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Vinylmagnesium bromide

Product Name
Vinylmagnesium bromide
CAS No.
1826-67-1
Chemical Name
Vinylmagnesium bromide
Synonyms
bromovinylmagnesium;PEFC-028;0.98g/ml，20℃;bromoethenyl-magn;Bromvinylmagnesium;bromoethenyl-magnesiu;Bromoethenylmagnesium;VINYLMAGNESIUMBROMICLC;VINYLMAGNESIUM BROMIDE;Magnesium vinyl bromide
CBNumber
CB6710891
Molecular Formula
C2H3BrMg
Formula Weight
131.26
MOL File
1826-67-1.mol
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Vinylmagnesium bromide Property

Density 
0.981 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
Refrigerator
solubility 
vigorous reaction
form 
Solution
color 
Clear light brown to brown
Water Solubility 
vigorous reaction
BRN 
3535841
CAS DataBase Reference
1826-67-1(CAS DataBase Reference)
EPA Substance Registry System
Magnesium, bromoethenyl- (1826-67-1)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-14-19-34-14/15-40-37
Safety Statements 
16-26-29-33-36/37/39-45-6A-43B-43
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
F 
1-3-10
HazardClass 
4.3/3
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
225584
Product name
Vinylmagnesium bromide solution
Purity
1.0 M in THF
Packaging
100ml
Price
$63.4
Updated
2024/03/01
Sigma-Aldrich
Product number
225584
Product name
Vinylmagnesium bromide solution
Purity
1.0?M in THF
Packaging
4X25ML
Price
$90.4
Updated
2024/03/01
Sigma-Aldrich
Product number
225584
Product name
Vinylmagnesium bromide solution
Purity
1.0?M in THF
Packaging
18L
Price
$2330
Updated
2024/03/01
TCI Chemical
Product number
V0053
Product name
Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca. 1mol/L)
Packaging
100g
Price
$79
Updated
2024/03/01
Sigma-Aldrich
Product number
257257
Product name
Vinylmagnesium bromide solution
Purity
1.0 M in THF
Packaging
200ml
Price
$214
Updated
2024/03/01
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Vinylmagnesium bromide Chemical Properties,Usage,Production

Chemical Properties

Clear light brown to brown solution

Uses

Vinylmagnesium bromide solution (1 M in THF) may be used in the synthesis of 2-vinylchroman-4-ones by the conjugate addition with chromones in the presence of a Lewis acid.
It may also be used in the following transformations:

  • (S)-3-(benzyloxy)-4-oxo-butanoic acid methyl ester to methyl (3S,4S)-4-hydroxy-3-(phenylmethoxy)hex-5-enoate.
  • (R)-1-Azido-5,6-epoxyhexane to (S)-1-(4-azidobutyl)-2-propen-1-ol.
  • 2,3-O-Isopropylidene-D-ribose to 1-[(4R,5S)-5-((1S)-1-hydroxyallyl)-2,2-dimethyl[1,3]dioxolan-4-yl]ethane-1,2-diol.
  • (4S,5S)-2,2-Dimethyl-5-vinyl[1,3]dioxolane-4-carbaldehyde to (1R,4R,5S)- and (1S,4R,5S)-1-(2,2-dimethyl-5-vinyl[1,3]dioxolan-4-yl)prop-2-en-1-ol.
  • Ethyl levulinate to ?-methyl-?-vinylbutyrolactone.

Vinylmagnesium bromide Preparation Products And Raw materials

Raw materials

Vinyl bromide Tetrahydrofuran Magnesium

Preparation Products

Tributyl(vinyl)tin 4-bromo-7-chloro-1H-pyrrolo[2,3-c]pyridine 7-Fluoroindole 9-VINYLANTHRACENE
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Vinylmagnesium bromide Suppliers

Belgium 1 China 196 France 1 Germany 1 India 19 Japan 1 Slovakia 1 Switzerland 1 United Kingdom 5 United States 17 Global 243
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View Lastest Price from Vinylmagnesium bromide manufacturers

Hebei Duling International Trade Co. LTD
Product
Vinylmagnesium bromide 1826-67-1
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-01-13
Hebei Yanxi Chemical Co., Ltd.
Product
Vinylmagnesium bromide 1826-67-1
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-11-29
Career Henan Chemical Co
Product
Vinylmagnesium bromide 1826-67-1
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10KG
Release date
2019-08-05

1826-67-1, Vinylmagnesium bromideRelated Search:

Allyl bromide Vinyl bromide Methylmagnesium Bromide Magnesium bromide VINYL PROPIONATE Ethylmagnesium bromide N-Vinyl-2-pyrrolidone PHENYLMAGNESIUM BROMIDE ETHYNYLMAGNESIUM BROMIDE Ethidium bromide Triethoxyvinylsilane Rocuronium bromide Sodium bromate Iridium(III) acetylacetonate POTASSIUM VINYLTRIFLUOROBORATE Vinylmagnesium chloride Ethoxydimethylvinylsilane POLY(VINYLPHOSPHONIC ACID)

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  • 1826-67-1
  • CH2CHMgBr
  • C2H3BrMg
  • Organometallic Reagents
  • Alkenyl
  • Grignard Reagents & Alkyl Metals
  • Grignard Reagents
  • Typical Metal Compounds
  • Mg (Magnesium) Compounds
  • Classes of Metal Compounds
  • Grignard Reagent
  • GRIGNARD REAGENTS
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Mg (Magnesium) Compounds
  • Synthetic Organic Chemistry