Methyl 5-thiazolecarboxylate

Product Name: Methyl 5-thiazolecarboxylate
CAS No.: 14527-44-7
Chemical Name: Methyl 5-thiazolecarboxylate
Synonyms: NSC 321257;RARECHEM AL BF 1261;Methyl 5-thiazolecar;5-thiazole carboxylate.;METHYL 5-THIAZOLECARBOXYLATE;METHYL THIAZOLE-5-CARBOXYLATE;5-(Methoxycarbonyl)-1,3-thiazole;methyl 1,3-thiazole-5-carboxylate;Methyl 1,3-thiazole-5-carboxylate 98%;Thiazole-5-carboxylic acid methyl ester
CBNumber: CB6481766
Molecular Formula: C5H5NO2S
Formula Weight: 143.16
MOL File: 14527-44-7.mol

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Methyl 5-thiazolecarboxylate Property

Melting point:: 68-69°C
Boiling point:: 87-90°C (10 mmHg)
Density: 1.45
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: 0.80±0.10(Predicted)
Appearance: Off-white to light yellow Solid
CAS DataBase Reference: 14527-44-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39
Hazard Note: Harmful
HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: M331478
Product name: MethylThiazole-5-carboxylate
Packaging: 10mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H70-1-V8
Product name: Methyl 1,3-thiazole-5-carboxylate
Packaging: 1g
Price: $105
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H70-1-V8
Product name: Methyl 1,3-thiazole-5-carboxylate
Packaging: 250mg
Price: $35
Updated: 2021/12/16

AK Scientific

Product number: C222
Product name: Methylthiazole-5-carboxylate
Packaging: 1g
Price: $40
Updated: 2021/12/16

ChemScene

Product number: CS-M1604
Product name: 5-Thiazolecarboxylicacid,methylester
Packaging: 5g
Price: $129
Updated: 2021/12/16

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Methyl 5-thiazolecarboxylate Chemical Properties,Usage,Production

Synthesis

6633-61-0

14527-44-7

The general procedure for the synthesis of methyl 5-thiazolecarboxylate from methyl 2-aminothiazole-5-carboxylate was as follows: a mixture of 2.25 g of isoamyl nitrite with 10 mL of dioxane was stirred at 80 °C under nitrogen protection. Subsequently, a 20 mL dioxane solution containing 1.23 g of methyl 2-aminothiazole-5-carboxylate (g-3) was slowly added dropwise. After the dropwise addition was completed, the reaction mixture was refluxed for 2 hours. After the reaction was completed, it was cooled to room temperature and diluted by adding 30 mL of ethyl acetate. The organic phase was washed with saturated saline, dried over anhydrous sodium sulfate and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography to give 0.54 g (48% yield) of the target product methyl 5-thiazolecarboxylate (g-4).

References

[1] Patent: WO2003/97616, 2003, A1. Location in patent: Page/Page column 26

Methyl 5-thiazolecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 5-thiazolecarboxylate Suppliers

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View Lastest Price from Methyl 5-thiazolecarboxylate manufacturers

Career Henan Chemical Co

Product: Methyl 5-thiazolecarboxylate 14527-44-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-26

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Methyl 1,3-thiazole-5-carboxylate 98%

methyl 1,3-thiazole-5-carboxylate

METHYL 5-THIAZOLECARBOXYLATE

METHYL THIAZOLE-5-CARBOXYLATE

RARECHEM AL BF 1261

5-Thiazolecarboxylic acid, methyl ester

Thiazole-5-carboxylic acid methyl ester

Methyl 5-thiazolecar

NSC 321257

5-(Methoxycarbonyl)-1,3-thiazole

5-thiazole carboxylate.

14527-44-7

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C3 to C7

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