ChemicalBook > CAS DataBase List > CYCLOHEXYLZINC BROMIDE

CYCLOHEXYLZINC BROMIDE

Product Name
CYCLOHEXYLZINC BROMIDE
CAS No.
7565-57-3
Chemical Name
CYCLOHEXYLZINC BROMIDE
Synonyms
CYCLOHEXYLZINC BROMIDE;bromozinc(1+),cyclohexane;cyclohexylzinc(II) broMide;cyclohexylzinc bromide solution;Cyclohexylzinc bromide, 0.5 M in THF;Cyclohexylzinc bromide, 0.50 M in THF;Cyclohexylzinc bromide solution 0.5 in THF;Cyclohexylzinc broMide solution 0.5 M in THF;Cyclohexylzinc broMide, 0.5 M solution in THF, SpcSeal;CYCLOHEXYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
CBNumber
CB6705378
Molecular Formula
C6H11BrZn
Formula Weight
228.45
MOL File
7565-57-3.mol
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CYCLOHEXYLZINC BROMIDE Property

Melting point:
114.0-116.0 °C
Density 
0.963 g/mL at 25 °C
Flash point:
3 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety

Hazard Codes 
F,Xn,C
Risk Statements 
14-19-22-36/37/38-40-37-34-11
Safety Statements 
16-23-26-36-45-36/37/39
RIDADR 
UN 2056 3/PG 2
WGK Germany 
1
HazardClass 
4.3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231Handle under inert gas.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
498033
Product name
Cyclohexylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$287
Updated
2024/03/01
Alfa Aesar
Product number
H58852
Product name
Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$217
Updated
2024/03/01
TRC
Product number
C991955
Product name
Cyclohexylzinc bromide solution
Packaging
25ml
Price
$385
Updated
2021/12/16
Matrix Scientific
Product number
121891
Product name
Cyclohexylzincbromide
Purity
0.50MinTHF97%
Packaging
100ml
Price
$442
Updated
2021/12/16
Matrix Scientific
Product number
121891
Product name
Cyclohexylzincbromide
Purity
0.50MinTHF97%
Packaging
500ml
Price
$1349
Updated
2021/12/16
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CYCLOHEXYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

It is used as primary and secondary intermediate.

Uses

Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.

It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones.

CYCLOHEXYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CYCLOHEXYLZINC BROMIDE Suppliers

China 17 India 1 Switzerland 1 United Kingdom 1 United States 6 Global 26
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
Rieke Metals, Inc.
Tel
--
Fax
--
Email
sales@riekemetals.com
Country
United States
ProdList
6509
Advantage
69
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Labseeker Inc
Tel
--
Fax
--
Email
marketing@labseeker.com
Country
United States
ProdList
1495
Advantage
55

7565-57-3, CYCLOHEXYLZINC BROMIDERelated Search:

1-ADAMANTYLZINC BROMIDE CYCLOHEXYLZINC BROMIDE EXO-2-NORBORNYLZINC BROMIDE 2-ADAMANTYLZINC BROMIDE 3,5-DIMETHYL-1-ADAMANTYLZINC BROMIDE

  • CYCLOHEXYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
  • CYCLOHEXYLZINC BROMIDE
  • cyclohexylzinc bromide solution
  • Cyclohexylzinc bromide solution 0.5 in THF
  • Cyclohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
  • cyclohexylzinc(II) broMide
  • Cyclohexylzinc broMide solution 0.5 M in THF
  • Cyclohexylzinc broMide, 0.5 M solution in THF, SpcSeal
  • Cyclohexylzinc bromide, 0.50 M in THF
  • Cyclohexylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
  • Cyclohexylzinc bromide, 0.5 M in THF
  • bromozinc(1+),cyclohexane
  • 7565-57-3
  • C6H11ZnBr
  • C6H11BrZn
  • Alkyl
  • Reike and Organozinc Reagents
  • Organometallic Reagents
  • Organozinc Halides
  • Chemical Synthesis
  • Organometallic Reagents
  • Organozinc Halides
  • Rieke and Organozinc Reagents
  • Alkyl
  • Organozinc Halides
  • Reike and Organozinc Reagents