RIDADR 
UN3272
WGK Germany 
3
Hazard Note 
Toxic
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
528951
Product name
Methyl 2-fluorobenzoate
Purity
97%
Packaging
5g
Price
$73.4
Updated
2023/06/20
TCI Chemical
Product number
F0241
Product name
Methyl 2-Fluorobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$32
Updated
2024/03/01
TCI Chemical
Product number
F0241
Product name
Methyl 2-Fluorobenzoate
Purity
>98.0%(GC)
Packaging
500g
Price
$311
Updated
2024/03/01
Alfa Aesar
Product number
A16133
Product name
Methyl 2-fluorobenzoate, 98%
Packaging
5g
Price
$30.65
Updated
2024/03/01
Alfa Aesar
Product number
A16133
Product name
Methyl 2-fluorobenzoate, 98%
Packaging
25g
Price
$87.65
Updated
2024/03/01
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METHYL 2-FLUOROBENZOATE Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Methyl 2-fluorobenzoate may be used to synthesize 2-fluoro-α-methylstyrene and 2-fluorophenyldiphenylmethanol.

Synthesis Reference(s)

Synthetic Communications, 21, p. 2377, 1991 DOI: 10.1080/00397919108021598

General Description

Methyl 2-fluorobenzoate is an ortho-halogen-substituted methyl benzoate ester. It reacts with hydrazide to afford 2-fluorobenzoic hydrazide. Methyl 2-fluorobenzoate undergoes enzymatic dihydroxylation via the whole-cell fermentation in the presence of Escherichia coli JM109 (pDTG601A) to afford a diol.

METHYL 2-FLUOROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 2-FLUOROBENZOATE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
METHYL 2-FLUOROBENZOATE 394-35-4
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
99%
Supply Ability
2000tons
Release date
2019-12-25
Honest Joy Holdings Limited
Product
methyl 2-fluorobenzoate 394-35-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99.1%
Supply Ability
100 tons
Release date
2022-02-18
Career Henan Chemical Co
Product
METHYL 2-FLUOROBENZOATE 394-35-4
Price
US $1.00/kg
Min. Order
1g
Purity
99%
Supply Ability
100KG
Release date
2018-12-21

394-35-4, METHYL 2-FLUOROBENZOATERelated Search:

ETHYL 2-FLUOROBENZOATE 4,5-DIFLUOROPHTHALIC ANHYDRIDE Tetrafluorophthalic anhydride METHYL 2-FLUOROBENZOATE METHYL PENTAFLUOROBENZOATE METHYL 2,6-DIFLUOROBENZOATE 3-Fluorophthalic anhydride DIMETHYL 2-FLUOROTEREPHTHALATE ETHYL PENTAFLUOROBENZOATE 3,6-DIFLUOROPHTHALIC ANHYDRIDE ETHYL 2,4-DIFLUOROBENZOATE METHYL 4-FLUOROBENZOATE,METHYL P-FLUOROBENZOATE,Methyl4-fluorobenzoate,97%,Methyl 4-fluorobenzoate 97% METHYL 2-METHYL-5-FLUOROBENZOATE Methyl benzoate 2-Fluorobenzoic acid 5-FLUORO-2H-3,1-BENZOXAZINE-2,4(1H)-DIONE 2-((2-[(4-METHOXYBENZOYL)AMINO]ACETYL)AMINO)ETHYL 2-FLUOROBENZENECARBOXYLATE METHYL 2-FLUORO-6-HYDROXYBENZOATE

  • 2-fluoro-benzoicacimethylester
  • Benzoic acid, 2-fluoro-, methyl ester
  • Benzoic acid, o-fluoro-, methyl ester
  • o-Fluorobenzoic acid, methyl ester
  • METHYL 2-FLUOROBENZOATE
  • METHYL O-FLUOROBENZOATE
  • Methyl2-fluorobenzoate,98%
  • Methyl 2-fluorobenzoate 98%
  • 2-FLUOROBENZOIC ACID METHYL ESTER
  • RARECHEM AL BF 0016
  • 2-FLUOROBENZOIC ACID METHYL ESTER 98+%
  • METHYL 2-FLUOROBENZO
  • Methyl 2-fluorobenzoic acid
  • 394-35-4
  • 94-35-4
  • FC6H4CO2CH3
  • Organic Building Blocks
  • Esters
  • C8 to C9
  • Carbonyl Compounds
  • Building Blocks
  • Acids & Esters
  • Fluorine Compounds
  • C8 to C9
  • Carbonyl Compounds
  • Esters
  • Aromatic Esters