Methyl 5-fluoro-2-methylbenzoate

Product Name: Methyl 5-fluoro-2-methylbenzoate
CAS No.: 175278-29-2
Chemical Name: Methyl 5-fluoro-2-methylbenzoate
Synonyms: METHYL 5-FLUORO-2-METHYLBENZOATE;RARECHEM AL BF 0505;5-fluoro-2-methylbenzoate;METHYL 2-METHYL-5-FLUOROBENZOATE;Benzoic acid, 5-fluoro-2-methyl-, methyl ester
CBNumber: CB0334796
Molecular Formula: C9H9FO2
Formula Weight: 168.16
MOL File: 175278-29-2.mol

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Methyl 5-fluoro-2-methylbenzoate Property

Boiling point:: 90-92°C 15mm
Density: 1.137±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: liquid
color: Brown

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
Hazard Note: Irritant
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: M219378
Product name: Methyl5-Fluoro-2-MethylBenzoate
Packaging: 10mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-3-25
Product name: Methyl 5-fluoro-2-methylbenzoate
Purity: 97%
Packaging: 2g
Price: $10
Updated: 2021/12/16

Oakwood

Product number: 006817
Product name: Methyl5-fluoro-2-methylbenzoate
Purity: 98%
Packaging: 1g
Price: $10
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-3-25
Product name: Methyl 5-fluoro-2-methylbenzoate
Purity: 97%
Packaging: 5G
Price: $20
Updated: 2021/12/16

Apolloscientific

Product number: PC5114D
Product name: Methyl5-fluoro-2-methylbenzoate
Packaging: 5g
Price: $25
Updated: 2021/12/16

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Methyl 5-fluoro-2-methylbenzoate Chemical Properties,Usage,Production

Uses

Methyl 5-fluoro-2-methylbenzoate was used for the preparation of derivatives of piperidinedione.

Synthesis

33184-16-6

74-88-4

175278-29-2

5-Fluoro-2-methylbenzoic acid (2.3 g) was dissolved in tetrahydrofuran (THF, 50 ml). To the solution, iodomethane (0.95 ml) and N,N-diisopropylethylamine (3.2 ml) were added sequentially. The reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, the mixture was filtered and the filtrate concentrated to give methyl 5-fluoro-2-methylbenzoate (2.3 g; 90% yield).1H-NMR (CDCl3) δ: 2.6 (s, 3H), 3.9 (s, 3H), 7.0-7.2 (m, 2H), 7.6-7.7 (m, 1H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 17, p. 5286 - 5289
[2] Patent: WO2006/116157, 2006, A2. Location in patent: Page/Page column 83-84

Methyl 5-fluoro-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 5-fluoro-2-methylbenzoate Suppliers

China 95 France 1 Germany 2 India 2 Italy 1 United Kingdom 5 United States 18 Global 124

J & K SCIENTIFIC LTD.

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View Lastest Price from Methyl 5-fluoro-2-methylbenzoate manufacturers

Career Henan Chemical Co

Product: METHYL 2-METHYL-5-FLUOROBENZOATE 175278-29-2
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-02-13

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RARECHEM AL BF 0505

METHYL 2-METHYL-5-FLUOROBENZOATE

METHYL 5-FLUORO-2-METHYLBENZOATE

5-fluoro-2-methylbenzoate

Benzoic acid, 5-fluoro-2-methyl-, methyl ester

175278-29-2