ChemicalBook > CAS DataBase List > 3-BENZYLOXYBROMOBENZENE

3-BENZYLOXYBROMOBENZENE

Product Name: 3-BENZYLOXYBROMOBENZENE
CAS No.: 53087-13-1
Chemical Name: 3-BENZYLOXYBROMOBENZENE
Synonyms: Metaraminol Impurity 14;oxy-3-bromobenzene;3-Benzyloxybromobenzen;3-BENZYLOXYBROMOBENZENE;Metaraminol Impurity 29;Metaraminol Impurity 62;3-BROMOPHENYL BENZYL ETHER;1-Bromo-3-benzyloxybenzene;BENZYL 3-BROMOPHENYL ETHER;1-BENZYLOXY-3-BROMOBENZENE
CBNumber: CB6700025
Molecular Formula: C13H11BrO
Formula Weight: 263.13
MOL File: 53087-13-1.mol

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3-BENZYLOXYBROMOBENZENE Property

Melting point:: 57-60 °C
Boiling point:: 333.5±17.0 °C(Predicted)
Density: 1.382±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: Solid
color: White
InChI: InChI=1S/C13H11BrO/c14-12-7-4-8-13(9-12)15-10-11-5-2-1-3-6-11/h1-9H,10H2
InChIKey: HVWZMGZBJCJDOX-UHFFFAOYSA-N
SMILES: C1(Br)=CC=CC(OCC2=CC=CC=C2)=C1
CAS DataBase Reference: 53087-13-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,N
Risk Statements: 36/37/38-50/53-43-41
Safety Statements: 26-36/37/39-50/53-43-41-61-60
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 668419
Product name: 3-Benzyloxybromobenzene
Purity: 96%
Packaging: 10g
Price: $84.5
Updated: 2023/06/20

Sigma-Aldrich

Product number: 668419
Product name: 3-Benzyloxybromobenzene
Purity: 96%
Packaging: 50g
Price: $216
Updated: 2023/06/20

TCI Chemical

Product number: B2307
Product name: 1-Benzyloxy-3-bromobenzene
Purity: >98.0%(GC)
Packaging: 5g
Price: $34
Updated: 2025/07/31

TCI Chemical

Product number: B2307
Product name: 1-Benzyloxy-3-bromobenzene
Purity: >98.0%(GC)
Packaging: 25g
Price: $134
Updated: 2025/07/31

TRC

Product number: B291410
Product name: 1-(Benzyloxy)-3-bromobenzene
Packaging: 1g
Price: $55
Updated: 2021/12/16

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3-BENZYLOXYBROMOBENZENE Chemical Properties,Usage,Production

Chemical Properties

Whitetolightyellowcrystalpowde

Synthesis

591-20-8

100-44-7

53087-13-1

1. Anhydrous potassium carbonate (37.32 g, 270 mmol) and benzyl chloride (11.50 mL, 99 mmol) were added to a suspension of anhydrous ethanol (300 mL) containing m-bromophenol (15.57 g, 90 mmol) under nitrogen protection. The reaction mixture was heated to reflux for 4 hours. After completion of the reaction, the ethanol was removed by vacuum filtration and evaporation. The residue was extracted with ethyl acetate (EtOAc) and the combined organic layers were washed sequentially with water, 2 M NaOH solution, saturated brine and 2 M HCl solution, dried over anhydrous sodium sulfate (Na2SO4) and concentrated to give the yellow solid product 3-benzyloxybromobenzene (22.02 g, 93%). 2. To a 250 mL two-necked round-bottomed flask, protected by nitrogen, were added dry magnesium chips (2.18 g, 90 mmol) and trace iodine, equipped with two rubber septa and stirred. Anhydrous tetrahydrofuran (THF, 40 mL) solution of 3-benzyloxybromobenzene (15.79 g, 60 mmol) was slowly added through a syringe and kept at reflux. After addition, stirring was continued at reflux for 5 hours. After the reaction mixture was cooled to -30°C, anhydrous THF (60 mL) solution of trimethyl borate (9.36 g, 90 mmol) was slowly added. After addition, the mixture was stirred at room temperature overnight, followed by treatment with saturated ammonium chloride (NH4Cl) solution and continued stirring at room temperature for 1 hour. THF was removed by rotary evaporation, the aqueous layer was extracted with EtOAc, dried over anhydrous Na2SO4, filtered and concentrated to give a yellow crude product. The crude product was purified by recrystallization in water to give white solid target product (7.53 g, 55%).

References

[1] Journal of Materials Chemistry, 2010, vol. 20, # 15, p. 3069 - 3078
[2] Bioorganic and Medicinal Chemistry, 2015, vol. 23, # 5, p. 1044 - 1054
[3] Journal of Medicinal and Pharmaceutical Chemistry, 1962, vol. 5, p. 752 - 762
[4] Patent: US5447656, 1995, A
[5] Patent: EP838461, 1998, A2

3-BENZYLOXYBROMOBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-BENZYLOXYBROMOBENZENE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 3-BENZYLOXYBROMOBENZENE 53087-13-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-03-07

Career Henan Chemical Co

Product: 3-BENZYLOXYBROMOBENZENE 53087-13-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2018-12-25

53087-13-1, 3-BENZYLOXYBROMOBENZENERelated Search:

3-BENZYLOXYBROMOBENZENE 4-BENZYLOXYBROMOBENZENE,Benzyloxybromobenzene,4-BENZYLOXYBROMOBENZENE TECH GRADE BENZOYL BROMIDE 3-(3-BROMO-PHENOXYMETHYL)-BENZOIC ACID 4-(BENZYLOXY)-2-BROMO-5-ETHOXYBENZALDEHYDE 2-(Benzyloxy)broMobenzene 3,5-DICHLORO-4-BENZYLOXYBROMOBENZENE AKOS B005166 AKOS B005164 AKOS B005176 3-BROMO-5-BENZYLOXY-2,6-DINITROBENZOIC ACID BENZYL ESTER AKOS B005175 AKOS B005426 AKOS B005177 SPECS AN-655/15530009 AKOS B005457 AKOS B005168 AKOS B005178

1-BENZYLOXY-3-BROMOBENZENE

1-Benzyloxy-3-broMobenzene,Benzyl 3-BroMophenyl Ether

BENZYL 3-BROMOPHENYL ETHER

3-Benzyloxybromobenzen

1-Bromo-3-benzyloxybenzene

3-BROMOPHENYL BENZYL ETHER

3-BENZYLOXYBROMOBENZENE

1-(Benzyloxy)-3-bromobenzen

oxy-3-bromobenzene

1-Benzyloxy-3-bromobenzene &gt

Benzene, 1-bromo-3-(phenylmethoxy)-

Metaraminol Impurity 14

1-Benzyloxy-3-bromobzenzene

(E)-1-(3-(benzyloxy)phenyl)-1-hydroxypropan-2-one oxime

Metaraminol Impurity 29

Metaramine bitartrate Impurity 33

Metaraminol Impurity 62

Metaraminol Bitartrate Impurity 83

53087-13-1

Ethers

Organic Building Blocks

Oxygen Compounds

Building Blocks

Phenetole

Anisoles, Alkyloxy Compounds & Phenylacetates

Bromine Compounds

Ethers

Organic Building Blocks

Oxygen Compounds

alkyl bromide