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Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate

Product Name
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
CAS No.
194999-85-4
Chemical Name
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
Synonyms
BBI 109;DTBPIO-nF;DTBPI-PFBS;photoacid generator I;Bis(4-t-butylphenyl)iodonium nonaflate;BIS(4-T-BUTYLPHENYL)IODONIUM PERFLUORO-1;BIS(4-TERT-BUTYLPHENL)IODONIUM PERFLUOR&;Bis(4-tert-butylphenyl)iodonium nonaflate;Di(4-tert-butylphenyl)iodonium perfluorobutanesulfonate;Bis(4-tert-butylphenyl)iodonium perfluorobutanesulfonate
CBNumber
CB6500274
Molecular Formula
C20H26I.C4F9O3S
Formula Weight
692.414
MOL File
194999-85-4.mol
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Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Property

Melting point:
175-177 °C (lit.)
solubility 
PGMEA: ~40%
InChI
InChI=1S/C20H26I.C4HF9O3S/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6;5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h7-14H,1-6H3;(H,14,15,16)/q+1;/p-1
InChIKey
DJBAOXYQCAKLPH-UHFFFAOYSA-M
SMILES
C(C(F)(F)C(F)(F)F)(F)(F)C(F)(F)S([O-])(=O)=O.C1(C(C)(C)C)=CC=C([I+]C2=CC=C(C(C)(C)C)C=C2)C=C1
EPA Substance Registry System
Bis(4-tert-butylphenyl)iodanium nonafluorobutane-1-sulfonate (194999-85-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531014
Product name
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
Purity
electronic grade, ≥99%
Packaging
1g
Price
$304
Updated
2025/07/31
TCI Chemical
Product number
B6071
Product name
Bis(4-tert-butylphenyl)iodonium Nonafluoro-1-butanesulfonate
Packaging
1G
Price
$72
Updated
2025/07/31
TCI Chemical
Product number
B6071
Product name
Bis(4-tert-butylphenyl)iodonium Nonafluoro-1-butanesulfonate
Packaging
5G
Price
$216
Updated
2025/07/31
American Custom Chemicals Corporation
Product number
HCH0318478
Product name
BIS(4-TERT-BUTYLPHENYL)IODONIUM PERFLUORO-1-BUTANESULFONATE
Purity
95.00%
Packaging
5MG
Price
$500.67
Updated
2021/12/16
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Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Chemical Properties,Usage,Production

Uses

Cationic photoinitiator. Photoacid generator.

Research

To test the reactivity of gaseous 18F-AcF in radiofluorination, bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate was radiofluorinated with anhydrous 18F-CsF (generated from 18F-AcF and 20 mg Cs2CO3) in 0.3 mL anisole. The results supported the high reactivity for 18F-fluoride derived from 18F-AcF [1].    Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate is a photoinitiator (PI). The photoinitiator (PI) mechanisms are radical and cationic. In the cationic PI system, light is absorbed, causing heterolytic and homolytic cleavage that forms a cationic portion (labeled in green) and anionic portion (labeled in pink). The generated molecules are reactive with monomers, forming an acid and free radicals, propagating polymerization[2].    

References

[1] Huailei Jiang , Timothy R. DeGrado, Stephen G. DiMagno . “Production and transport of gaseous 18F-synthons: 18F-acyl fluorides.” Journal of Fluorine Chemistry 180 (2015): Pages 181-185.
[2] Megan Carve, &Donald Wlodkowic. “3D-Printed Chips: Compatibility of Additive Manufacturing Photopolymeric Substrata with Biological Applications.” Micromachines 9 2 (2018).

Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate manufacturers

Shanghai Z&T Chemical Co., Ltd
Product
Bis(4-tert-butylphenyl) Iodonium Perfluoro-1-Butane sulfonate; Bis(4-tert-butylphenyl) Iodoniumnonaflate 194999-85-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.50%
Supply Ability
20 TON
Release date
2023-03-14
Henan Fengda Chemical Co., Ltd
Product
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate 194999-85-4
Price
US $8.00-2.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-24

194999-85-4, Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonateRelated Search:


  • BIS(4-TERT-BUTYLPHENL)IODONIUM PERFLUOR&
  • BBI 109
  • Bis(4-t-butylphenyl)iodonium nonaflate
  • Bis(4-tert-butylphenyl)iodonium nonaflate
  • Bis(4-tert-butylphenyl)iodonium nonafluorobutanesulfonate
  • Bis(4-tert-butylphenyl)iodonium perfluorobutanesulfonate
  • Di(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
  • Di(4-tert-butylphenyl)iodonium perfluorobutanesulfonate
  • DTBPI-PFBS
  • BIS(4-T-BUTYLPHENYL)IODONIUM PERFLUORO-1
  • Bis[4-(1,1-dimethylethyl)phenyl]iodonium salt with 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonic acid (1:1)
  • Bis(4-tertbutylphenyl) iodanium,1,1,2,2,3,3,4, 4,4-nonafluorobutane-1-sulfonate
  • Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate electronic grade, >=99%
  • DTBPIO-nF
  • Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate electronic grade
  • photoacid generator I
  • 2H-Isoindole-2-acetamide,α-(5-fluoro-2-hydroxyphenyl)-1,3-dihydro-1-oxo-N-6-thiazolyl-
  • Iodonium, bis[4-(1,1-dimethyl- ethyl)phenyl]-,1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonate
  • BIS(4-TERT-BUTYLPHENYL)IODONIUM PERFLUORO-1-BUTANESULFONATE
  • Bis(4-tert-butylphenyl)iodonium Nonafluoro-1-butanesulfonate
  • bis(4-(tert-butyl)phenyl)iodonium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
  • Bis(4-<i>tert</i>-butylphenyl)iodonium perfluoro-1-butanesulfonate
  • 194999-85-4
  • CH33CC6H42IC4F9SO3
  • C20H26IC4F9O3S
  • Cationic PhotoinitiatorsSelf Assembly&Contact Printing
  • Organic Photoinitiators
  • Photoacid Generators (PAGs)
  • Photoresists
  • Polymerization Initiators