Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
- Product Name
- Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
- CAS No.
- 194999-85-4
- Chemical Name
- Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
- Synonyms
- BBI 109;DTBPIO-nF;DTBPI-PFBS;photoacid generator I;Bis(4-t-butylphenyl)iodonium nonaflate;BIS(4-T-BUTYLPHENYL)IODONIUM PERFLUORO-1;BIS(4-TERT-BUTYLPHENL)IODONIUM PERFLUOR&;Bis(4-tert-butylphenyl)iodonium nonaflate;Di(4-tert-butylphenyl)iodonium perfluorobutanesulfonate;Bis(4-tert-butylphenyl)iodonium perfluorobutanesulfonate
- CBNumber
- CB6500274
- Molecular Formula
- C20H26I.C4F9O3S
- Formula Weight
- 692.414
- MOL File
- 194999-85-4.mol
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Property
- Melting point:
- 175-177 °C (lit.)
- solubility
- PGMEA: ~40%
- InChI
- InChI=1S/C20H26I.C4HF9O3S/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h7-14H,1-6H3;(H,14,15,16)/q+1;/p-1
- InChIKey
- DJBAOXYQCAKLPH-UHFFFAOYSA-M
- SMILES
- C(C(F)(F)C(F)(F)F)(F)(F)C(F)(F)S([O-])(=O)=O.C1(C(C)(C)C)=CC=C([I+]C2=CC=C(C(C)(C)C)C=C2)C=C1
- EPA Substance Registry System
- Bis(4-tert-butylphenyl)iodanium nonafluorobutane-1-sulfonate (194999-85-4)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 531014
- Product name
- Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
- Purity
- electronic grade, ≥99%
- Packaging
- 1g
- Price
- $124
- Updated
- 2024/03/01
- Product number
- HCH0318478
- Product name
- BIS(4-TERT-BUTYLPHENYL)IODONIUM PERFLUORO-1-BUTANESULFONATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $500.67
- Updated
- 2021/12/16
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Chemical Properties,Usage,Production
Uses
Cationic photoinitiator. Photoacid generator.
Research
To test the reactivity of gaseous 18F-AcF in radiofluorination, bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate was radiofluorinated with anhydrous 18F-CsF (generated from 18F-AcF and 20 mg Cs2CO3) in 0.3 mL anisole. The results supported the high reactivity for 18F-fluoride derived from 18F-AcF [1].
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate is a photoinitiator (PI). The photoinitiator (PI) mechanisms are radical and cationic. In the cationic PI system, light is absorbed, causing heterolytic and homolytic cleavage that forms a cationic portion (labeled in green) and anionic portion (labeled in pink). The generated molecules are reactive with monomers, forming an acid and free radicals, propagating polymerization[2].
References
[1] Huailei Jiang , Timothy R. DeGrado, Stephen G. DiMagno . “Production and transport of gaseous 18F-synthons: 18F-acyl fluorides.” Journal of Fluorine Chemistry 180 (2015): Pages 181-185.
[2] Megan Carve, &Donald Wlodkowic. “3D-Printed Chips: Compatibility of Additive Manufacturing Photopolymeric Substrata with Biological Applications.” Micromachines 9 2 (2018).
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate manufacturers
- Product
- Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate 194999-85-4
- Price
- US $8.00-2.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-24
- Product
- Bis(4-tert-butylphenyl) Iodonium Perfluoro-1-Butane sulfonate; Bis(4-tert-butylphenyl) Iodoniumnonaflate 194999-85-4
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 99.50%
- Supply Ability
- 20 TON
- Release date
- 2023-03-14