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DIMETHYL BROMOMALONATE

Product Name
DIMETHYL BROMOMALONATE
CAS No.
868-26-8
Chemical Name
DIMETHYL BROMOMALONATE
Synonyms
Dimethyl 2-bromomalonate;DIMETHYL BROMOMALONATE;DimethylBromomalonate>Dimethyl bromomalonate ,98%;Dimethyl bromomalonate ,96%;dimethyl 2-bromopropanedioate;DiMethyl broMoMalonate, GC 90%;Bromomalonic acid dimethyl ester;DiMethyl BroMoMalonate, 95.0%(GC);2-Bromomalonic acid dimethyl ester
CBNumber
CB6685803
Molecular Formula
C5H7BrO4
Formula Weight
211.01
MOL File
868-26-8.mol
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DIMETHYL BROMOMALONATE Property

Boiling point:
105-108 °C/11 mmHg (lit.)
Density 
1.601 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.460(lit.)
Flash point:
>230 °F
pka
9.25±0.46(Predicted)
form 
Liquid
color 
Clear colorless to light yellow
BRN 
971135
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
F 
19
HazardClass 
8
PackingGroup 
III
HS Code 
29171900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
359890
Product name
Dimethyl bromomalonate
Purity
technical grade, 90%
Packaging
5ml
Price
$29.64
Updated
2024/03/01
Sigma-Aldrich
Product number
359890
Product name
Dimethyl bromomalonate
Purity
technical grade, 90%
Packaging
25ml
Price
$197
Updated
2024/03/01
TCI Chemical
Product number
D3887
Product name
Dimethyl Bromomalonate
Purity
>95.0%(GC)
Packaging
5g
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
D3887
Product name
Dimethyl Bromomalonate
Purity
>95.0%(GC)
Packaging
25g
Price
$125
Updated
2024/03/01
TRC
Product number
D471278
Product name
Dimethyl bromomalonate
Packaging
500mg
Price
$75
Updated
2021/12/16
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DIMETHYL BROMOMALONATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Dimethyl bromomalonate may be used in the enantioselective synthesis of nitrocyclopropanes.

General Description

Dimethyl bromomalonate undergoes manganese(III)-promoted free-radical chain addition reaction with olefins, to yield dimethyl 2-bromoalkylmalonates. Organocatalyzed Michael addition of dimethyl bromomalonate to nitrostyrenes to yield synthetically useful nitrocyclopropanes has been reported. Dimethyl bromomalonate reacts readily with arylnitroso compounds to yield the corresponding N-aryl-C,C-dimethoxycarbonylnitrones.

DIMETHYL BROMOMALONATE Preparation Products And Raw materials

Raw materials

Dimethyl malonate Sodium thiosulfate Carbon tetrachloride Sodium bicarbonate Government regulation Dichloromethane

Preparation Products

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View Lastest Price from DIMETHYL BROMOMALONATE manufacturers

Career Henan Chemical Co
Product
DIMETHYL BROMOMALONATE 868-26-8
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-09

868-26-8, DIMETHYL BROMOMALONATERelated Search:

Dimethyl malonate DIETHYL 2-BROMO-2-FLUORO-MALONATE DIMETHYL BROMOMALONATE DIMETHYL DIBROMOMALONATE Diethyl 2-bromo-2-methylmalonate DIMETHYL 2-BROMO-2-(5-NITRO-2-PYRIDINYL)MALONATE DIETHYL BROMOMALONATE DIMETHYL 2-BROMO-2-(4-NITROPHENYL)MALONATE 2-BROMO-2- (1-TERT-BUTOXYCARBONYL-PYRROLIDIN-3-YL)-MALONIC ACID DIMETHYL ESTER 2-BROMO-2- (1-TERT-BUTOXYCARBONYL-PIPERIDIN-4-YL)-MALONIC ACID DIMETHYL ESTER DIETHYL DIBROMOMALONATE

  • Dimethyl bromomalonate technical grade, 90%
  • Bromomalonic acid dimethyl ester
  • Bromopropanedioic acid dimethyl ester
  • Dimethyl bromomalonate ,96%
  • DiMethyl broMoMalonate, tech., 90% 25ML
  • DiMethyl broMoMalonate, GC 90%
  • DiMethyl BroMoMalonate, 95.0%(GC)
  • Dimethyl 2-bromomalonate
  • Propanedioic acid, bromo-, dimethyl ester
  • DIMETHYL BROMOMALONATE
  • Dimethyl bromomalonate ,98%
  • Dimethyl bromomalonate, 90%, tech.
  • 2-Bromomalonic acid dimethyl ester
  • DIMETHYL BROMOMALONATE, TECH., 90%
  • DimethylBromomalonate&gt
  • Propanedioic acid, 2-bromo-, 1,3-dimethyl ester
  • dimethyl 2-bromopropanedioate
  • 868-26-8
  • C5H7BrO4
  • BrCHCOOCH32
  • Building Blocks
  • C2 to C5
  • Carbonyl Compounds
  • Organic Building Blocks
  • Esters
  • Pharmaceutical Intermediates
  • C2 to C5
  • Carbonyl Compounds
  • Esters